Taming the killer in the kitchen: mitigating household air pollution from solid-fuel cookstoves through building design

In this study, we attempt to mitigate household air pollution (HAP) through improved kitchen design. Field surveys were conducted in ten kitchens of rural western India, which were then modelled and simulated for dynamic indoor airflow network analysis. The simulated results were statistically clustered using principal component analysis and hierarchical agglomerative clustering, to construct a cumulative built environment parameter called ‘Built Factor’ for each kitchen, and subsequently a derivative matrix was developed. Categorization of better performing kitchens from this derivative matrix enabled in deriving the built parameter thresholds for a ‘better’ kitchen design. This derived kitchen showed 60 % reduction in PM2.5 peak concentration during cooking hours. The evaluation described here is essentially a “proof of concept”, that effective building design can be an alternative way to reduce HAP without the introduction of chimneys, improved cookstoves or shifting to cleaner fuel.     

Greenhouse gases mitigation by CO<Subscript>2</Subscript> reforming of methane to hydrogen-rich syngas using praseodymium oxide supported cobalt catalyst

This study focuses on the potential of hydrogen-rich syngas production by CO₂ reforming of methane over Co/Pr₂O₃ catalyst. The Co/Pr₂O₃ catalyst was synthesized via wet-impregnation method and characterized for physicochemical properties by TGA, XRD, BET, H₂-TPR, FESEM, EDX, and FTIR. The CO₂ reforming of methane over the as-synthesized catalyst was studied in a tubular stainless steel fixed-bed reactor at feed ratio ranged 0.1–1.0, temperature ranged 923–1023 K, and gas hourly space velocity (GHSV) of 30,000 h^?1 under atmospheric pressure condition. The catalyst activity studies showed that the increase in the reaction temperature from 923 to 1023 K and feed ratio from 0.1 to 1.0 resulted in a corresponding increase in the reactant’s conversion and the product’s yields. At 1023 K and feed ratio of 1.0, the activity of the Co/Pr₂O₃ catalyst climaxed with CH₄ and CO₂ conversions of 41.49 and 42.36 %. Moreover, the catalyst activity at 1023 K and feed ratio of 1.0 resulted in the production of H₂ and CO yields of 40.7 and 40.90 %, respectively. The syngas produced was estimated to have H₂:CO ratio of 0.995, making it suitable as chemical building blocks for the production of oxygenated fuel and other value-added chemicals. The used Co/Pr₂O₃ catalyst which was characterized by TPO, XRD, and SEM-EDX show some evidence of carbon formation and deposition on its surface.     

Application of fuzzy quality function deployment for sustainable design of consumer electronics products: a case study

With a steep increase in the demand for consumer electronics products, the contemporary manufacturers are committed toward sustainable development of such products. There exists a scope for developing a methodology for enabling sustainable development of consumer electronics products. In this context, fuzzy quality function deployment (QFD) approach has been presented in this article in order to prioritize relevant customer requirements, sustainability parameters and sustainability initiatives. Key influential parameters for sustainable development of consumer electronics products have been identified from the literature. In the first phase of fuzzy QFD, parameters influencing sustainable development have been prioritized in accordance with customer requirements. In the second phase, environmental design initiatives have been prioritized based on critical sustainability parameters. From phase I of fuzzy QFD, ‘reduction in environmental release’ has been found as the most significant sustainability parameter with a crisp value of 22.83, and from phase II, environmental impact assessment is proved to be the significant design method with a crisp value of 20.40. The methodology would provide a comprehensive understanding to practitioners on the interrelationships among customer requirements, sustainability parameters and environmentally benign initiatives for development of consumer electronic products. The generic model developed can be applied to most of the consumer electronics product     

Estimating vulnerability to risks: an application in a biofuel supply chain

In the present work, we propose a theoretical model to identify and prioritize risks involved in a biofuel supply chain. We adopt a set of indicators associated with determinant factors of the supply chain to identify risks that are characterized through a risk matrix. We consider the five largest world biodiesel producers and included China due to its global market importance and potential impacts of its growth on the environment and society. To determine the impacts and the probability of occurrence of risks, we use the Canberra distance, as metrics. To facilitate the analysis and interpretation, a convenient manner is to express the results in terms of matrices. To exemplify the potentiality of the scheme and for the sake of simplicity, a more comprehensive discussion is focused on the Brazilian case, restricted to the Technology and Innovation, and Integration, Logistics and Infrastructure determining factors (dimensions) of the biodiesel supply chain. Concerning these determining factors, the Brazilian biodiesel chain shows strong vulnerability when compared with developed and developing countries, despite that the evolution of the data over recent years indicates small improvements in Integration, Logistics and Infrastructure dimension. Although in this work the calculations are restricted to the Canberra distance, the present approach may be applied to other distances to compare or validate the results. This work presents a contribution to model vulnerability to risks, providing to policy makers and stakeholders a tool to design, analyze and improve sustainability system by measuring its risks. The study of the contribution of each indicator suggests corrections to be taken and which indicators should be prioritized.     

