Hydrogen storage properties of Mg2Ni affected by Cr catalyst

The effect of Cr as a catalyst in different proportions was investigated to monitor the hydrogen storage properties of Mg₂Ni including their thermodynamic aspects. The P–C–T isotherms for absorption/desorption were measured at 225 °C, 250 °C, 275 °C and 300 °C temperatures. A significant increment in the plateau pressures at different temperature was observed, which shows the positive impact of Cr content in the formation of less stable hydrides. The active sites produced by the ball milling may be the reason for the formation of less stable hydrides. Decrements in the storage capacity with the Cr content were attributed to the formation of MgNi₂ phase which does not absorb hydrogen at the employed temperature-pressure conditions. XRD and SEM technique were used to identify the structural and morphological changes induced by the hydrogenation cycles.     

Curvelet-based fingerprint anti-spoofing

Existing perspiration-based liveness detection algorithms need two successive images (captured in certain time interval), hence they are slow and not useful for real-time applications. Liveness detection methods using extra hardware increase the cost of the system. To alleviate these problems, we propose new curvelet-based method which needs only one fingerprint to detect liveness. Wavelets are very effective in representing objects with isolated point singularities, but fail to represent line and curve singularities. Curvelet transform allows representing singularities along curves in a more efficient way than the wavelets. Ridges oriented in different directions in a fingerprint image are curved; hence curvelets are very significant to characterize fingerprint texture. Textural measures based on curvelet energy and co-occurrence signatures are used to characterize fingerprint image. Dimensionalities of feature sets are reduced by running Pudil’s sequential forward floating selection (SFFS) algorithm. Curvelet energy and co-occurrence signatures are independently tested on three different classifiers: AdaBoost.M1, support vector machine and alternating decision tree. Finally, all the aforementioned classifiers are fused using the “Majority Voting Rule” to form an ensemble classifier. A fingerprint database consisting of 185 real, 90 Fun-Doh and 150 Gummy fingerprints is created by using varieties of artificial materials for casts and moulds of spoof fingerprints. Performance of the new liveness detection approach is found very promising, as it needs only one fingerprint and no extra hardware to detect vitality.     

Melanocyte pigmentation stiffens murine cardiac tricuspid valve leaflet

Pigmentation of murine cardiac tricuspid valve leaflet is associated with melanocyte concentration, which affects its stiffness. Owing to its biological and viscoelastic nature, estimation of the in situ stiffness measurement becomes a challenging task. Therefore, quasi-static and nanodynamic mechanical analysis of the leaflets of the mouse tricuspid valve is performed in the current work. The mechanical properties along the leaflet vary with the degree of pigmentation. Pigmented regions of the valve leaflet that contain melanocytes displayed higher storage modulus (7–10 GPa) than non-pigmented areas (2.5–4 GPa). These results suggest that the presence of melanocytes affects the viscoelastic properties of the mouse atrioventricular valves and are important for their proper functioning in the organism.     

Study of crystal structure,dielectric, magnetic and magnetoelecrtic properties of xCoFe2O4-(1-x)Na0.5Bi0.5TiO3 composites

Multiferroic composites of spinel ferrite and ferroelectric xCoFe₂O₄ – (1-x)Na_0.5Bi_0.5TiO₃ (with x = 0.10,0.30,0.50) were efficiently prepared by standard solid state reaction mechanism. X-ray diffractometer was used to analyze crystal structure of the prepared composites. The observed XRD patterns of the composites comprise peaks of both the phases i.e. ferrite and ferroelectric, with no sign of secondary peaks. Rietveld refinement of XRD data further confirms the coexistence of these two phases with cubic (Fd3m) and rhombohedral (R3c) symmetry corresponding to ferrite and ferroelectric phase respectively. The 3-dimensional overview of crystal structure of pure CoFe₂O₄ and Na_0.5Bi_0.5TiO₃ and of composite 0.50CoFe₂O₄?0.50Na_0.5Bi_0.5TiO₃ is generated by using refined parameters. The dielectric constant (ε´) and dielectric loss (tanδ) values were recorded as a function of frequency ranging from 100?Hz to 7?MHz and at different temperatures. Both ε´ and tanδ follow dispersion pattern at lower frequencies while show frequency independent behavior at higher frequencies. The magnetic evaluation carried by analyzing M-H hysteresis loop reveals the ferrimagnetic characteristics of these composites. The highest value of magnetic moment is 1.12μ_B observed for composite 0.50CoFe₂O₄ – 0.50Na_0.5Bi_0.5TiO_3. Magnetoelectric (ME) voltage coefficient (α) was also demonstrated to observe the interaction between ferrite and ferroelectric phases. The highest value of α (72.72μV/Oe cm) is obtained for low ferrite composition 0.10CoFe₂O₄ – 0.90Na_0.5Bi_0.5TiO₃, which suggests the dependence of magnetoelectric response on the resistivity of the composites.     

Synthesis and characterization of zirconia-based catalyst for the isomerization of n-hexane

Sulfated zirconia is a very strong solid acid catalyst which can be utilized for various reactions. The present study focuses on synthesis of zirconia-based catalyst with high acidity and high surface area, particularly for isomerization reaction. Sulfated zirconia has been obtained by sulfation of zirconia prepared by hydrothermal route. The catalyst was developed by impregnating tungstophosphoric acid on sulfated zirconia by wet incipient method. The catalyst was characterized through Brunauer–Emmett–Teller (BET) surface area, temperature-programmed desorption of ammonia, temperature program reduction of hydrogen, Fourier transmission infrared spectroscopy, and thermogravimetric analysis. The results revealed that the catalyst is crystalline in nature with surface area 190–225?m² g^?1 and acidity 0.135–0.558?mmol?g^?1. Twenty-five percent conversion was obtained (as confirmed by gas chromatography) at 225°C using n-hexane as model hydrocarbon in fixed-bed microreactor.     

