无线通信系统的GUI设计与仿真实现

探讨了无线通信系统的调制、编码、解调、译码等信号处理功能以及无线信道的GUI界面设计与仿真实现。首先将无线通信系统拆分为调制器和解调器、采样器和滤波器以及编码器和解码器等模块;然后通过各种信号处理函数对输入信号进行信号处理模块功能仿真;最后通过GUI编程实现各个通信系统模块的调用和链接,从而最终实现无线通信系统的调制和编码、解调和译码等信号处理仿真和无线通信信道仿真。通过基于Matlab的GUI界面设计和仿真结果表明,可以有效地对无线通信系统进行功能仿真,对于利用软件无线电技术构建无线通信具有十分重要的参考意义。     

基于CFD的LED阵列自然对流散热研究

基于计算流体动力学(CFD)方法,分别采用带浮力修正的k-ε模型和P-1模型计算对流换热和热辐射,构建了包括LED固体部件和外部流体空间的全场三维数学模型。应用该模型对LED自然对流散热过程进行模拟,并通过物理试验验证了模型的有效性。计算表明,温度场与对流换热系数分布均具有各向异性特征,前者取决于芯片的功率密度和布设位置,而后者源于外部流体的流动状态。并且,辐射在整个散热过程中起着重要的作用,它不仅能减小热阻、降低结温,而且能弱化温度场的不均性、提高整体散热效率,在本文的计算条件下,辐射散热量占总散热功率的23.3%。     

具备定位功能的ZigBee^R SoC

今日相容于IEEE802．15．4且适用于ZigBee的无线射频收发器、微控制器及系统单芯片（SOC）半导体装置已相当普及。高度整合的多功能SOC解决方案是促成ZigBee无线网络得以广泛运用在众多应用中的重要因素,包括工业监控、家庭及建筑自动化、传感器网络,乃至于无线医疗解决方案。在以上解决方案中增添无线射频装置的定位功能使得这些网络的价值得以大幅提升。     

Physico-chemical investigation of clayey/cement-based materials interaction in the context of geological waste disposal: Experimental approach and results

Within the concepts under study for the geological disposal of intermediate-level long-lived waste, cement-based materials are considered as candidate materials. The clayey surrounding rock and the cement-based material being considered differ greatly in their porewater composition. Experiments are conducted on the diffusion of solutes constituting those porewaters in a confined clay/cement composite system using cells. The test temperature was set at 25 °C and 2, 6 and 12 months. Results supply new information: carbonation is low and not clog the interface. Such absence of carbonation allows for the diffusion of aqueous species and, thus, for the degradation of the cement paste and the illitisation of illite/smectite interstratifications. The cement material is subjected to a decalcification: portlandite dissolution and a CaO/SiO₂ reduction in the calcium silicate hydrate. The sulphate in diffusion induces non-destructive ettringite precipitation in the largest pores. After 12 months, about 800 µm of cement material is concerned by decalcification.     

Concrete modelling for expertise of structures affected by alkali aggregate reaction

Alkali aggregate reaction (AAR) affects numerous civil engineering structures and causes irreversible expansion and cracking. In order to control the safety level and the maintenance cost of its hydraulic dams, Electricité de France (EDF) must reach better comprehension and better prediction of the expansion phenomena. For this purpose, EDF has developed a numerical model based on the finite element method in order to assess the mechanical behaviour of damaged structures. The model takes the following phenomena into account: concrete creep, the stress induced by the formation of AAR gel and the mechanical damage. A rheological model was developed to assess the coupling between the different phenomena (creep, AAR and anisotropic damage). Experimental results were used to test the model. The results show the capability of the model to predict the experimental behaviour of beams subjected to AAR. In order to obtain such prediction, it is necessary to take all the phenomena occurring in the concrete into consideration.     

