Effect of Inlet Conditions on Taylor Bubble Length in Microchannels

The effect of inlet conditions on the frequency and size of the bubbles that form during gas–liquid Taylor flow in microchannels is investigated in this paper. Three different inlet configurations, T-, Y-, and M- junction, and three test channels with hydraulic diameters 0.345 mm, 0.577 mm, and 0.816 mm were used. The test fluids were nitrogen and water or octane, which have different surface tensions. It was found that bubble length increased with increasing gas flow rate, gas inlet size, and liquid surface tension and with decreasing liquid flow rate. From the different inlet configurations, the M-junction resulted in the largest bubbles and the Y-junction in the smallest ones, particularly at low liquid flow rates. Bubble lengths calculated from experimental bubble formation frequencies were tested against a number of literature correlations but the agreement was not very good. Two new correlations were developed for the T- and the Y-junctions to calculate the unit cell (one bubble and one slug) frequency, from which the bubble length can be found. Bubble lengths predicted from these correlations were in good agreement with experimental ones obtained from video recordings.     

Determination of ochratoxin A in grapes of Greek origin by immunoaffinity and high-performance liquid chromatography

A simple analytical method for ochratoxin A (OTA) determination in grapes is described, using aqueous methanolic extraction, an immunoaffinity column clean-up step and high-performance liquid chromatography with fluorescence detection. Mean recovery was 94% (RSD = 4.0%) with a detection limit of 0.4 ng g^-1 and quantification limit of 1.20 ng g^-1. Repeatability (r) and reproducibility (R) were 1.17 and 1.34, respectively. OTA determinations were applied to 50 grape samples (23 different varieties) originating from representative regions of Greece. Results showed the presence of OTA in 86% of samples tested (n = 50). Traces were found in 56% of samples but OTA was not detectable in 14% of samples. Traces were also found in 4% of red, organically grown samples. The most contaminated were three samples of red grapes, two from Central Greece (2.69 and 1.41 ng g^-1), both table and wine-making grapes. The third sample (1.46 ng g^-1), originating from the island of Samos, was used only in wine-making. Mean (1.06 ng g^-1) and median (0.76 ng g^-1) OTA concentrations in red grapes were slightly higher compared to the mean (0.82 ng g^-1) and median (0.65 ng g^-1) concentrations in white grape samples. The study shows that the potential risk for a person of 60 kg ranged from 0.9 to 9 ng kg^-1 bw day^-1 and is dependent on the quantity of grapes consumed daily.     

Workplace and organizational accident causation factors in the manufacturing industry

Labor inspectors investigate accidents to identify possible accident causes, initiate prosecution, and plan future accident prevention. The Method of Investigation for Labor Inspectors (MILI) was designed to help them to identify workplace and organizational factors in addition to immediate factors and legal breaches. The present study analyzes the impact of workplace (work design and provision of unsafe equipment) and organizational factors (training and employee involvement) on accident causation and validates MILI on real accident cases. Accident data from the manufacturing sector are analyzed with LISREL structural equation modeling. Results confirm the relationship between work design and training as well as between provision of unsafe equipment and employee involvement. The present study provides evidence that MILI is a structured accident investigation method allowing multiple accident causation factors to be revealed and that it could help all interested parts (not only labor inspectors, but companies as well) to thoroughly investigate occupational accidents. © 2009 Wiley Periodicals, Inc.     

Dielectric relaxation phenomena and dynamics in polyoxymethylene/polyurethane/alumina hybrid nanocomposites

Ternary hybrid composites composed of polyoxymethylene (POM), polyurethane (PU) and boehmite alumina nanoparticles were produced by melt blending with and without latex pre‐compounding. PU latex pre‐compounding was employed for the fine dispersion of both the PU and alumina particles within the POM matrix. In this study the electrical properties of the POM/PU/boehmite alumina nanocomposites were examined by means of broadband dielectric spectroscopy over a wide temperature (?100 to 150 °C) and frequency (10^?1 to 10⁶ Hz) range. Data were analysed by means of the electric modulus formalism. The recorded relaxations include contributions from both polymers and the inorganic reinforcing phase. In the ternary hybrid systems five distinct relaxation processes were detected. Relaxations were assigned and interpreted by considering the morphology of the corresponding composite. In particular, they were attributed to the γ‐mode of POM and/or of PU, the α‐mode of PU, the α‐mode of POM and to the interfacial polarization process. Finally, the dynamics of all the recorded processes are examined and discussed. Copyright © 2011 Society of Chemical Industry     

Non-Repudiation By The Use of Biometrics—Risk Analysis

Abstract

A model is recommended for the provision of non-repudiation by the use of biometrics. A risk analysis of the recommended model is conducted in order to evaluate its feasibility and secure operation.     

