Magnetic Force Microscopy in Liquids

In this work, the use of magnetic force microscopy (MFM) to acquire images of magnetic nanostructures in liquid environments is presented. Optimization of the MFM signal acquisition in liquid media is performed and it is applied to characterize the magnetic signal of magnetite nanoparticles. The ability for detecting magnetic nanostructures along with the well‐known capabilities of atomic force microscopy in liquids suggests potential applications in fields such as nanomedicine, nanobiotechnology, or nanocatalysis.     

Antioxidant activity and free radical-scavenging capacity of a selection of wild-growing Colombian plants

BACKGROUND: The replacement of some synthetic food antioxidants by safe natural antioxidants has fostered research on the screening of raw materials to find new vegetable sources of antioxidants. In this study the antioxidant activity of eight wild‐growing Colombian plants was assessed by four complementary assays. RESULTS: An evaluation of the antioxidant activity of ten ethanolic extracts from Baccharis chilco, Cinnamomum triplinerve, Ilex laurina, Lachemilla orbiculata, Lepechinia conferta, Quercus humboldtii, Rubus urticifolius and Tephrosia cinerea was carried out. Furthermore, the total phenolic content was determined by the Folin–Ciocalteu method, and the relationship between phenolic content and activity was also statistically investigated. Cinnamomum triplinerve, L. conferta and I. laurina were found to have the highest phenolic contents. Baccharis chilco, C. triplinerve, I. laurina, L. conferta, Q. humboldtii and R. urticifolius showed higher radical‐scavenging activity (DPPH and superoxide assays) than commercial rosemary oleoresin (reference). Lachemilla orbiculata and R. urticifolius showed higher antioxidant activity (β‐carotene‐bleaching test) than the reference. The protection factor of all studied plant extracts was below that of the reference according to the Rancimat test. CONCLUSION: On the basis of the results obtained, C. triplinerve, Q. humboldtii and R. urticifolius seem to be the most promising species for further investigation in order to identify the compounds responsible for their activity. Copyright © 2011 Society of Chemical Industry     

Influence of thermal treatment on the “in vitro” bioactivity of wollastonite materials

The aim of this work was to study the influence of the composition and thermal treatment of the in vitro bioactivity of wollastonite materials obtained by sol–gel method. For this purpose, gels in the system SiO₂–CaO were obtained applying calcium nitrate and tetraethoxysilicate as precursors. The gels were heated to 700°C and then sintered up to 1400°C. The bioactivity of the gel-derived materials in simulated body fluid (SBF) was investigated and characterized. Additional changes in ionic concentration, using inductively couple plasma atomic emission spectroscopy (ICP-AES), were determined. The results showed that all materials obtained were bioactive and indicate that the absence of phosphorous in the material composition is not an essential requirement for the development of a Hydroxyapatite layer. The bioactivity was influenced by the thermal treatment, the different phases (glass-phase, wollastonite and pseudowollastonite) as well as the porous size. On the gel-derived materials the bioactivity decreased with the sintering temperature.     

Modeling of mixed-mode crack growth in ductile thin sheets under combined in-plane and out-of-plane loading

This paper describes a modeling approach for analyzing mixed-mode crack growth events in ductile thin-sheet materials under large deformation and combined in-plane and out-of-plane loading conditions. The remote mixed-mode I/III loading leads to local mixed-mode I/II/III fields near the crack front. Making use of full-field surface deformation measurements, finite element models of mixed-mode I/III stable tearing events in thin-sheet specimens have been developed. Model predictions have been compared with experimental measurements (a) just prior to initial crack growth and (b) during stable tearing crack growth. Analyses of curvilinear crack growth events are carried out using a nodal release option or a local re-meshing option and using a generalized CTOD parameter with experimentally measured critical CTOD values. Results of this study suggest that the modeling approach can be employed to numerically re-construct experimental crack growth events in thin plate specimens. This offers a viable means of analyzing and understanding the mixed-mode crack growth events and provides a tool for further investigations of 3D crack front fields (which are otherwise unavailable experimentally) and for the study of fracture criteria for stable tearing events.     

Volatile composition of pomegranates from 9 Spanish cultivars using headspace solid phase microextraction

Fruits of 9 Spanish pomegranate cultivars were analyzed for quality parameters, volatile composition, and sensory profile. Volatile compounds were extracted using headspace solid phase micro-extraction (HS-SPME) and analyzed by gas chromatography-mass spectrometry (GC-MS) and flame ionization detector (GC-FID). Twenty-one compounds were found in the headspace of fresh pomegranate juices, including aldehydes, monoterpenes, and alcohols. The most abundant compounds were hexanal, limonene, trans-2-hexenal, and cis-3-hexenol. Fruits from the cultivars Mollar Elche(ME) ME14, ME1, and ME2 presented the highest values of overall liking by the consumer panel; however, their total volatiles concentration were low compared to the other pomegranate cultivars and their color intensity was intermediate. Overall consumer liking of pomegranate juices was mainly associated with the presence of monoterpenes (α-terpineol); however, high aldehydes (trans-2-hexenal) concentrations were correlated with poor overall consumer liking. Fruits from sour-sweet cultivars (PTO7 and ADO4) could improve the quality of ME pomegranate juices due to their intense color, high monoterpenes concentrations, and their moderate sourness. Practical Application: The information provided in this study proves that sour-sweet pomegranate fruits can be used in the manufacturing of pomegranate juices and will improve the sensory quality and the volatile composition of this product.     

