Synthesis of hydroxyapatite/poly(vinyl alcohol phosphate) nanocomposite and its characterization

Hydroxyapatite (HAp)/poly(vinyl alcohol phosphate) (PVAP) nanocomposite has been prepared using a solution‐based method varying HAp from 10 to 60% (w/w). X‐ray diffraction, Fourier transform infrared absorption spectra (FTIR), and thermal analysis have indicated the presence of bonding between HAp particles and PVAP matrix. Transmission electron microscope analysis shows the needle‐like crystals of HAp powder having a diameter of 6–10 nm and a length of 26–38 nm. The surface roughness and the homogeneous dispersion of HAp particles in the polymer matrix have been observed by scanning electron microscopy. Particle size distribution analysis shows the narrow distribution of hydrodynamic particles in the polymer matrix. The tensile stress–strain curves show the improvement in mechanical properties of the composites with increase in amount of HAp particles loading. The composites along with polymer are highly hemocompatible. The use of PVAP promotes the homogeneous distribution of particles on the polymer matrix along with strong particle–polymer interfacial bonding, which has supported the improvement in mechanical properties of the composites. The prepared HAp/PVAP composite with uniform microstructure would be effective to act as a potential biomaterial. POLYM. COMPOS., 2008. © 2008 Society of Plastics Engineers     

Biofunctionalized,Phosphonate‐Grafted,Ultrasmall Iron Oxide Nanoparticles for Combined Targeted Cancer Therapy and Multimodal Imaging

A novel, inexpensive biofunctionalization approach is adopted to develop a multimodal and theranostic nanoagent, which combines cancer‐targeted magnetic resonance/optical imaging and pH‐sensitive drug release into one system. This multifunctional nanosystem, based on an ultrasmall superparamagnetic iron oxide (USPIO) nanocore, is modified with a hydrophilic, biocompatible, and biodegradable coating of N‐phosphonomethyl iminodiacetic acid (PMIDA). Using appropriate spacers, functional molecules, such as rhodamine B isothiocyanate, folic acid, and methotrexate, are coupled to the amine‐derivatized USPIO–PMIDA support with the aim of endowing simultaneous targeting, imaging, and intracellular drug‐delivering capability. For the first time, phosphonic acid chemistry is successfully exploited to develop a stealth, multifunctional nanoprobe that can selectively target, detect, and kill cancer cells overexpressing the folate receptor, while allowing real‐time monitoring of tumor response to drug treatment through dual‐modal fluorescence and magnetic resonance imaging.     

Magnetic and microwave properties of Sm1?xBa2Cu3+xO7?δ superconductors at 4.2 K prepared by an organic carbonate coprecipitation route

Samples of Sm₁Ba₂Cu₃O_7– and Sm_0.95Ba₂Cu_3.05O_7– are prepared by a coprecipitation technique using organic carbonates in the presence of stable polymers. The electrical, magnetic, and microwave measurements have been carried out to characterize the materials. Both normal (Sm₁Ba₂Cu₃O_7– ) and copper-rich (Sm_0.95Ba₂Cu_3.05O_7– ) samples showed sharp superconducting transitions at 94 K. Lower and upper critical fields of the samples are estimated from magnetization measurements. The critical magnetization current density (J _mc ) and pinning force density (F _p ) of the samples are obtained from the magnetization hysteresis loop at 4.2 K for fields up to 5T. Superconducting parameters (H _c (O),K _GL,,) are obtained by using the values of lower and upper critical magnetic fields. Microwave-induced d.c. voltage measurements indicated a smaller number of weak links for copper-rich samples. The enhancement of critical current density and the reduction of total number of weak links for copper-rich samples may be due to the increase in hole concentration caused by the partial replacement of Sm by Cu.     

Electrical Discharge Machining of MMCs Reinforced with Very Small Particles

This paper investigates material removal rate (MRR), kerf width, surface finish, and electrode wire wear for different pule-on-times as well as wire tensions during EDM of 6061 aluminum alloy reinforced with 10 vol % 700 nm SiCp MMC. Effects of pulse-on-time on output variables at lower and higher wire tensions were investigated. Similarly, effects of the wire tensions on output variables at shorter and longer pulse-on-times were also investigated. Longer pule-on-time increases the MRR though the higher wire tension reduces the MMR. The effect of wire tension on MRR is much more significant at longer pule-on-time compare to that at shorter pule-on-time. There is an optimum pule-on-time for which best surface finish is achieved. The surface finish deteriorates when the pulse-on-time is higher or lower than the optimum pule-on-time. With the rise of tension in wire, the surface roughness increases and decreases at shorter and longer pule-on-times, respectively. The machined surface contains solidified molten material, splash of materials, and blisters. Generation of the tapered slot with higher kerf width at the top indicates the wear of wire electrode. Significant variation of the electrode wire diameter was due to coating of the matrix, wear, and clogging of small reinforced particles in the electrode gap.     

Fire monitoring in coal mines using wireless underground sensor network and interval type-2 fuzzy logic controller

International Journal of Coal Science & Technology - From the view of underground coal mining safety system, it is extremely important to continuous monitoring of coal mines for the prompt...     

RETRACTED ARTICLE: Sintered Aluminum–Graphene Nano-Bio Composite Materials for the Medical Application

Powder Metallurgy and Metal Ceramics - It is known that graphene is stronger than steel. It is characterized by extremely high values of the Young's modulus (up to 1 TPa), strength (~125 GPa)...     

Observation of extremely long spin relaxation times in an organic nanowire spin valve

Organic semiconductors that are pi-conjugated are emerging as an important platform for 'spintronics', which purports to harness the spin degree of freedom of a charge carrier to store, process and/or communicate information. Here, we report the study of an organic nanowire spin valve device, 50 nm in diameter, consisting of a trilayer of ferromagnetic cobalt, an organic, Alq3, and ferromagnetic nickel. The measured spin relaxation time in the organic is found to be exceptionally long-between a few milliseconds and a second-and it is relatively temperature independent up to 100 K. Our experimental observations strongly suggest that the primary spin relaxation mechanism in the organic is the Elliott-Yafet mode, in which the spin relaxes whenever a carrier scatters and its velocity changes.     

A Study on Process Parameters of Direct Ethanol Fuel Cell

Ethanol is one of the promising future fuels of Direct Alcohol Fuel Cells (DAFC). The electro‐oxidation of ethanol fuel on anode made of carbon‐supported Pt‐Ru electrode catalysts was carried out in a lab scale direct ethanol fuel cell (DEFC). Cathode used was Pt‐black high surface area. The membrane electrode assembly (MEA) was prepared by sandwiching the solid polymer electrolyte membrane, prepared from Nafion^® (SE‐5112, DuPont USA) dispersion, between the anode and cathode. The DEFC was fabricated using the MEA and tested at different catalyst loadings at the electrodes, temperatures and ethanol concentrations. The maximum power density of DEFC for optimized value of ethanol concentration, catalyst loading and temperature were determined. The maximum open circuit voltage (OCV) of 0.815 V, short circuit current density (SCCD) of 27.90 mA/cm² and power density of 10.30 mW/cm² were obtained for anode (Pt‐Ru/C) and cathode (Pt‐black) loading of 1 mg/cm² at a temperature of 90°C anode and 60°C cathode for 2M ethanol.