Pulsed laser deposited heterogeneous mixture of Li2Se-Sb2Se3 nanocomposite as a new storage lithium material

Li₂Se-Sb₂Se₃ nanocomposites with a highly heterogeneous mixture have been fabricated by reactive pulsed laser deposition method. The electrochemical properties of the as-deposited Li₂Se-Sb₂Se₃ thin film during the first charging and discharging have been investigated by the galvanostatic cycling and cyclic voltammetry measurements for the first time. By using ex situ X-ray diffraction (XRD), X-ray photoelectron spectra (XPS), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and selected-area electron diffraction (SAED) measurements, the decomposition of Li₂Se driven by Sb₂Se₃ under the electrochemical potential is revealed. In the first cycle, the oxidation peaks at 2.5 V and 3.2 V and the reduction peaks at 2.0 V can be attributed to the decomposition and formation of Li₂Se with the conversion reaction of Sb₂Se₃ into Sb₂Se₅. Our findings demonstrate that nanocomposite Li₂Se-Sb₂Se₃ can possess very high electrochemical activity. These results present a special case of solid-state heterogeneous electrochemistry with both nanostructured binary materials.     

Influence of the tetravalent cation on the high-voltage electrochemical activity of LiNi0.5M1.5O4 spinel cathode materials

The electrochemical properties of substituted LiNi_0.5Mn_1.5−xM_xO₄ spinels at high potential (>4 V vs Li⁺/Li) have been investigated for M = Ti and Ru, in order to determine the role of the tetravalent cation in such systems where nickel is a priori the only electroactive species. These systems are found to form extended solid solutions (up to x = 1.3 and x = 1.0 for Ti and Ru, respectively) that were characterized by X-ray diffraction and Raman spectroscopy. Titanium substitution induces a drastic decrease in high potential electrochemical capacity, whereas the capacity is maintained and the kinetics are even improved in the presence of ruthenium. These results are completed by new results on the Li_4−2xNi_3xTi_5−xO₁₂ spinel system, which shows not any high potential activity in spite of the presence of up to 0.5 Ni²⁺ per spinel formula unit on the octahedral site. Taking into account previous data on LiNi_0.5Ge_1.5O₄, we clearly show that even if the tetravalent cation does not participate in the overall redox reaction, electrochemical activity is only possible when nickel is surrounded by tetravalent cations able to accept a local variation of valence (Mn, Ru), whereas full-shell cations such as Ti⁴⁺ and Ge⁴⁺ block the necessary electron transfer pathways in the spinel oxide electrode.     

基于Femtocell的CDMA室内覆盖技术研究

文章首先介绍了Femtocell飞小区的特性和网络架构,分析了Femtocell相比传统的CDMA室内覆盖技术的优点,最后深入剖析了目前Femtocell室内覆盖技术存在的问题并提出解决方案。     

Probing enzyme promiscuity of SGNH hydrolases

Several hydrolases of the SGNH superfamily, including the lipase SrLip from Streptomyces rimosus (Q93MW7), the acyl-CoA thioesterase I TesA from Pseudomonas aeruginosa (Q9HZY8) and the two lipolytic enzymes EstA (from P. aeruginosa, O33407) and EstP (from Pseudomonas putida, Q88QS0), were examined for promiscuity. These enzymes were tested against four chemically different classes of a total of 34 substrates known to be hydrolysed by esterases, thioesterases, lipases, phospholipases, Tweenases and proteases. Furthermore, they were also analysed with respect to their amino acid sequences and structural homology, and their phylogenetic relationship was determined. The Pseudomonas esterases EstA and EstP each have an N-terminal domain with catalytic activity together with a C-terminal autotransporter domain, and so the hybrid enzymes EstA(N)-EstP(C) and EstP(N)-EstA(C) were constructed by swapping the corresponding N- and C-terminal domains, and their hydrolytic activities were compared. Interestingly, substrate specificity and kinetic measurements indicated a significant influence of the autotransporter domains on the catalytic activities of these enzymes in solution. TesA, EstA and EstP were shown to function as esterases with different affinities and catalytic efficacies towards p-nitrophenyl butyrate. Of all the enzymes tested, only SrLip revealed lipase, phospholipase, esterase, thioesterase and Tweenase activities.     

Synthesis,structure and catalytic activities for hydrogen transfer reaction of the carbonyl ruthenium(II) complex containing polypyridine and phosphine ligands

The synthesis and characterization of new ruthenium(II) carbonyl complexes containing polypyridine and triphenylphosphine ligands is reported. Crystallographic information obtained for the trans-PPh₃-[Ru(biq)(PPh₃)₂(CO)]Cl₂ complex (biq = 2,2’-biquinoline) reveals five-coordination on the metal. The complexes were studied as catalysts in hydrogen transfer reactions in basic solution. Turnover frequencies in the 2250-817 h^-1 range were determined in 1 hour of reaction with a substrate/catalysts ratio of 830.