Optimization of sodium sulfide treatment of rice straw to increase the enzymatic hydrolysis in bioethanol production

The efficiency of sodium sulfide-assisted alkaline pulping for cellulose preparation from Oryza sativa L. rice straw in Vietnam for enzymatic saccharification was investigated. The response surface methodology was used for the determination of optimal technological parameters of alkaline pulping such as active alkali dosage, temperature and time. The optimal technological parameters were established to be active alkali dosage of 7%, treatment temperature of 100 °C and treatment time of 120 min. At these regimes, a maximal sugar yield of 51.8% (over dry rice straw) was obtained. It meant that the saccharification efficiency up to 97.1% could be achieved by using sodium sulfide-assisted alkaline pretreatment method. Addition of sodium sulfide into alkaline pretreatment resulted in higher sugar yield, higher level of depolymerization of lignin and less loss of cellulose. Moreover, liquid hydrolyzate after enzymatic hydrolysis was analyzed by HPLC to determine the compositions of sugar mixture. The fiber morphology in pretreated biomass solid was also revealed by SEM.     

How can Cleaner Production practices contribute to meet ISO 14001 requirements? Critical analysis from a survey with industrial companies

The companies’ needs to adopt changes in their way of production to maximize the environmental performance required by their stakeholders, and at the same time, to maximize their economic and market performance, have made them seek for environmental strategies and certifications. In this sense, the Cleaner Production and the Environmental Management System based on ISO 14001 have been, respectively, presented, since the main objective of this research is to identify and analyze Cleaner Production contributions to comply with ISO 14001 requirements. For such, a survey research has been carried out in Brazilian industrial companies certified by ISO 14001. We have identified the main performance factors by leading practices and variables of Cleaner Production that contribute to the compliance with the standard requirements by companies. Thus, it has been noted that Cleaner Production is an important strategy for the preparation of companies for certification as well as for improving their environmental performance.     

Value recovery from end-of-use products facilitated by automated dismantling planning

Circular economy is a promising business model that promotes sustainable development by closing material loops. Making progress toward a circular economy requires the recovery of valuable materials and components from end-of-use products and subsequent reuse of them in some form, thus maximizing the utility of components and materials. Currently, end-of-use products value recovery is carried out without a rational planning, causing the loss of the recoverable value embedded in material and components. To address this problem, dismantling planning and appropriate technologies should be employed to improve the economic performance of end-of-use products value recovery. In this paper, a two-stage dismantling planning method is proposed to find a profitable end-of-use strategy. In the first stage of this method, disassembly optimization model is constructed and can be executed to obtain the optimal disassembly plan allowing maximum preservation of component function value, in a preservative disassembly scenario. To speed up the modeling, a method for automatic generation of AND/OR graph—a structure of incorporating all possible disassembly operations and associated subassemblies, is presented. In the second stage of the method, in order to increase profitability, Pareto analysis is employed to identify bottlenecks to disassembly and automated/destructive technologies are considered to remove the bottlenecks. A hard disk drive serves as a case study to illustrate the suggested method.     

Investigation of deep drawing concept of multi-point forming process in terms of prevalent defects

Multi-point forming is a novel flexible process that is economically suitable for both rapid prototyping and batch production of sheet metal parts. This technique is established based on altering rigid dies by matrices of adjustable punch elements. In this paper, the basic principle of this technique is implemented on deep drawing process. A reconfigurable die was constructed to investigate the multi-point deep drawing process. AA 2024-O Aluminum alloy was designated as test material. The formed specimens were evaluated in terms of dimpling defect, rupture, thickness distribution and dimensional accuracy. The onset of rupture was predicted by integrating the forming limit diagram of employed material with finite element Code. The predicted results were in a reasonable agreement with the experimental tests. It was found that for complete elimination of dimpling defect and acquiring maximum drawing depth, the proper allocation of elastic layer parameters such as thickness and hardness was crucial. The conducted investigations indicated that, in general, dimensional accuracy of formed parts was acceptable. However, for areas with sharp changes in geometry such as corners and side walls, deviation from desired geometry was evident. This phenomenon was remarkably dominant for manufactured parts utilizing softer elastic layer.     

Inverse analysis procedure to determine flow stress and friction data for finite element modeling of machining

This paper describes an inverse procedure to determine the constitutive constants and the friction conditions in the machining processes using Finite Elements (FE) simulations. In general, the FE modeling of machining processes is an effective tool to analyze the materials machinability under different cutting conditions. However, the use of reliable rheological and friction models represents the basis of a correct numerical investigation. The presented inverse procedure was based on the numerical results obtained using a commercial FE code and was developed considering a specific optimization problem, in which the objective functions that have to be minimized is the experimental/numerical error. This problem was performed by a routine developed in a commercial optimization software. In order to verify the goodness and the robustness of the methodology, it was applied on a Super Duplex Stainless Steel (SDSS) and on an Austenitic Stainless Steel (AUSS) orthogonal machining processes. This work, then, was focused on the identification of the Johnson-Cook (JC) coefficients (A,B,C, n and m) and on the calibration of a Coulomb friction model, in the specific cases of the SAF2507 SDSS and of an AISI 316 Based AUSS Alloy (AISI 316 ASBA). The identification phases were performed considering forces and temperatures experimental data, collected in two specific experimental tasks in which different orthogonal cutting tests were carried out under different cutting parameters conditions.     

Thermal modeling in electricity assisted incremental sheet forming

A thermal model was built to account for the effects of geometrical parameters of sheet specimen, process parameters and material parameters on the temperature increase of the sheet specimen in Electricity-Assisted Incremental Sheet Forming (EISF). In the EISF, the local area of sheet specimen contacting with a forming tool is heated by direct current, which flows through the forming tool to the sheet specimen. EISF experiments of two high strength steel sheets were carried out to validate the thermal model. The thermal model can be integrated into the control program of EISF system to achieve more accurate temperature control.