Thermooptic two-mode interference device for reconfigurable quantum optic circuits

Reconfigurable large-scale integrated quantum optic circuits require compact component having capability of accurate manipulation of quantum entanglement for quantum communication and information processing applications. Here, a thermooptic two-mode interference coupler has been introduced as a compact component for generation of reconfigurable complex multi-photons quantum interference. Both theoretical and experimental approaches are used for the demonstration of two-photon and four-photon quantum entanglement manipulated with thermooptic phase change in TMI region. Our results demonstrate complex multi-photon quantum interference with high fabrication tolerance and quantum fidelity in smaller dimension than previous thermooptic Mach–Zehnder implementations.     

Robust vectorization method for electrical circuit drawings using component morphology

Pattern Analysis and Applications - Decomposition and representation of electrical circuit drawings to a suitable vector form has widespread applications related to data compression, storage,...     

Exercise classification and event segmentation in Hammersmith Infant Neurological Examination videos

Image and video processing techniques are being frequently used in medical science applications. Computer vision-based systems have successfully replaced various manual medical processes such as analyzing physical and biomechanical parameters, physical examination of patients. These systems are gaining popularity because of their robustness and the objectivity they bring to various medical procedures. Hammersmith Infant Neurological Examinations (HINE) is a set of physical tests that are carried out on infants in the age group of 3–24 months with neurological disorders. However, these tests are graded through visual observations, which can be highly subjective. Therefore, computer vision-aided approach can be used to assist the experts in the grading process. In this paper, we present a method of automatic exercise classification through visual analysis of the HINE videos recorded at hospitals. We have used scale-invariant-feature-transform features to generate a bag-of-words from the image frames of the video sequences. Frequency of these visual words is then used to classify the video sequences using HMM. We also present a method of event segmentation in long videos containing more than two exercises. Event segmentation coupled with a classifier can help in automatic indexing of long and continuous video sequences of the HINE set. Our proposed framework is a step forward in the process of automation of HINE tests through computer vision-based methods. We conducted tests on a dataset comprising of 70 HINE video sequences. It has been found that the proposed method can successfully classify exercises with accuracy as high as 84%. The proposed work has direct applications in automatic or semiautomatic analysis of “vertical suspension” and “ventral suspension” tests of HINE. Though some of the critical tests such as “pulled-to-sit,” “lateral tilting,” or “adductor’s angle measurement” have already been addressed using image- and video-guided techniques, scopes are there for further improvement.     

Using channel state dependent packet scheduling to improve TCPthroughput over wireless LANs

In recent years, a variety of mobile computers equipped with wireless communication devices have become popular. These computers use applications and protocols, originally developed for wired desktop hosts, to communicate over wireless channels. Unlike wired networks, packets transmitted on wireless channels are often subject to burst errors which cause back to back packet losses. In this paper we study the effect of burst packet errors and error recovery mechanisms employed in wireless MAC protocols on the performance of transport protocols such as TCP. Most wireless LAN link layer protocols recover from packet losses by retransmitting lost segments. When the wireless channel is in a burst error state, most retransmission attempts fail, thereby causing poor utilization of the wireless channel. Furthermore, in the event of multiple sessions sharing a wireless link, FIFO packet scheduling can cause the HOL blocking effect, resulting in unfair sharing of the bandwidth. This observation leads to a new class of packet dispatching methods which explicitly take wireless channel characteristics into consideration in making packet dispatching decisions. We compare a variety of channel state dependent packet (CSDP) scheduling methods with a view towards enhancing the performance of transport layer sessions. Our results indicate that by employing a CSDP scheduler at the wireless LAN device driver level, significant improvement in channel utilization can be achieved in typical wireless LAN configurations. This revised version was published online in July 2006 with corrections to the Cover Date.     

