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81.
Hiroyuki Ikawa Hiromasa Shimojima Kazuyori Urabe Osamu Fukunaga 《Journal of the American Ceramic Society》1991,74(8):1899-1904
Axial and dilatometric thermal expansions and phase transformations were studied for solid solutions having the α-PbO2 structure in the ZrTiO4 —In2 O3 —M2 O5 (M = Sb, Ta) system with nominal formulas of Zr x Ti y In z Sb z O4 and Zr x Ti y In z Ta z O4 where x + y + 2 z = 2. With increased substitution of z , the cell volume increased, the difference in the b parameters at room temperature between those quenched from 1400° and 1000°C decreased, and the thermal expansion decreased. The axial thermal expansion of ZrTi y In z · Ta z O4 with z = 0.3 was almost identical with that of HfTiO4 , and those with z = 0.4 and z = 0.45 were smaller than that of HfTiO4 . Unit-cell volumes of these compound were compared with those of single oxides to make it clear that the unit-cell volume of ZrTiO4 was small anomalously and to distinguish the normal and abnormal substitution systems. These results were explained by the working hypothesis proposed for these compounds. 相似文献
82.
Summary This paper describes the so-called No Catalyst Copolymerization between dioxo-1,1-thiazetidine-1,2(Ethanesultam; ESm) and 2-methyl-2-oxazoline. The copolymerization took place without any added initiator to produce copolymers of MeOZO and ESm. The structure of the copolymer was determined by the IR and NMR spectra, elemental analysis, as well as by the result of an alkaline hydrolysis of the copolymer. The reaction scheme of the copolymerization via zwitterion mechanism (Eq 3–5) was proposed. 相似文献
83.
Keiji Mimura Susumu Yukawa Yoshio Mori Kazuya Okada Masatoshi Mune Osamu Nishikawa Akira Hibino Miyahiko Sonobe Tetuya Goto Hiroshi Nomoto 《Lipids》1991,26(12):1102-1107
We investigated the effect of platelet-activating factor (PAF) and of the PAF specific antagonist CV-6209 on plasma lipid
metabolism, and particularly on post-heparin plasma lipolytic activity in male Wistar rats. Lipoprotein lipase (LPL) activity
was enhanced by intravenous injection of PAF before intravenous injection of heparin when the PAF dose was low (0.2 μg/kg).
PAF activated hepatic triacylglycerol lipase (HTGL) activity dose-dependently. Plasma triacylglycerols (TG) significantly
decreased with the activation of LPL and/or HTGL. Plasma total cholesterol (TC) and phospholipid (PL) levels decreased at
a low dose of PAF (0.2 μg/kg), but increased when higher doses were used. The PAF antagonist CV-6209 partially reversed the
PAF induced effects on HTGL, TC and PL.
Based on a paper presented at the Third International Conference on Platelet-Activating Factor and Structurally Related Alkyl
Ether Lipids, Tokyo, Japan, May 1989. 相似文献
84.
Shingo Hirano Masaru Yoshinaka Ken Hirota Osamu Yamaguchi 《Journal of the American Ceramic Society》1996,79(1):171-176
In the ZrO2 -Cr2 O3 system, metastable t -ZrO2 solid solutions containing up to 11 mol% Cr2 O3 crystallize at low temperatures from amorphous materials prepared by the hydrazine method. The lattice parameter c decreases linearly from 0.5149 to 0.5077 nm with increased Cr2 O3 content, whereas the lattice parameter a is a constant value ( a = 0.5077 nm) regardless of the starting composition. At higher temperatures, transformation (decomposition) of the solid solutions proceeds in the following way: t (ss)→ t (ss) + m + Cr2 O3 → m + Cr2 O3 . Above 11 mol% Cr2 O3 addition, c-ZrO2 phases are formed in the presence of Cr2 O3 . The t -ZrO2 solid solution powders have been characterized for particle size, shape, and surface area. They consist of very fine particles (15–30 nm) showing thin platelike morphology. Dense ZrO2 (3Y)-Cr2 O3 composite ceramics (∼99.7% of theoretical) with an average grain size of 0.3 μm have been fabricated by hot isostatic pressing for 2 h at 1400°C and 196 MPa. Their fracture toughness increases with increased Cr2 O3 content. The highest K Ic value of 9.5 MPa·;m1/2 is achieved in the composite ceramics containing 10 mol% Cr2 O3 . 相似文献
85.
