Microprocessor controlled three-way catalyst efficiency monitoring system

The present paper describes a new design for a microcontrolled three-way catalyst efficiency monitoring system. The system is based on the Motorola 68HC11e2 microprocessor and utilizes the differential signal from a pair of thermocouples installed at the catalyst outlet and inlet sections. This signal is processed in real time using an appropriate statistical algorithm and the corresponding results are compared to experimentally determined limiting values to assess the current state of the catalyst efficiency during driving conditions. The result of this comparison is presented on an LCD display as an A, B, C, or FAIL catalyst condition signal. The system can be readily installed and can operate on new and used cars provided that the type of catalyst used has been experimentally tested to provide the necessary limiting values that characterize its relative levels of efficiency. It can also be reprogrammed and calibrated via a RS232C serial interface.     

Uniting bounded control and MPC for stabilization of constrained linear systems

In this work, a hybrid control scheme, uniting bounded control with model predictive control (MPC), is proposed for the stabilization of linear time-invariant systems with input constraints. The scheme is predicated upon the idea of switching between a model predictive controller, that minimizes a given performance objective subject to constraints, and a bounded controller, for which the region of constrained closed-loop stability is explicitly characterized. Switching laws, implemented by a logic-based supervisor that constantly monitors the plant, are derived to orchestrate the transition between the two controllers in a way that safeguards against any possible instability or infeasibility under MPC, reconciles the stability and optimality properties of both controllers, and guarantees asymptotic closed-loop stability for all initial conditions within the stability region of the bounded controller. The hybrid control scheme is shown to provide, irrespective of the chosen MPC formulation, a safety net for the practical implementation of MPC, for open-loop unstable plants, by providing a priori knowledge, through off-line computations, of a large set of initial conditions for which closed-loop stability is guaranteed. The implementation of the proposed approach is illustrated, through numerical simulations, for an exponentially unstable linear system.     

水化水泥颗粒表面超塑化剂吸附层分布模型

制备了钙矾石(AFt)、单硫型硫铝酸钙(AFm)和钾长石类单矿物,并研究了三聚氰胺磺酸盐甲醛缩聚物(PMS)、β-萘磺酸盐甲醛缩合物(BNS)及聚羧酸盐(PC)等几种化学成分不同的超塑化剂在其早期水化颗粒表面上的吸附行为.研究发现,zeta电位是决定水泥颗粒表面对超塑化剂吸附量的关键因素.以溶液沉淀析出法人工合成的AFt具有较高的正zeta电位,能吸附大量带负电荷的超塑化剂,AFm仅带少量正电荷,其吸附超塑化剂相对较少,钾长石、氢氧钙石和石膏的zeta电位几乎为零或负值,因而基本不吸附超塑化剂.根据实验结果,笔者认为水化水泥颗粒用马赛克结构表示为最佳,而超塑化剂主要吸附在AF表面上.     

Room‐Temperature Phase Demixing in Bulk Heterojunction Layers of Solution‐Processed Organic Photodetectors: the Effect of Active Layer Ageing on the Device Electro‐optical Properties

Herein, we address the reduction in the external quantum efficiency (EQE) of solution‐processed organic photodetectors caused by the room temperature phase demixing of components in the composite material of the photoactive layer. The reduction takes place under ambient conditions and after the completion of device fabrication. As a model system, we study photoactive blend films that consist of the electron acceptor N,N’‐bis(alkyl)‐3,4,9,10‐perylene tetracarboxylic diimide) (PDI) and the electron donor polymer poly(9,9’‐dioctylfluorene‐co‐benzothiadiazole) (F8BT). The ambient ageing of these photo­active layers is a consequence of the PDI component segregation; however, the final PDI domain size remains smaller than the resolution limit of optical microscopy. We find that the photophysical properties of the aged F8BT:PDI layer and the EQE of the aged device are significantly altered. The fabrication of F8BT:PDI layers from solvents of increasing boiling point allows for the spectroscopic monitoring of the ageing‐induced phase segregation (a‐PSG) process. For each solvent used, the extent of a‐PSG is correlated with the PDI dispersion in the F8BT matrix as received immediately after layer deposition. The tendency for room temperature phase demixing becomes stronger as PDI is more finely dispersed in the freshly spun F8BT:PDI layer. The evolution of the room temperature phase segregation of PDI has a negative impact on the photophysical processes that are essential for charge photogeneration in the F8BT:PDI photoactive layer.     

