Iron(II)-catalyzed oxidation of arsenic(III) in a sediment column

Arsenic contamination in aquatic systems is a worldwide concern. Understanding the redox cycling of arsenic in sediments is critical in evaluating the fate of arsenic in aquatic environments and in developing sediment quality guidelines. The direct oxidation of inorganic trivalent arsenic, As(III), by dissolved molecular oxygen has been studied and found to be quite slow. A chemical pathway for As(III) oxidation has been proposed recently in which a radical species, Fe(IV), produced during the oxidation of divalent iron, Fe(II), facilitates the oxidation of As(III). Rapid oxidation of As(III) was observed (on a time scale of hours) in batch systems at pH 7 and 7.5, but the extent of As(III) oxidation was limited. The Fe(II)-catalyzed oxidation of As(III) is examined in a sediment column using both computational and experimental studies. A reactive-transport model is constructed that incorporates the complex kinetics of radical species generation and Fe(II) and As(III) oxidation that have been developed previously. The model is applied to experimental column data. Results indicate that the proposed chemical pathway can explain As(III) oxidation in sediments and that transport in sediments plays a vital role in increasing the extent of As(III) oxidation and efficiency of the Fe(II) catalysis.     

Produced water re-injection with seawater treated by sulphate reduction plant: Injectivity decline, analytical model

Commingled injection of seawater with produced water is an option for offshore fields submitted to waterflooding. It resolves the problems of produced water disposal and of the reservoir pressure maintenance.The presence of barium (strontium) in the formation water and consequent sulphate scaling with seawater flooding is a wide spread phenomenon. In this case, the produced water also contains some barium, which results in sulphate scaling in injection well during commingled injection with seawater.One of the ways around to avoid injectivity damage during the commingled injection of incompatible waters is using a sulphate reduction plant. Being mounted on sea platform, the plant significantly reduces sulphate concentration in seawater and allows using it for commingled produced water re-injection (PWRI). Low sulphate seawater injection together with PWRI causes low injectivity decline and makes it feasible to apply in offshore waterflood projects.Planning and design of commingled PWRI with low sulphate seawater injection includes choice of the ratio “produced water:seawater”, determination of maximum allowed sulphate concentration in seawater after treatment, and injectivity decline prediction. The reliable design and plan is based on mathematical modelling with well-known model coefficients.In the current paper we derive an analytical model for the co-injection of low sulphate seawater with barium-containing produced water. Reagent and deposit concentrations along with the injectivity index are expressed by explicit formulae. It was found out that bulk sulphate deposition occurs in the 10–20 well radius neighbourhood. The injectivity decline is one order of magnitude higher than the productivity decline under similar reservoir conditions. Calculations for sulphate reduction plant have been performed for six fields of Campos Basin (Brazil).     

Potentials and prospects for renewable energies at global scale

Renewable energies (RE) represent a cornerstone to steer our energy system in the direction of sustainability and supply security. Generating electricity, heat or biofuels from renewable energy sources has become a high priority in the energy policy strategies at national level as well as at a global scale. Challenging goals for these “new” supply options to meet our energy demands have been set, e.g. at European level by the commitment of meeting 20% of the overall energy demand from renewable energy sources by 2020.     

A Talk between Flavonoids and Hormones to Reorient the Growth of Gymnosperms

Plants reorient the growth of affected organs in response to the loss of gravity vector. In trees, this phenomenon has received special attention due to its importance for the forestry industry of conifer species. Sustainable management is a key factor in improving wood quality. It is of paramount importance to understand the molecular and genetic mechanisms underlying wood formation, together with the hormonal and environmental factors that affect wood formation and quality. Hormones are related to the modulation of vertical growth rectification. Many studies have resulted in a model that proposes differential growth in the stem due to unequal auxin and jasmonate allocation. Furthermore, many studies have suggested that in auxin distribution, flavonoids act as molecular controllers. It is well known that flavonoids affect auxin flux, and this is a new area of study to understand the intracellular concentrations and how these compounds can control the gravitropic response. In this review, we focused on different molecular aspects related to the hormonal role in flavonoid homeostasis and what has been done in conifer trees to identify molecular players that could take part during the gravitropic response and reduce low-quality wood formation.     