Prediction of phase inversion in agitated vessels using a two-region model

Phase inversion in agitated vessels was studied using a two-region model. In this model, breakup and coalescence were assumed to take place in the vicinity of the impeller and away from that region, respectively. The mechanism of phase inversion was regarded as the result of an imbalance between the breakup and coalescence processes. Hence phase inversion was assumed to occur when the coalescence frequency exceeded that of breakup. In addition, the concept of a radial distribution function was adopted in the model in order to account for droplet coalescence in concentrated dispersions. Using the two-region model, the effect of interfacial tension, viscosity, density and impeller size on the width of the ambivalent range was investigated. The predictions agree well with experimental data particularly for the upper curve of the ambivalent range; however, the organic phase fraction of the lower curve is in some cases underestimated by the model.     

Low Inclination Oil‐water Flows

Two‐phase liquid flows at +5° inclination from the horizontal were studied experimentally for mixture velocities between 0.7 and 2.5 m/s and input oil fractions between 10% and 90%. The results were compared with a two‐fluid model that includes entrainment. The investigations were performed in a 38‐mm ID stainless steel test section, with water and oil as test fluids. Dual continuous flow (both phases remain continuous with inter‐dispersion) prevailed, while the two‐phase pressure gradient was found lower than the single‐phase oil or water. At low mixture velocities the velocity ratio increased with oil fraction while at high ones it decreased. Compared to horizontal flow, water holdup was higher and frictional pressure gradient lower.     

Production of activated carbon from agricultural by‐products

The production of activated carbon from agricultural by‐products is a research field of increasing interest as it deals with the problem of the disposal of agro‐residues, at the same time producing an added‐value product that can be used in a number of environmental applications. The paper presents an overview of the latest developments in processes for the production of activated carbon from agricultural by‐products, with emphasis on the methodology applied, the effect of critical process parameters such as retention time, temperature, chemical to material ratio, as well as the adsorbing capacity of the activated carbons produced in removing select compounds from synthetic and real wastewaters. Agricultural by‐products can be a source for activated carbon production with high surface areas and high adsorption capacity. Copyright © 2008 Society of Chemical Industry     

The anticoagulant activity of enoxaparin sodium during on-line hemodiafiltration and conventional hemodialysis

To study and compare the anticoagulant activity of enoxaparin sodium during on-line hemodiafiltration (OL-HDF) and conventional hemodialysis (C-HD). Enoxaparin was administered as an anticoagulant to 21 hemodialysis patients at the beginning of a single 4-hour OL-HDF session as an intravenous bolus dose of 80 mg/kg. On-line hemodiafiltration was performed using a high-flux polyester polymer alloy dialyzer and a total of 18 L replacement fluid (session A). One week later, the study was repeated in the same patients during a single 4-hour session of C-HD using a low-flux polysulfone dialyzer (session B). Blood samples for the measurement of Hb, blood urea and nitrogen (BUN), activated partial thromboplastin time (APTT), and anti-Xa levels were taken before each study session and 5-minute postdialysis. In 13 more patients, the same study was performed during OL-HDF using a high-flux polysulfone dialyzer (session C). No differences were found between sessions A, B, and C when predialysis values for Hb, BUN, APTT, and anti-Xa were compared. The mean postdialysis APTT and anti-Xa values were 32.5±3.8 seconds and 0.19±0.11 IU/mL, respectively, in session A, 39.0±5.0 seconds and 0.71±0.17 IU/mL in session B, and 33.8±3.1 seconds and 0.35±17 IU/mL in session C (A vs. B, P<0.0001, for both parameters, A vs. C, P<0.003 for anti-XA, and B vs. C, P<0.005, for both parameters). The anticoagulant activity of enoxaparin sodium is decreased significantly during a 4-hour OL-HDF session compared with to a similar session of C-HD. The degree of the reduction seems to depend on the dialyzer's membrane.     

Simulation of façade and envelope design options for a new institutional building

This paper presents a simulation case study of façade and envelope preliminary design options for the new Engineering building of Concordia University in Montreal. A major principle of the analysis was to create a high quality building envelope in order to optimally control solar gains, reduce heating and cooling energy demand and reduce electricity consumption for lighting, while at the same time maintain a comfortable and pleasant indoor environment. The stated approach of the design team was to aim for an energy-efficient building, employing innovative technologies and integrating concepts such as daylighting and natural ventilation. Detailed energy simulations were therefore performed from the early design stage, in order to present recommendations on the choice of façade, glazings, shading devices, lighting control options, and natural ventilation. Integrated thermal studies, a daylighting analysis and the impact of the above on HVAC system sizing were considered. Simulation results showed that, using an optimum combination of glazings, shading devices and controllable electric lighting systems, the energy savings in perimeter spaces can be substantial. Perimeter heating could be eliminated if a high performance envelope is used. The building is currently being commissioned.