Relay pursuit of a maneuvering target using dynamic Voronoi diagrams

This paper addresses the problem of the pursuit of a maneuvering target by a group of pursuers distributed in the plane. This pursuit problem is solved by associating it with a Voronoi-like partitioning problem that characterizes the set of initial positions from which the target can be intercepted by a given pursuer faster than any other pursuer from the same group. In the formulation of this partitioning problem, the target does not necessarily travel along prescribed trajectories, as it is typically assumed in the literature, but, instead, it can apply an “evading” strategy in an effort to delay or, if possible, escape capture. We characterize an approximate solution to this problem by associating it with a standard Voronoi partitioning problem. Subsequently, we propose a relay pursuit strategy, that is, a special group pursuit scheme such that, at each instant of time, only one pursuer is assigned the task of capturing the maneuvering target. During the course of the relay pursuit, the pursuer–target assignment changes dynamically with time based on the (time varying) proximity relations between the pursuers and the target. This proximity information is encoded in the solution of the Voronoi-like partitioning problem. Simulation results are presented to highlight the theoretical developments.     

Design issues and implications for structural integrity of fusion power plant components

The criteria and implications for successful design, licensing and power plant operation are assessed, and imposed constraints and limitations are examined. The design of a reliable fusion power plant is dependent on the availability of licensed nuclear materials and the structural-thermal loading conditions during normal and abnormal events. Various conditions in a tokamak lead to structural damage and possible failure. Taking into consideration all the possible structural failure mechanisms, the most likely are combinations of fatigue and creep. Issues encountered in the fusion environment are the significant amount of irradiation creep, the large ratio of helium production to displacement damage, and the degradation of fatigue strength and ductility, effects which are even encountered at low temperatures. Design codes distinguish between failure criteria under steady and transient loads, and lay down rules for failure prediction under combined creep-fatigue conditions. Currently, there are no established fusion specific licensing processes or component design codes. Any limits imposed on designs or performance are taken from existing design codes developed by the fission industry. There is a need to initiate the process of defining and developing tools for the design and licensing of fusion components and facilities to ensure nuclear safety.     

Design Signals: The Role of Software Architecture and Paradigms in Design Thinking and Practice

Does the ontology of design software influence built form? Panagiotis Michalatos , lecturer in architectural technology at Harvard Graduate School of Design and a principal research engineer at Autodesk, Inc, here looks at how the move from drawing typologies to digital modelling since the mid-1990s has affected architectural aesthetics. He goes on to examine two more recent developments that may announce a further paradigm shift: granular tracking of design input, and data organisation practices in biomedics which, transferred to architecture, could allow for a more spatio-temporal approach.     

Atrial Fibrillation: Pathogenesis,Predisposing Factors,and Genetics

Atrial fibrillation (AF) is the most frequent arrhythmia managed in clinical practice, and it is linked to an increased risk of death, stroke, and peripheral embolism. The Global Burden of Disease shows that the estimated prevalence of AF is up to 33.5 million patients. So far, successful therapeutic techniques have been implemented, with a high health-care cost burden. As a result, identifying modifiable risk factors for AF and suitable preventive measures may play a significant role in enhancing community health and lowering health-care system expenditures. Several mechanisms, including electrical and structural remodeling of atrial tissue, have been proposed to contribute to the development of AF. This review article discusses the predisposing factors in AF including the different pathogenic mechanisms, sedentary lifestyle, and dietary habits, as well as the potential genetic burden.