Synthesis and characterization of perfectly alternating polycarbonate‐polydimethylsiloxane multiblock copolymers possessing controlled block lengths

An array of perfectly alternating polycarbonate‐polydimethylsiloxane (PC‐PDMS) multiblock copolymers possessing systematic variations in block molecular weights were successfully produced by coupling preformed PC and PDMS telechelic oligomers using hydrosilylation. Based on gel permeation chromatography results, the multiblock copolymers were essentially void of the oligomeric precursors. Despite the relatively large difference in solubility parameter between PC and PDMS, the multiblock copolymers exhibited significant partial miscibility between the two phases. As expected, the degree of partial miscibility was dependent on the molecular weight of the blocks with the extent of partial miscibility increasing with decreasing block molecular weights. Morphological characterization using small angle X‐ray scattering showed that, at a given PC block molecular weight, the uniformity of the two phase morphology increased with increasing PDMS block molecular weight, which is consistent with a decrease in the extent of phase mixing with increasing PDMS block molecular weight. POLYM. ENG. SCI., 54:1648–1663, 2014. © 2013 Society of Plastics Engineers     

A thermodynamically consistent framework for non-isothermal modelling of local heat generation and electromotive force in SOFC single electrodes

Mathematical models for single electrode reversible heat and non-isothermal electromotive force (EMF) of a solid oxide fuel cell (SOFC) are developed. These models estimate the volumetric reversible heat generation and EMF of electrochemical reactions, within each electrode at local conditions of temperature and pressure, based on entropy change of half reactions. The resulting equations are thermodynamically consistent. They inherently obey the conservation of energy law as the electrochemical energy released added to the heat of reactions at each electrode equate the enthalpy change of the reacted species. The equations are implemented to model electrodes in a tubular micro- solid oxide fuel cell (TμSOFC). The thermodynamic consistency of the model is numerically confirmed as the enthalpy of the reactants equates the electric energy released by the cell plus the sum of electrode heats plus electrolyte Ohmic heat. The effect of thermal gradients on the cell's overall EMF is found to be negligible. The reversible and irreversible heat generation of each electrode are distinguished. Overall, the anode is found to be endothermic, and the cathode exothermic.     

On comparison of luminescence properties of La2Zr2O7 and La2Hf2O7 nanoparticles

Unveiling the underlying mechanisms of properties of functional materials, including the luminescence differences among similar pyrochlores A₂B₂O₇, opens new gateways to select proper hosts for various optoelectronic applications by scientists and engineers. For example, although La₂Zr₂O₇ (LZO) and La₂Hf₂O₇ (LHO) pyrochlores have similar chemical compositional and crystallographic structural features, they demonstrate different luminescence properties both before and after doped with Eu³⁺ ions. Based on our earlier work, LHO-based nanophosphors display higher photo- and radioluminescence intensity, higher quantum efficiency, and longer excited state lifetime compared to LZO-based nanophosphors. Moreover, under electronic O²⁻→Zr⁴⁺/Hf⁴⁺ transition excitation at 306 nm, undoped LHO nanoparticles (NPs) have only violet blue emission, whereas LZO NPs show violet blue and red emissions. In this study, we have combined experimental and density functional theory (DFT) based theoretical calculation to explain the observed results. First, we calculated the density of state (DOS) based on DFT and studied the energetics of ionized oxygen vacancies in the band gaps of LZO and LHO theoretically, which explain their underlying luminescence difference. For Eu³⁺-doped NPs, we performed emission intensity and lifetime calculations and found that the LHOE NPs have higher host to dopant energy transfer efficiency than the LZOE NPs (59.3% vs 24.6%), which accounts for the optical performance superiority of the former over the latter. Moreover, by corroborating our experimental data with the DFT calculations, we suggest that the Eu³⁺ doping states in LHO present at exact energy position (both in majority and minority spin components) where oxygen defect states are located unlike those in LZO. Lastly, both the NPs show negligible photobleaching highlighting their potential for bioimaging applications. This current report provides a deeper understanding of the advantages of LHO over LZO as an advanced host for phosphors, scintillators, and fluoroimmunoassays.     

