On the heat removal characteristics and the analytical model of a thermal energy storage capsule using gelled Glauber's salt as the PCM

An analytical and experimental investigation was performed on a heat removal process of the thermal energy storage (TES) capsule, using gelled Glauber's salt. Transient heat flux at the capsule wall was measured for various cooling conditions. In cases where the initial temperature was lower than the saturation temperature of the phase change material (PCM), numerical analyses were performed, approximating the process by a relaxation phenomenon where crystals grew around crystal nuclei. The results of the numerical solution agreed very well with the experimental results.     

Hydrocracking of diphenylmethane and tetralin over bifunctional NiW sulfide catalysts supported on three kinds of zeolites

Hydrocracking reactions of diphenylmethane and tetralin were carried out over three kinds of zeolites with or without NiW sulfide to discuss the roles of catalytic bifunctionality in two types of hydrocracking reactions. It was found that strong acid sites were not needed for the hydrocracking of diphenylmethane, while the conversion of tetralin required relatively strong acid sites. Ultra-stable Y zeolite with strong acidity exhibited high hydrocracking activity for both reactions. In contrast, mordenite catalysts did not show high activity for either hydrocracking, though isomerization of tetralin and excess hydrocracking to gaseous products proceeded. The superior performances of ultra-stable Y zeolite in the tetralin hydrocracking were suggested to be related to the hydrogen transfer ability. In most cases, the loading of NiW sulfide enhanced catalytic activity. In the diphenylmethane hydrocracking, the role of NiW sulfide was found to supply active hydrogen to the hydrocracking active sites on zeolite and to prevent polymerization of benzyl cations. In the tetralin hydrocracking, the dehydrogenated products from tetralin were re-hydrogenated over NiW sulfide.     

Feasibility study on cellular network analysis with patterned cell culture microdevice

In order to realize cellular network analysis on a chip-based system, our group has been developing a patterned cell culture microdevice with pillars in an array for tapping cells into space surrounded by the pillars. The pillar structures has advantages to trap both adhesive and non-adhesive cells and to precisely control positions of cells and distances between cells for understanding effects of various cell patterns on functions of a cellular network such as cell proliferation, differentiation, and network formation. In this paper, HeLa cell cultivation with the patterned cell culture microdevice having a pillar array fabricated by dry film of thick negative photoresist SU-8 on a glass substrate was executed as a feasibility study on a cellular network analysis. The results revealed that the device performance was found to be enough to culture HeLa cells for more than 48 h. In addition, relative extensibility of blocks of multiple cells compared with single cells tapped on the device was observed. Thus, the patterned cell culture microdevice proposed here could be applicable to analysis of cellular functions.     

AC side harmonic and phenomena accompanying DC-injection of utility-interactive PV system

The experiments investigated phenomena related to direct contact between the DC output of a PV array and the AC power from the utility grid. The results show that the DC power flows through the distribution transformers (DC-injection) saturating their magnetic circuits. The saturation of magnetic circuits makes peak currents, incorporating a large portion of even harmonics, flow through the high-voltage side of the distribution transformer, adding the level of harmonic distortion of its exciting current. With the increase of injecting DC-current to the utility grid, peak currents at the primary side of distribution transformer increases the most, and even among the same effective (rms) values, the increase of primary side current is larger than that of the secondary side current.     

Improvement of strength distribution inside slab concrete by vacuum dewatering method

The strength and hardness of concrete slab surface is considered significantly affected by bleeding of concrete. It has been reported that dewatering by vacuum processing is quite effective to obtain high density of concrete. The method, however, has not been successfully used for the concrete work in the field of building construction, compared with that of civil engineering works in Japan. In the present study, firstly the state of the art concerning vacuum dewatering method is reviewed and the newly improved vacuum dewatering method is introduced. Then the effect of the proposed method on concrete properties of slab is examined by a series of experiments in order to find more reasonable and effective way in the application of the proposed method.     

XPS analysis of CdS/CuInSe2 heterojunctions

CdS/CuInSe₂ (CIS) heterojunctions were investigated by XPS analysis. An In-excess layer which may form an ordered vacancy compound (OVC) was present at the as-deposited CIS surface and it remained after chemical bath deposition of a CdS layer. The In-excess layer was removed by preferential etching with NH₃ aqueous solution. This result implies that the surface of the as-deposited CIS film was converted from the OVC with n-type conductivity into the CIS with p-type by NH₃ treatment. The conduction band offsets at the CdS/p-CIS and CdS/n-OVC were determined to be 1.0 and 0.3 eV, respectively. The CIS solar cells fabricated with n-OVC surface layer exhibited higher cell efficiencies than those fabricated with p-CIS surface layer.     

