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41.
T. X. Chu A.-V. Salsac D. Barthès-Biesel L. Griscom F. Edwards-Lévy E. Leclerc 《Microfluidics and nanofluidics》2013,14(1-2):309-317
We have designed a microfluidic system that enables both the fabrication of calibrated capsules and the in situ characterization of their mechanical properties. The fabrication setup consists of a double flow-focusing system. A human serum albumin aqueous solution is introduced in the central channel of a first Y-junction. Intercepted by the lateral flows of a hydrophobic phase, it is dispersed into microdroplets. A cross-linking agent is then introduced at a second Y-junction allowing a membrane to form around the droplets. The time of cross-linking is controlled by the length of a wavy channel located downstream of the second junction. A cylindrical microchannel finally enables to deform and characterize the capsules thus formed. The mechanical properties of the capsule membrane are obtained by inverse analysis. The results show that the drop size increases with the flow rate ratio between the central and lateral channels. The mean shear modulus of the capsules fabricated after 23 s of cross-linking is of the order of the surface tension between the two phases indicating that a reaction time of 23 s is too short for an elastic membrane to form around the droplet. When the cross-linking time is increased to 60 s, the microcapsules surface is wrinkled, thus confirming that a solid membrane is formed around the drop. The mean shear modulus of the capsule membrane increases with the cross-linking time, which is in agreement with our previous chemical results and proves that a fine control of the mechanical properties is possible by choosing adequately the control parameters of the system. 相似文献
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Entwicklung eines optisch zugänglichen Reaktors zur Thermographiemessung in einer Katalysatorschüttung 下载免费PDF全文
To measure the microkinetics in heterogeneously catalyzed strongly exothermic gas phase reaction heat and mass transfer limitations should be excluded. Also an unequal distribution of temperature in the catalyst fixed bed, like a hot spot, distorts the results of microkinetic investigations. A promising approach to measure the temperature contactless is thermography. For this work, an optically accessible reactor is developed to measure the temperature in a catalytically powder fixed bed. In the scope of this work, this technique is used to investigate the temperature development and distribution during the exothermal CO2 methanation depending on the bed and gas dilution and the reactor performance. 相似文献
45.
James A. Birrell Kathrin Wrede Krzysztof Pawlak Patricia Rodriguez-Maciá Olaf Rüdiger Edward J. Reijerse Wolfgang Lubitz 《Israel journal of chemistry》2016,56(9-10):852-863
Hydrogenases catalyze the reduction of protons and oxidation of molecular hydrogen with high turnover frequencies and low overpotentials under ambient conditions. The heterodimeric [FeFe] hydrogenase from Desulfovibrio desulfuricans has an exceptionally high activity, and can be purified aerobically in an oxygen-stable inactive state. Recently, it was demonstrated that monomeric [FeFe] hydrogenases produced recombinantly in Escherichia coli can be artificially maturated by simply incubating the inactive “apo” enzymes with the synthetic [2Fe] cofactor mimic [Fe2(adt)(CO)4(CN)2]2−. Here, we use the same technique to produce the heterodimeric “apo” hydrogenase from D. desulfuricans in E. coli with a high yield and purity, and maturate the “apo” enzyme with [Fe2(adt)(CO)4(CN)2]2− to generate fully active “holo” enzyme. Interestingly, the rate of the artificial maturation process with D. desulfuricans is significantly slower than that for all other hydrogenases tested so far. The artificially maturated enzyme is spectroscopically and electrochemically identical to the native enzyme and shows high rates of hydrogen production (3700 s−1) and hydrogen oxidation (63,000 s−1). We expect that our highly efficient production method will facilitate future studies of this enzyme and other related [FeFe] hydrogenases from Desulfovibrio species. 相似文献
46.
Michael Herrmann Ulrich Frter‐Barth Manfred A. Bohn Horst Krause Michael Koch Werner Arnold 《Propellants, Explosives, Pyrotechnics》2015,40(6):880-885
Non‐destructive X‐ray diffraction techniques were applied in order to monitor the influence of mechanical and shock‐loading on the microstructure of the plastic‐bonded high explosive KS32. The investigations uncovered damage to embedded coarse HMX crystals and to the binder system HTPB‐IPDI. Damage to the crystals occurred already during the kneading process in terms of deformation twinning. On higher loading between 400 MPa (static) and 480 MPa (dynamic) also crystal fracture was observed. The change in the binder structure was found after both static and dynamic loading, but not in the cured, differently kneaded samples. Moreover, the change in binder structure after dynamic loading was verified by dynamic mechanical analysis, and interpreted as a partial damage of the binder rubber shell around the explosive particles. The results are compared to literature data from imaging techniques. 相似文献
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Eckhart Nietzschmann Olaf Bge Alfred Tzschach 《Advanced Synthesis \u0026amp; Catalysis》1991,333(2):281-284
Ultrasound-induced Synthesis of Trimethylsilylacetic Acid Trimethylsilylester . The reaction of bromoacetic acid trimethylsilylester with zinc in presence of chlorotrimethylsilane is promoted by sono-waves. The trimethylsilylacetic acid trimethylsilylester could be obtained in high yield. Different products are observed in presence of dichloro dimethylsilane. Mechanical aspects are discussed. 相似文献
49.
New concepts for the utilisation of residual products from food industry - Prospects for the potato starch industry. In disposed waste are quite a lot of reusable substances of high value. These residual products can be transferred into commercial products in dependency to the adequate technology either as raw material for secondary processes, as operating supplies or as ingredients of novel products. Numerous valuable substances in food production are suitable for separation and recycling at the end of their life cycle even though present separation and recycling processes are not absolutely cost saving. Based on a concept of food production in its entirely the actual state is exemplary demonstrated at the potato starch industry in its occurrence, quantity and utilisation of the residual products. The target state of a clean production process will be realised by the development of multifunctional food ingredients. The outlined concept can be naturally transferred to several areas of industrial food production. The intentions of this research area are located at the development of techniques, which fulfil the conditions of environmental protection with costs to a minimum. 相似文献
50.
厌氧氨氧化技术用于高氨废水脱氮 总被引:1,自引:0,他引:1
在简要介绍厌氧氨氧化菌生理生化特性的基础上,总结了目前应用厌氧氨氧化的主要工艺及其工程实例,重点分析了厌氧氨氧化技术在处理高氨废水实际工程应用过程中需要解决的关键技术,为厌氧氨氧化技术在污水处理工程中的推广提供技术借鉴. 相似文献