Influence of Jet‐Cooking Temperature and Ionic Strength on Size and Structure of Cationic Potato Amylopectin Starch as Measured by Asymmetrical Flow Field‐Flow Fractionation Multi‐Angle Light Scattering

Asymmetrical flow field‐flow fractionation (AsFlFFF) in combination with multi‐angle light scattering (MALS) was applied to cationic potato amylopectin (CPAP) to investigate how molar mass, root‐mean‐square (r.m.s.) radius and shape was influenced by different conditions of jet‐cooking. The effect of different jet‐cooking temperatures in the range 110°C – 140°C was studied in an excess steam jet‐cooker. This equipment is used in the industry for dissolution of starch and starch derivatives before technical application. The effect of different ionic strengths conditions was examined in the range of 10–200 mM. The weight‐average molar mass decreased from about 34×10⁷ g/mol to 2.6×10⁷ g/mol when the jet‐cooking temperature was increased from 110°C to 140°C. Concurrently the root‐mean‐square radius decreased from ca 380 nm to 90 nm. The decrease in size was reflected by a decrease in viscosity with increasing temperature. The root‐mean‐square radius was reduced when increasing the ionic strength. This decrease in size was correlated with a decrease in viscosity. Conformation and Kratky plots showed that at low ionic strength (≤ 10 mM) CPAP behaved as a flexible chain with high degree of branching, close to hyperbranching. Increase of the ionic strength gave a more compact structure and changes in the internal structure were observed as well. Consequently, by using AsFlFFF – MALS the effect of technical processing on the molar mass, molecular radius, conformational structure, and shape could be determined in a size region where standard methodology commonly fails.     

Use of nanoparticular and soluble anionic celluloses in coagulation-flocculation treatment of kaolin suspension

In this work, the effectiveness of a novel, combined coagulation-flocculation treatment based on alum and soluble or nanoparticular anionic derivatives of dialdehyde cellulose, ADAC, was evaluated by studying the removal of colloidal material in a model suspension containing kaolin. Four different ADACs with varying degrees of substitution, size and water solubility were synthesized by periodate oxidation and sulfonation of cellulose. The effects of ADAC dosage, solution pH and temperature on flocculation were studied by measuring residual turbidity of the settled suspension. Moreover, the charge densities, sizes, ζ-potentials and stability of the ADACs in aqueous solutions were studied. The combined treatment was effective in the removal of colloidal particles, as demonstrated by reduced residual turbidity with remarkably lower total chemical consumption compared with coagulation with alum alone. Of the ADACs, samples with lower solubility that contained cellulose nanoparticles performed better than the fully water-soluble sample. Due to the restricted pH tolerance of alum, the combined treatment was effective only at acidic conditions (pH < 5), although the ADACs were found to be stable in a much broader pH range (pH of 3 to about 9). ADACs also retained strong activity at higher temperatures (30-60 °C) and after several days of storage in aqueous solution.     

Unstable eigenmodes are possible drivers for cardiac arrhythmias

The well-organized contraction of each heartbeat is enabled by an electrical wave traversing and exciting the myocardium in a regular manner. Perturbations to this wave, referred to as arrhythmias, can lead to lethal fibrillation if not treated within minutes. One manner in which arrhythmias originate is an ill-fated interaction of the regular electrical signal controlling the heartbeat, the sinus wave, with an ectopic stimulus. It is not fully understood how and when ectopic waves are generated. Based on mathematical models, we show that ectopic beats can be characterized in terms of unstable eigenmodes of the resting state.     

A method for landscape regionalization based on fuzzy membership signatures

The aim of this paper is to present a new method for regionalization that can be used in landscape analysis and planning. The approach in this study concentrates on the possibility to use membership functions developed from training sites as a mean to characterize whole regions. Instead of traditional classification routines a fuzzy method was developed. The method is described with an example from a study area located in Sweden. Pre-classified and unclassified satellite data were used in the study. The frequency distribution of three land cover types was calculated for three different training sites. The frequency distributions were transformed into membership functions. As such they describe the graded membership for every frequency pixel to all the training sites. Thereafter, were the membership images combined through a weighted linear combination. The result shows the membership for every location in the study area to one of the training sites. The images were also classified into one resulting image showing the crisp regions of the study area. An accuracy assessment of the method was performed. The result showed an overall classification accuracy of 86% compared to existing regional divisions of the study area.     

Professionals’ knowledge and use of environmental assessment in an architectural competition

In early design phases, architects, landscape architects and urban planners are key actors whose decisions determine the environmental impact of planning and building projects. Environmental and sustainability assessment tools for buildings and neighbourhoods have been developed to promote sustainable building, but their usage has not been thoroughly evaluated. This study investigated self-reported knowledge and usage of such tools among competitors and jury group from 10 European countries involved in the international architectural competition ‘A New City Centre for Kiruna’ in Sweden. The questionnaire revealed that 13% used environmental assessment tools or management systems in the competition, although 47% had used them previously. Tool users reported greater knowledge of how to handle environmental impacts than non-users. However, the self-rated experience of handling various environmental impacts, in the competition and in general, was low for both groups. Nevertheless, the self-rated importance of environmental impacts was high among all participants. Based on this study, it is concluded that environmental assessment tools, issues and goals can be better integrated into the processes of early design in planning and building projects, and in architectural competitions. Furthermore, to limit environmental impacts in building and planning projects, professionals need to be educated about environmental strategies and solutions.     

Effect of commercial rye whole-meal bread on postprandial blood glucose and gastric emptying in healthy subjects

Background  

The intake of dietary fibre has been shown to reduce the risk of developing diabetes mellitus. The aim of this study was to compare the effects of commercial rye whole-meal bread containing whole kernels and white wheat bread on the rate of gastric emptying and postprandial glucose response in healthy subjects.