Relationships between acute toxicities of para nitrophenol (p-NP) and nitrobenzene (NB) to Daphnia magna and Photobacterium phosphoreum: physicochemical properties and metabolites under anaerobic/aerobic sequentials

In this study, the acute toxicities of nitrobenzene (NB) and para nitrophenol (p-NP) were investigated in a high rate sequential anaerobic migrating blanket (AMBR)/aerobic completely stirred tank reactor (CSTR) using Microtox and Daphnia magna tests. After sequential anaerobic and aerobic treatments, the inhibitions in the Microtox bacteria decreased from an initial 78.10-48.20% and 4.00%, respectively, in wastewater containing 40.00 mg/L p-NP. The inhibitions of the influent wastewater containing 60.00 mg/L NB decreased from 72.10% to 45.30% and to 4.00% after anaerobic and aerobic treatment, respectively. The acute toxicity removals were 94% and 93% in the effluent of the whole sequential system, for p-NP and NB, respectively. The acute toxicity in the influent was dependent on the parent NB and p-NP concentrations and ons their physicochemical properties such as hydrophobicity, octanol/water partition coefficient and vapour density for both Microtox bacteria and Daphnia magna while the toxicity in the effluent of the anaerobic reactor was strongly dependent on the metabolites of p-NP (p-amino phenol, phenol, NH(4)-N) and NB (aniline) for Microtox test. This effluent was not toxic to Daphnia magna.     

Decolorization of malachite green, decolorization kinetics and stoichiometry of ozone-malachite green and removal of antibacterial activity with ozonation processes

This study aimed to identify degradation intermediates and to investigate the stoichiometry of decolorization and degradation, decolorization kinetics, and removal of antibacterial activity of malachite green (MG) using ozonization processes. The decolorization of MG was optimal at an acidic pH value of 3 based on molecular ozone attack on MG molecules. The stoichiometric ratio of decolorization between ozone and MG was calculated to be 7.0 with a regression coefficient of 0.995, whereas the ratio for degradation was calculated as 13.1 with a regression coefficient of 0.998. With MG concentrations in the range of 0.30-1.82 mM, the concentration of decolorized MG increased with higher initial concentrations of MG, whereas the ozonolytic decolorization rates of MG, decreased with increasing initial concentration. The pseudo-first-order degradation rate constants (k') decreased with the initial concentration and ranged from 0.769 to 0.223 min(-1). Twelve different intermediates were produced during the ozonation of MG with ozonation times between 5 min and 30 min and were identified by GC-MS. Although 86% of MG in the reaction mixture was removed by ozonation after 10 min, the decrease of antibacterial activity was very low (10%) for Bacillus subtilis and Staphylococcus epidermidis because the degradation intermediates, phenol and benzoic acid, also have antibacterial activity. The antibacterial activity of both MG and its intermediates were removed successfully with ozonation times above 26 min.     

Is there any interaction of resistin and adiponectin levels with protein‐energy wasting among patients with chronic kidney disease

The aim of this study was to evaluate the effects of adipocytokines including adiponectin, leptin, resistin, neuropeptide Y and ghrelin in chronic kidney disease (CKD) patients on appearance of protein‐energy wasting (PEW). One hundred fifty patients with mean age of 45.4 ± 15.9 years, without active infections or chronic inflammatory conditions were recruited into the study. Study groups were control group (consisting of 30 healthy volunteers with normal kidney functions), hemodialysis group, predialysis group, peritoneal dialysis group and kidney transplant group. Fasting morning serum leptin, ghrelin, acylated ghrelin, neuropeptide Y, adiponectin, resistin levels of all of the groups were measured. Anthropometric and nutritional assessments of all patients were obtained. Diagnosis of PEW was made according to definition recommended by the International Society of Renal Nutrition and Metabolism. Presence of PEW in hemodialysis (23.3%) and peritoneal dialysis (26.7%) groups were significantly higher than those of predialysis (3.3%), and transplantation (0%) groups. Adiponectin and resistin levels in predialysis, peritoneal dialysis and hemodialysis patients were significantly higher than control group (p: 0.0001). This study had given significant positive correlations between presence of PEW and serum resistin (r: 0.267, p: 0.001), and serum adiponectin levels (r: 0.349, p: 0.0001). There were no relationship between presence of PEW and ghrelin, acylated‐ghrelin, neuropeptide Y, and leptin levels of the groups. CKD patients except transplant patients had higher adiponectin and resistin levels than control group. PEW was found to be linearly correlated with resistin and adiponectin. High serum resistin and adiponectin levels might have a role in development of PEW among dialysis patients.     