Effect of Pd and In on mercury evaporation from amalgams

The aim of work was evaluation of voice pathology in patients with allergic rhinitis. Larynx organic pathology were found in 75% patients with coexisting allergic rhinitis in the form of Reinke's oedema, chronic hypertrophic laryngitis, larynx polyp and vocal nodules. It caused serious voice pathology (dysphonia) which was confirmed by an objective spectrographic method. Larynx organic pathology was not in 15% patients. In these cases rhinophonia was found in consequence of resonance nasal defect.     

Theoretical model of the two-chamber pressure casting process

This article develops a theoretical model of the two-chamber pressure casting process. In this process, a molten metal drop, formed by arc melting a solid ingot, falls into a conical crucible attached to a gas-filled, porous cast mold. An energy-based formulation of the mold-filling process is developed which focuses on the drop’s motion within the crucible and mold cavity and on pressure evolution within the mold cavity. The model shows that drop acceleration into the mold depends on three dimensionless parameters, the Euler number, Eu, the Froude number, Fr, and the pressure loss coefficient, K, across the crucible exit. These parameters are in turn determined by the mold’s permeability to the process gas, the characteristic initial pressure difference between the interior and exterior of the mold, the mold thickness, the process gas viscosity, and the metal density. Drop acceleration into the mold compresses trapped gas within the mold cavity; under most conditions, pressure decay due to leakage of the trapped gas through the mold occurs at a faster rate than inertial compression. Under these circumstances, a downward acting pressure force, having a magnitude determined by the Euler number, acts on the drop. At low Froude numbers, however, gas compression occurs at a faster rate than leakage-induced decay and the pressure force acts upward, again with a magnitude determined by Eu. Scaling arguments show that friction and evaporation recoil forces are negligible in determining drop motion, while surface tension, pressure, drop inertia, and gravity are dominant. In addition, solidification effects are shown to be negligible.     

Fatigue crack initiation and growth under mixed mode loading in aluminum alloys 2017-T3 and 7075-T6

Fatigue crack initiation and growth characteristics under mixed mode loading have been investigated on aluminum alloys 2017-T3 and 7075-T6, using a newly developed apparatus for mixed mode loading tests. In 2017-T3, the fatigue crack initiation and growth characteristics from a precrack under mixed mode loading are divided into three regions—shear mode growth, tensile mode growth and no growth—on the ΔK_I-ΔK_II plane. The shear mode growth is observed in the region expressed approximately by ΔK_II > 3MPa√m and ΔK_II/ΔK_I > 1.6. In 7075-T6, the condition of shear mode crack initiation is expressed by ΔK_II > 8 MPa√m and ΔK_II/ΔK_I > 1.6, and continuous crack growth in shear mode is observed only in the case of ΔK_I/ΔK_II, 0. The threshold condition of fatigue crack growth in tensile mode is described by the maximum tensile stress criterion, which is given by Δσ_θmax √2πr 1.6MPa√m, in both aluminum alloys. The direction of shear mode crack growth approaches the plane in which K_I decreases and K_II increases towards the maximum with crack growth. da/dN-ΔK_II relations of the curved cracks growing in shear mode under mixed mode loading agree well with the da/dN-ΔK_II relation of a straight crack under pure mode II loading.     

Properties of bifunctional phosphonate fibers derived from chloromethylstyrene grafted polyolefin fibers

Bifunctional fibers containing phosphonate and sulfonate were derived from chloromethylstyrene grafted polyolefin fibers (PPPE-g-CMS) by phosphorylation and subsequent sulfonation reactions. It was clarified that phosphorylation of PPPE-g-CMS by Arbusov reaction is more suitable than one by the reaction with PCl₃ in the presence of AlCl₃, because the latter damaged fibers and gave phosphinate groups in addition to phosphonate ones. Then, bifunctional fibers containing phosphonate and sulfonate groups were prepared by sulfonation of monofunctional phosphonate fibers obtained via Arbusov reaction with chlorosulfonic acid. The metal ion selectivity of the bifunctional fibers was governed by both phosphonate and sulfonate groups. In addition, bifunctional fibers gave much more excellent kinetic performances in column-mode uptake of Cu(II) than the monofunctional phosphonate fibers and resin.