Happiness versus sadness as a determinant of thought confidence in persuasion: A self-validation analysis.

The present research introduces a new mechanism by which emotion can affect evaluation. On the basis of the self-validation hypothesis (R. E. Petty, P. Bri?ol, & Z. L. Tormala, see record 2002-12575-003), the authors predicted and found that emotion can influence evaluative judgments by affecting the confidence people have in their thoughts to a persuasive message. In each study, participants first read a strong or weak persuasive communication. After listing their thoughts about the message, participants were induced to feel happy or sad. Relative to sad participants, those put in a happy state reported more thought confidence. As a consequence, the effect of argument quality on attitudes was greater for happy than for sad participants. These self-validation effects generalized across different emotion inductions, different persuasion topics, and different measures of thought confidence. In one study, happy and sad conditions each differed from a neutral affect control. Most important, these metacognitive effects of emotion only occurred under high elaboration conditions. In contrast, individuals with relatively low motivation to think showed a main effect of emotion on attitudes, regardless of argument quality. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Structure and bonding of ArClF: Intermolecular potential surface

The ground-state potential surface of the Ar-ClF complex is determined by restricted coupled-cluster with single and double excitations and a noniterative perturbation treatment of triple excitation (RCCSD(T)) calculations, using augmented correlation consistent basis sets supplemented with an additional set of midbond functions. Three local minima are found for the Ar-ClF, which correspond to linear Ar-Cl-F and Ar-F-Cl configurations and a near T-shaped structure. The well depths and the equilibrium distances are 283.62 cm⁻¹ at 3.84 Å and 128.96 cm⁻¹ at 4.31 Å for the linear ones and 173.13 cm⁻¹ at 3.58 Å for the one at θ = 107.5°. Bound-state calculations are carried out and the linear Ar-Cl-F structure is found to be the most stable one, in accordance with the experiment. Dissociation energies, intermolecular distances, and vibrational frequencies are computed and compared with available experimental data.     

Stock Market Response to Acquisitions and Alliances in the European Telecom Industry: An Information Asymmetry Perspective

This paper investigates two kinds of strategic combinations carried out by the European telecom operators between 1986 and 2001: acquisitions, on the one hand, and strategic alliances, on the other. The aim of the paper is twofold. First, it analyzes the behavior adopted by these companies to adapt to an environment that, after the processes of globalization and privatization presents a clearly different structure. Second, it focuses on the effect that internationalization and diversification could exert over the returns obtained by the European telecom firms involved in acquisitions and alliances, differentiating when such strategic combinations are more profitable for the shareholders of the firms that carry them out.     

Effects of JPEG2000 data compression on an automated system for detecting clustered microcalcifications in digital mammograms.

The functionalities of the JPEG2000 standard have led to its incorporation into digital imaging and communications in medicine (DICOM), which makes this compression method available for medical systems. In this study, we evaluated the compression of mammographic images with JPEG2000 (16 : 1, 20 : 1, 40 : 1, 60.4 : 1, 80: 1, and 106 : 1) for applications with a computer-aided detection (CAD) system for clusters of microcalcifications. Jackknife free-response receiver operating characteristic (JAFROC) analysis indicated that differences in the detection of clusters of microcalcifications were not statistically significant for uncompressed versus 16: 1 (T = -0.7780; p = 0.4370), 20 : 1 (T = 1.0361; p = 0.3007), and 40 : 1 (T = 1.6966; p = 0.0904); and statistically significant for uncompressed versus 60.4 : 1 (T = 5.8883; p < 0.008), 80 : 1 (T = 7.8414; p < 0.008), and 106 : 1 (T = 17.5034; p = < 0.008). Although there is a small difference in peak signal-to-noise ratio (PSNR) between compression ratios, the true-positive (TP) and false-positive (FP) rates, and the free-response receiver operating characteristic (FROC), figure of merit values considerably decreased from a 60 : 1 compression ratio. The performance of the CAD system is significantly reduced when using images compressed at ratios greater than 40 : 1 with JPEG2000 compared to uncompressed images. Mammographic images compressed up to 20 : 1 provide a percentage of correct detections by our CAD system similar to uncompressed images, regardless of the characteristics of the cluster. Further investigation is required to determine how JPEG2000 affects the detectability of clusters of microcalcifications as a function of their characteristics.