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71.
H. Hakan Yudar Suat Pat Soner Özen Volkan Şenay Şadan Korkmaz Zerrin Pat 《Journal of Materials Science: Materials in Electronics》2017,28(13):9289-9294
In this paper, the effect of RF power on LiCoO2 thin films was investigated using X-ray diffractometer (XRD), atomic force microscopy, UV–Vis spectrophotometer, and potentiostat. The microstructural, surface, optical and electrochemical impedance measurements were performed to LiCoO2 thin films, are used to for the fully solid-state battery cathode material. According to obtained results, the relative intensities of the Li (002) crystal phase in XRD patterns of deposited LiCoO2 thin films were increased by increasing applied RF power, for the first time. The intensity of the LiCoO2 (104) plane is nearly invariant. The relative intensities of the LiCoO2 (113) plane were decreased by increasing RF power. The peak locations of the Li (002) and LiCoO2 (104) were not changed. It was found that Li (002) relative intensities affect the all investigated parameters for the LiCoO2 thin films. Especially, transmittance value increased about 20%. The band gap of the deposited film was changed 100–300 meV drastically. Deposited samples are shown high transparency in the visible region. Randles circuit was used for the equivalent circuit model. Nyquist plots, fitting parameters values and value of the circuit elements were estimated by ZSim software. 相似文献
72.
Alastair R. McInroy David T. Lundie John M. Winfield Chris C. Dudman Peter Jones Stewart F. Parker David Lennon 《Catalysis Today》2006,114(4):403-411
The interaction of HCl with an η-alumina catalyst has been investigated by a combination of diffuse reflectance infrared spectroscopy, temperature-programmed desorption and inelastic neutron scattering (INS) spectroscopy. Infrared spectra provide evidence for dissociative adsorption of HCl and for a process in which hydroxyl groups terminally bound to Al are replaced by chlorine. Temperature-programmed desorption experiments show HCl to desorb over the temperature range 350–>970 K, indicating dissociative HCl adsorption to occur on a wide range of active sites. INS experiments show the residual alumina hydroxyl groups to exhibit an out-of-plane deformation feature, γ(OH), at ca. 200 cm−1, while the in-plane deformation mode, δ(OH), is seen at ca. 1000 cm−1. The formation of new surface hydroxyl groups via the adsorption of hydrogen chloride yields a δ(OH) feature that can be resolved into two bands at 990 and 1050 cm−1. Hydrogen bonding within the alumina/HCl system is responsible for the observation of an Evans transmission window in the infrared spectrum, that occurs via a Fermi resonance interaction between (i) the ν(OH) mode of hydrogen bonded hydroxyl groups and chemisorbed water with (ii) the overtone of the δ(OH) mode of surface hydroxyl groups. The INS technique is able to discriminate among different hydroxyl group bonding geometries on the basis of the local symmetry of the active sites. 相似文献
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Pradipta Biswas Varun Dutt Pat Langdon 《International journal of human-computer interaction》2016,32(1):23-38
Eye-gaze tracking is traditionally used to analyze ocular parameters for investigating visual psychology, marketing study, behavior analysis, and so on. Currently, eye-gaze trackers are also being used to control electronic interfaces in assistive technology, automobile control, and even consumer electronic products like smartphones and tablets. However, there are not many attempts to combine these two streams of research on active and passive uses of eye-gaze trackers. This article compares a few ocular parameters to estimate users’ cognitive load in eye-gaze-controlled interfaces. It was found that average velocity of a particular type of microsaccadic eye movement called Saccadic Intrusion is most indicative of users’ cognitive load compared to pupil dilation and eye-blink-based parameters. Results from the study can be used to develop new metrics of cognitive load measurement, as well as to design intelligent gaze-controlled interfaces that respond to users’ cognitive load. 相似文献
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The Cuban power sector faces a need for extensive investment in new generating capacity, under a large number of uncertainties regarding future conditions, including: rate of demand growth, fluctuations in fuel prices, access to imported fuel, and access to investment capital for construction of new power plants and development of fuel import infrastructure. To identify cost effective investment strategies under these uncertainties, a supply and power sector MARKAL model was assembled, following an extensive review of available data on the Cuban power system and resource potentials. Two scenarios were assessed, a business-as-usual (BAU) scenario assuming continued moderate electricity load growth and domestic fuel production growth, and a high growth (HI) scenario assuming rapid electricity demand growth, rapid increase in domestic fuel production, and a transition to market pricing of electricity. Within these two scenarios sets, sensitivity analyses were conducted on a number of variables. The implications of least-cost investment strategies for new capacity builds, investment spending requirements, electricity prices, fuel expenditures, and carbon dioxide emissions for each scenario were assessed. Natural gas was found to be the cost effective fuel for new generation across both scenarios and most sensitivity cases, suggesting that access to natural gas, through increased domestic production and LNG import, is a clear priority for further analysis in the Cuban context. 相似文献
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This article assessed the glass formability for crystallization of lead titanate (PbTiO3) as the primary phase. It was found that silicate-based glasses formed glass as a block without the need for cold splatting,
but B2O3-based glasses needed to be prepared by cold splatting to retard devitrification. Also, incorporation of BaO was favoured
by an increase in the concentration of B2O3. DTA showed the crystallization of crystalline phases occurred above glass transition temperature. XRD traces supported the
DTA data where the first exothermic peak in each case was presumed to be related to the crystallization of PbTiO3 (PT) phase. XRD also showed the lower c/a ratios compared to pure PT ceramic, which suggested three possibilities for lower
values: crystal clamping by the rigid glass matrix, intrinsic size effect and incorporation of impurities in the PT phase. 相似文献