An Automated Ultrasonic NDT System for In-Situ Inspection of Wind Turbine Blades

It is crucial to maintain wind turbine blades regularly, due to the high stress leading to defects or damage. Conventional methods require shipping the blades to a workshop for off-site inspection, which is extremely time-consuming and very costly. This work investigates the use of pulse-echo ultrasound to detect internal damages in wind turbine blades without the necessity to ship the blades off-site. A prototype 2D ultrasonic NDT （non-destructive testing） system has been developed and optimised for in-situ wind turbine blade inspection. The system is designed to be light weight so it can be easily carried by an inspector onto the wind turbine blade for in-situ inspection. It can be operated in 1D A-scan, 2D C-scan or 3D volume scan. A software system has been developed to control the automated scanning and show the damage areas in a 2D/3D map with different colours so that the inspector can easily identify the defective areas. Experiments on GFRP （glass fibre reinforced plastics） and wind turbine blades （made of GFRP） samples showed that internal defects can be detected. The main advantages of this system are fully automated 2D spatial scanning and the ability to alert the user to the damage of the inspected sample. It is intended to be used for in-situ inspection to save maintenance time and hence considered to be economically beneficial for the wind energy industry.     

Liquefaction Potential Index: Field Assessment

Cone penetration test (CPT) soundings at historic liquefaction sites in California were used to evaluate the predictive capability of the liquefaction potential index (LPI), which was defined by Iwasaki et al. in 1978. LPI combines depth, thickness, and factor of safety of liquefiable material inferred from a CPT sounding into a single parameter. LPI data from the Monterey Bay region indicate that the probability of surface manifestations of liquefaction is 58 and 93%, respectively, when LPI equals or exceeds 5 and 15. LPI values also generally correlate with surface effects of liquefaction: Decreasing from a median of 12 for soundings in lateral spreads to 0 for soundings where no surface effects were reported. The index is particularly promising for probabilistic liquefaction hazard mapping where it may be a useful parameter for characterizing the liquefaction potential of geologic units.     

Polytetrahydrofuran macroinimer

Summary Polytetrahydrofuran macroinimers were synthesized by means of cationic polymerization of tetrahydrofuran, initiated by azo-oxocarbenium salt, followed by termination with methacrylate anion. The macroinimers were characterized by ¹H-NMR analysis and GPC measurements. Self polymerization of macroinimers and copolymerization with methyl methacrylate (MMA) yielded crosslinked and soluble branched block copolymers depending on the MMA concentration.     

Structural health monitoring system of the long-span bridges in Turkey

Abstract

This study presents the general features of the structural health monitoring (SHM) system of the long-span cable-supported bridges in Turkey, namely the First Bosphorus Bridge, the Second Bosphorus Bridge (Fatih Sultan Mehmet Bridge), the newly constructed the Third Bosphorus Bridge (Yavuz Sultan Selim) and the Osman Gazi Bridge (Izmit Bay Bridge). Due to the critical function of the bridges in the transportation networks of Istanbul, structural health under extreme and operational load cases without interruption of their operation is essential. The SHM systems are already available and in use for the First and Second Bosphorus Bridges; however, the Yavuz Sultan Selim and the Osman Gazi Bridges, only have the preliminary SHM systems established. General preferences of the current and planned SHM systems of the bridges are given based on the monitoring objectives and requirements. Data collected from the SHM systems are also exhibited as an illustration for structural modal identification of the First Bosphorus Bridge. Based on the experiences from the current SHM systems, future works and planning are recommended to effectively design new SHM system and to efficiently update the current ones.     

An Experimental Investigation on the Chemical Stability of Selected Formation and Determination of the Proper Type of Water-Base Drilling Fluids. Part 2. Test Results

The objective of this study was to select the proper drilling fluid type and composition for drilling stable holes through the problems of the selected formations. This study was performed on shale samples taken from 10 wells in which hole instability was encountered to various extents during drilling the Germav formation. Both ionic and polymer inhibitions were utilized in formulating the proper drilling for the Germav formation. Ionic inhibition was obtained using KCl and NaCl. Polyanionic polymer (Pac-L) was used for providing the polymer encapsulation. Experimental results indicated that KCl is superior to NaCl in providing ionic inhibition. Both salts lowered the interaction between the drilling fluid and Germav formation, but better results were obtained with KCl. Minimum salt concentration up to 15% yields more inhibitive environment. Polymer inhibition tests indicated that minimum Pac-L concentration required for maintaining the polymer inhibition was about 2 lb/bbl for both systems. In conclusion, KCl/encapsulating polymer system seems to be the most proper water: base drilling fluid available for Germav formation achieving the required wellbore stability. The fluid loss and suspending properties of the proposed system must be controlled using the modified starch and XC polymer.     

Effects of sheet thickness and anisotropy on forming limit curves of AA2024-T4

In this study, the effects of sheet thickness and anisotropy of AA2024-T4 on forming limit curve (FLC) are experimentally investigated according to ISO 12004-2 standard. A new limit strain measurement method is proposed by using the grid analysis method so as to determine limit strains conveniently and reliably. In addition to the regular test specimens, various widths are added to enhance the FLC’s accuracy at the plane strain condition (PSC). The accuracy and reliability of the proposed method are verified for different materials. Results illustrate that an increase in the sheet thickness increases the FLC level. The additional experiments for additional widths improve the accuracy of the FLC at the PSC, and the position of the lowest major strain value differs from the literature. However, the effect of anisotropy on the FLC is found to be insignificant. Finally, experimental and numerical case studies are carried out for conventional deep drawing, stretch drawing, and hydraulic bulge processes. Results reveal that different FLCs are necessary for different thicknesses for accurate predictions.