Development of a novel proton conducting fuel cell based on a Ni‐YSZ support

A new proton conducting fuel cell design based on the BZCYYb electrolyte is studied in this research. In high‐performance YSZ‐based SOFCs, the Ni‐YSZ support plays a key role in providing required electrical properties and robust mechanical behavior. In this study, this well‐established Ni‐YSZ support is used to maintain the proton conducting fuel cell integrity. The cell is in a Ni‐YSZ (375 μm support)/Ni‐BZCYYb (20 μm anode functional layer)/BZCYYb (10 μm electrolyte)/LSCF‐BZCYYb (25 μm cathode) configuration. Maximum power density values of 166, 218, and 285 mW/cm² have been obtained at 600°C, 650°C, and 700°C, respectively. AC impedance spectroscopy results show values of 2.17, 1.23, and 0.76 Ω·cm² at these temperatures where the main resistance contributor above 600°C is ohmic resistance. Very fine NiO and YSZ powders were used to achieve a suitable sintering shrinkage which can enhance the electrolyte sintering. During cosintering of the support and BZCYYb electrolyte layers, the higher shrinkage of the support layer led to compressive stress in the electrolyte, thereby enhancing its densification. The promising results of the current study show that a new generation of proton conducting fuel cells based on the chemically and mechanically robust Ni‐YSZ support can be developed which can improve long‐term performance and reduce fabrication costs of proton conducting fuel cells.     

Possibility to Use Hydrothermally Synthesized CuFeS<Subscript>2</Subscript> Nanocomposite as an Acceptor in Hybrid Solar Cell

Here we have approached the plausible use of CuFeS₂ nanocomposite as an acceptor in organic–inorganic hybrid solar cell. To produce CuFeS₂ nanocomposite, hydrothermal strategy was employed. The room-temperature XRD pattern approves the synthesized material as CuFeS₂ with no phase impurity (JCPDS Card no: 37-0471). The elemental composition of the material was analyzed from the TEM-EDX data. The obtained selected area electron diffraction (SAED) planes harmonized with the XRD pattern of the synthesized product. Optical band gap (4.14 eV) of the composite from UV–Vis analysis depicts that the synthesized material is belonging to wide band gap semiconductor family. The HOMO (? 6.97 eV) and LUMO (? 2.93 eV) positions from electrochemical study reveal that there is a possibility of electron transfer from MEH-PPV to CuFeS₂. The optical absorption and photoluminescence spectra of MEH-PPV:CuFeS₂ (donor:acceptor) composite were recorded sequentially by varying weight ratios. The monotonic blue shifting of the absorption peak position indicated the interaction between donor and acceptor materials. The possibility of electron transfer from donor (MEH-PPV) to acceptor (CuFeS₂) was approved with photoluminescence analysis. Subsequently, we have fabricated a hybrid solar cell by incorporating CuFeS₂ nanocomposite with MEH-PPV in open atmosphere and obtained 0.3% power conversion efficiency.     

Influence of martensite morphology on the work-hardening behavior of high strength ferrite–martensite dual-phase steel

This study concerns influence of martensite morphology on the work-hardening behavior of high-strength ferrite–martensite dual-phase (DP) steel. A low-carbon microalloyed steel was subjected to intermediate quenching (IQ), step quenching (SQ), and intercritical annealing (IA) to develop different martensite morphologies, i.e., fine and fibrous, blocky and banded, and island types, respectively. Analyses of work-hardening behavior of the DP microstructures by differential Crussard–Jaoul technique have demonstrated three stages of work-hardening for IQ and IA samples, whereas the SQ sample revealed only two stages. Similar analyses by modified Crussard–Jaoul technique showed only two stages of work-hardening for all the samples. Among different treatments, IQ route has yielded the best combination of strength and ductility due to its superior work-hardening behavior. The influence of martensite morphology on nucleation and growth of microvoids/microcracks has been correlated with the observed tensile ductility.