Photodegradation of pentachlorophenol on ZnO

The photocatalytic degradation of pentachlorophenol on ZnO catalysts is reported. The studies were carried out in a conventional photoreactor at 298 K using 30 ppm of pentachlorophenol. Appropriate catalytic activity and high selectivity to mineralization products were found. A significant increase in the conversion was achieved at higher temperatures. No direct relationship between catalytic activity and specific area or bandgap was found. © 1998 SCI     

An Upgrade on the Surveillance System of SARS-CoV-2: Deployment of New Methods for Genetic Inspection

SARS-CoV-2 variants surveillance is a worldwide task that has been approached with techniques such as Next Generation Sequencing (NGS); however, this technology is not widely available in developing countries because of the lack of equipment and limited funding in science. An option is to deploy a RT-qPCR screening test which aids in the analysis of a higher number of samples, in a shorter time and at a lower cost. In this study, variants present in samples positive for SARS-CoV-2 were identified with a RT-qPCR mutation screening kit and were later confirmed by NGS. A sample with an abnormal result was found with the screening test, suggesting the simultaneous presence of two viral populations with different mutations. The DRAGEN Lineage analysis identified the Delta variant, but there was no information about the other three mutations previously detected. When the sequenced data was deeply analyzed, there were reads with differential mutation patterns, that could be identified and classified in terms of relative abundance, whereas only the dominant population was reported by DRAGEN software. Since most of the software developed to analyze SARS-CoV-2 sequences was aimed at obtaining the consensus sequence quickly, the information about viral populations within a sample is scarce. Here, we present a faster and deeper SARS-CoV-2 surveillance method, from RT-qPCR screening to NGS analysis.     

Characterization of Endogenous Levels of Brassinosteroids and Related Genes in Grapevines

Agronomic breeding practices for grapevines (Vitis vinifera L.) include the application of growth regulators in the field. Brassinosteroids (BRs) are a family of sterol-derived plant hormones that regulate several physiological processes and responses to biotic and abiotic stress. In grapevine berries, the production of biologically active BRs, castasterone and 6-deoxocastasterone, has been reported. In this work, key BR genes were identified, and their expression profiles were determined in grapevine. Bioinformatic homology analyses of the Arabidopsis genome found 14 genes associated with biosynthetic, perception and signaling pathways, suggesting a partial conservation of these pathways between the two species. The tissue- and development-specific expression profiles of these genes were determined by qRT-PCR in nine different grapevine tissues. Using UHPLC-MS/MS, 10 different BR compounds were pinpointed and quantified in 20 different tissues, each presenting specific accumulation patterns. Although, in general, the expression profile of the biosynthesis pathway genes of BRs did not directly correlate with the accumulation of metabolites, this could reflect the complexity of the BR biosynthesis pathway and its regulation. The development of this work thus generates a contribution to our knowledge about the presence, and diversity of BRs in grapevines.     

Influence of rheological behaviour on extrusion parameters during non-continuous extrusion of multi-base propellants

During the production of multi-base propellants, in order to identify both the optimal and safety conditions to be used at processing these rubber-like compounds, its rheological behaviour is considered as a key factor. Thus, an analysis of their rheological moduli at the end of the mixing stage and prior to the non-continuous extrusion (ram extrusion) is required so as to predict the optimum parameters to be assumed for both the mixing and extrusion processes. The rheological analysis of this multi-base propellant is carried out by means of a DHR-1 rotational rheometer of TA Instruments, and the complex modulus is proposed as a generalized indicator of the rheological response of these special materials. The complex interrelations among the main parameters of the extrusion process (steady extrusion pressure and extrusion ram velocity) together with the rheological properties of these multi-base propellants, will serve to deduce useful technical guidelines for improving the manufacturing system productivity, safety processing conditions and final product quality.     

Treatment of gasoline-contaminated waters by advanced oxidation processes

In this study, the efficiency of advanced oxidative processes (AOPs) was investigated toward the degradation of aqueous solutions containing benzene, toluene and xylenes (BTX) and gasoline-contaminated waters. The results indicated that BTX can be effectively oxidized by near UV-assisted photo-Fenton process. The treatment permits almost total degradation of BTX and removal of more than 80% of the phenolic intermediates at reaction times of about 30 min. Preliminary investigations using water contaminated by gasoline suggest a good potentiality of the process for the treatment of large volumes of aqueous samples containing these polluting species. Heterogeneous photocatalysis and H2O2/UV system show lower degradation efficiency, probably due to the heterogeneous character of the TiO2-mediated system and lost of photonic efficiency of the H2O2/UV system in the presence of highly colored intermediated.     

Praseodymium based high-k dielectrics grown on Si and SiC substrates

High-k polycrystalline Pr₂O₃ thin films have been deposited by metal organic chemical vapor deposition (MOCVD) technique on Si(0 0 1) and 4H–SiC(0 0 0 1) substrates. MOCVD processes have been carried out from the Pr(tmhd)₃ (H-tmhd= 2,2,6,6-tetramethyl-3,5-heptandione) precursor. Complete structural and morphological characterization of films has been carried out using several techniques (X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM)). Polycrystalline Pr₂O₃ films have been obtained and at the interface a praseodymium silicate amorphous layer has been observed on both substrates. The electrical properties of the dielectric praseodymium films have been evaluated.