Tsunehiro Aki Kazutaka Hachida Megumi Yoshinaga Yuko Katai Takashi Yamasaki Seiji Kawamoto Toshihide Kakizono Takashi Maoka Seiko Shigeta Osamu Suzuki Kazuhisa Ono 《Journal of the American Oil Chemists' Society》2003,80(8):789-794
Thraustochytrids, marine protists whose dominant genera are Thraustochytrium and Schizochytrium, belong to the kingdom Chromista and are known as an industrial source of DHA. We describe here that thraustochytrid strain
KH105, isolated as a DHA producer, also accumulates significant levels of β-carotene and xanthophylls including canthaxanthin
and astaxanthin. A4-d cultivation using a medium composed of 10% glucose and less than 0.3% of nitrogen sources in a half-concentration
of seawater gave an astaxanthin production up to 6.1 mg/L, and canthaxanthin content reached more than 10 mg/L under conditions
where a higher concentration of nitrogen sources (6%) was employed. It might be advantageous in mass production systems for
these carotenoids to be extracted readily by simply suspending the cells with organic solvents such as acetone and chloroform.
Analyses on the morphological and life history features of the KH105 strain revealed that it belongs to the genus Schizochytrium. This particular species of thraustochytrids is thus considered to be a promising source of xanthophylls as well as DHA for
use in the food industry. 相似文献
86.
Stress distributions and deformation of adhesive butt joints are analyzed by an elastoplastic finite element method when the joints of similar and dissimilar shafts are subjected to external bending moments. The effects of the ratio of Young's modulus for the adherends to that for an adhesive and the effects of the adhesive thickness on the interface stress distribution are investigated. Joint strength is predicted by using the elastoplastic interface stress distributions. It is found that the singular stress at the edge of the interfaces increases with an increase of the ratio of Young's modulus. Measurement of strains in joints and experiments on joint strength were conducted. The numerical results are in fairly good agreement with the experimental results. It is observed that the joint strength for dissimilar shafts are smaller than those for similar shafts. A fracture of dissimilar adhesive up-bonded shafts occurred from the interface of the adherend with smaller Young's modulus. It is seen that joint strength increases as the adhesive thickness increases. 相似文献
87.
Keiji Kobayashi 《Journal of the American Ceramic Society》1990,73(11):3500-3502
F− - and OH− -free ZnO-B2 O3 -SiO2 -Al2 O3 -P2 O5 glasses used for semiconductor-device passivation or insulation are investigated with regard to compositional dependencies for thermal expansion, viscosity points, and metal oxide semiconductor (MOS) capacitor properties. The experimental data show that thermal expansion increases, and flow points decrease, when P2 O5 is substituted for B2 O3 . MOS capacitors passivated by OH− - and F− -free ZnO-based glasses exhibit normal capacitance-voltage curves. 相似文献
88.
A new procedure has been developed to measure the temperature distribution of the polymer melts along the screw axis during injection by using a small sheath thermocouple. At the same time, the effects of molding conditions on temperature distribution has been studied. The temperature distribution of the polymer melt along the screw axis during injection can be obtained from the difference between the standard temperature profile and the temperature profile of the polymer melt with unknown and non-uniform temperature measured under the same rate of injection. The temperature of a polymer melt within a shot is not uniform. The difference between the maximum and the minimum temperature within a shot may exceed 10°C in some cases. There are two major factors which govern the effects of molding conditions on the temperature distribution of the polymer melts during injection. The first is the amount of shear heating in the metering zone. The second is the amount of heat absorbed into the polymer in the compression and feed zones. 相似文献
89.
Shin-ichiro Sekimiya Eikoh Kobayashi Nobukatsu Nemoto Yukihiko Ueno Koji Ikeda Nobuo Takamiya 《Polymer Bulletin》1991,27(1):37-40
Summary Liquid crystalline side-chain polysiloxanes were prepared without metal complex catalyst. Mesogenic groups such as cholesteryl, 4-cyano-4-biphenyl and 4-methoxy-4-biphenyl group were introduced into polysiloxane by esterification and from DSC measurements they were compatible with other liquid crystalline polysiloxanes reported previously. 相似文献
90.
The formation of lead tantalates in the PbO-rich region is studied using the powders prepared by the simultaneous hydrolysis of lead and tantalum alkoxides. Cubic 3PbO · 2Ta2O5 solid solutions crystallize at low temperatures from amorphous materials between 60 and 75 mol% PbO. The lattice parameter,a, increases linearly from 1.0545 to 1.0705 nm with increasing PbO. At higher temperatures the solid solutions above 66.67 mol% PbO are transformed into those of rhombohedral 2PbO · Ta2O5. Rhombohedral 5PbO · 2Ta2O5 is formed at 850 to 900 °C by transformation of 2PbO·Ta2O5 solid solution corresponding to 71.43 mol% PbO. The existence of previously reported 3PbO·Ta2O5 is not confirmed. 相似文献