Biomimetic synthesis and patterning of silver nanoparticles

The creation of nanoscale materials for advanced structures has led to a growing interest in the area of biomineralization. Numerous microorganisms are capable of synthesizing inorganic-based structures. For example, diatoms use amorphous silica as a structural material, bacteria synthesize magnetite (Fe3O4) particles and form silver nanoparticles, and yeast cells synthesize cadmium sulphide nanoparticles. The process of biomineralization and assembly of nanostructured inorganic components into hierarchical structures has led to the development of a variety of approaches that mimic the recognition and nucleation capabilities found in biomolecules for inorganic material synthesis. In this report, we describe the in vitro biosynthesis of silver nanoparticles using silver-binding peptides identified from a combinatorial phage display peptide library.     

The three-dimensional model of Dictyostelium discoideum racE based on the human rhoA-GDP crystal structure

The three-dimensional structure of racE was modeled using several homologous small G proteins, and the best model obtained using the human rhoA as modeling template is reported. The three-dimensional fold of the racE model is remarkably similar to the cellular form of human ras p21 crystal structure. Its secondary structure consists of six alpha-helices, six beta-strands and three 3(10) helices. The model retains its secondary structure after a 300 K, 300 ps molecular dynamics (MD) simulation. Important domains of the protein include its effector loop (residues 34-46), the insertion domain (residues 121-136), and the polybasic motif (between 210 and 220) not modeled in the current structure. The effector loop is inherently flexible and the structure docked with GDP exhibits the effector loop moving significantly closer to the nucleotide binding pocket, forming a tighter complex with the bound GDP. The mobility of the effector loop is conferred by a single residue 'hinge' point at residue 34Asp, also allowing the Switch I region, immediately preceding the effector loop, to be equally mobile. In comparison, the Switch II region shows average mobility. The insertion domain is highly flexible, with the insertion taking the form of a helical domain, with several charged residues forming a complex charged interface over the entire insertion region. While the GDP moiety is loosely held in the active site, the metal cation is extensively co-ordinated. The critical residue 38Thr exhibits high mobility, and is seen interacting directly with the metal ion at a distance of 2.64 A, and indirectly via an intervening water molecule. 64Gln, a key residue involved in GTP hydrolysis in ras, is seen facing the beta-phosphate group and the metal ion. Certain residues (i.e. 51Asn, 38Thr and 65Glu) exhibit unique characteristics and these residues, together with 158Val, may play important roles in the maintenance of the protein's integrity and function. There is strong consensus of secondary structural elements between models generated using various templates, such as h-rac1, h-rhoA and h-cdc42 bound to RhoGDI, all sharing only 50-55% sequence identity with racE, which suggests that this model is in all probability an accurate prediction of the true tertiary structure of racE.     

Computing Approximate Shortest Paths on Convex Polytopes

The algorithms for computing a shortest path on a polyhedral surface are slow, complicated, and numerically unstable. We have developed and implemented a robust and efficient algorithm for computing approximate shortest paths on a convex polyhedral surface. Given a convex polyhedral surface P in \reals ³ , two points s, t ∈ P , and a parameter \eps > 0 , it computes a path between s and t on P whose length is at most (1+\eps) times the length of the shortest path between those points. It constructs in time O(n/\sqrt \eps ) a graph of size O(1/\eps ⁴ ) , computes a shortest path on this graph, and projects the path onto the surface in O(n/\eps) time, where n is the number of vertices of P . In the postprocessing step we have added a heuristic that considerably improves the quality of the resulting path. Received July 25, 2000; revised June 6, 2001.     

Improved Algorithms for Uniform Partitions of Points

We consider the following one- and two-dimensional bucketing problems: Given a set S of n points in \reals ¹ or \reals ² and a positive integer b , distribute the points of S into b equal-size buckets so that the maximum number of points in a bucket is minimized. Suppose at most (n/b) + Δ points lie in each bucket in an optimal solution. We present algorithms whose time complexities depend on b and Δ . No prior knowledge of Δ is necessary for our algorithms. For the one-dimensional problem, we give a deterministic algorithm that achieves a running time of O(b ⁴ (Δ ² +log n) + n) . For the two-dimensional problem, we present a Monte Carlo algorithm that runs in subquadratic time for small values of b and Δ . The previous algorithms, by Asano and Tokuyama [1], searched the entire parameterized space and required Ω ( n ² ) time in the worst case even for constant values of b and Δ . We also present a subquadratic algorithm for the special case of the two-dimensional problem when b=2 .     

Synthesis and Physical Properties of (Cu,M)Ba2Ca3Cu4Oz (M=C,Mg,Ni,Al,Zn,Tl)

We have synthesized the single phase samples of Cu _x C _0.1 Ba ₂ Ca ₃ Cu ₄ O _z (x=0.20.9). Transport and magnetic measurements and iodometric titration analysis were carried out for these materials. From these results we discuss the correlation between T _c , the Hall number, copper valence and oxygen content. The effect of the substituted M ions on T _c in (CuC, M)-l234 (M=Ni,Zn,Al,TI,Mg) is also discussed. We propose a unique selective carrier-doping mechanism in (Cu,C)- and (CuC,Mg)-1234 systems.