Atomic layer deposition onto carbon fiber fabrics

Carbon fiber fabrics, consisting of interwoven bundles of 3000 single fibers, were coated with Al₂O₃ using the atomic layer deposition (ALD) process, exposing the fabrics to alternating pulses of trimethyl aluminium and water vapors. The thickness and uniformity of the coatings were investigated using scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). The obtained coatings were conformal, 84 ALD cycles gave rise to approximately 20‐nm‐thick coatings and 168 ALD cycles to approximately 40‐nm‐thick coatings. It was found, that a uniform coating can be obtained at a purge time of 40 seconds. Reducing purge times below 20 seconds gives rise to increased particle growth and thus the coating becomes inhomogeneous. Initially, the samples that were coated had a size of 2×10 cm (thickness 0.3 mm). The size of the fabric was subsequently increased up to 8×20 cm and a uniform coating of the same quality was obtained. By oxidizing the coated fabrics, fabrics composed of interwoven alumina microtubes were obtained. Infiltration of the microtubes with solutions of two distinguishable fluorescent dyes showed that interchange of the dyes between warp and weft microtubes occurs, but is absent at approximately 20% of the crossovers. Taking all our findings into account, we conclude that the majority of the fibers were separated from each other by the coating prior to the oxidation. This work demonstrates that ALD is a suitable method to produce thin, conformal coatings on the surface of carbon fiber fabrics.     

Effect of surfactants (PVB/EDTA/CTAB) assisted sol-gel synthesis on structural,magnetic and dielectric properties of NiFe2O4 nanoparticles

Nanocrystalline NiFe₂O₄ was synthesized by sol-gel route using various surfactants such as PVP, EDTA and CTAB. The effect of different surfactants on structure, magnetic and dielectric properties of the NiFe₂O₄ nanoparticles (NPs) were investigated. The prepared samples were inspected by XRD, HRSEM, and TEM. Powder XRD studies confirmed the realization of single crystalline cubic structure of the NiFe₂O₄ nanoferrites. The addition of surfactants significantly modified the crystallite size of the final products. Dielectric features of NiFe₂O₄ NPs were slightly modified with different surfactants. The magnetic results revealed an enormous decrease in coercivity and a moderate reduction in the saturation magnetization when EDTA and CTAB were used as compared to PVP. The present results declare that the adding of various surfactants in the sample preparation controls the size of NiFe₂O₄ NPs and thus noticeably influences the magnetic parameters.     

Use of an artificial mouth to study bread aroma

This work aimed to select artificial mouth extraction conditions to obtain an aroma extract of bread close to that perceived in the human mouth in terms of similarity and intensity. Once the representative extraction conditions were determined, they were used to show the influence of mastication and the effect of saliva on bread aroma release. The significance of mastication was shown by comparing headspace aromatic extracts with artificial mouth extracts. The results showed that headspace extraction, associated with a previous crushing of bread, did not provide an extract similar to that obtained after mastication. The determination of the influence of saliva on bread aroma was done respecting the ratio between saliva and bread in the human oral cavity. The results revealed that bread was crushed differently in the presence of saliva than in the presence of water. In addition, saliva had a significant influence on the volatile composition of bread extracts.     

Mapping burned areas and burn severity patterns in SW Australian eucalypt forest using remotely-sensed changes in leaf area index

Remote sensing is the most practical method available to managers of fire-prone forests for quantifying and mapping fire impacts. Differenced Normalised Burn Ratio (ΔNBR) is among the most widely used spectral indices for the mapping of burn severity but is difficult to interpret in terms of fire-related changes in key biophysical attributes and processes. We propose to quantify burn severity as a change in the leaf area index (ΔLAI) of a stand. LAI is a key biophysical attribute of forests, and is central to understanding their water and carbon cycles. Previous studies have suggested that changes in canopy LAI may be a major contributor to ΔNBR and to the composite burn index (CBI) that is frequently used in combination with the NBR to assess burn severity on the ground. We applied remotely-sensed ΔLAI to map burn severity in jarrah (Eucalyptus marginata) forest in south-western Australia burnt during the January 2005 Perth Hills wildfires. Ground-based digital photography was used to measure LAI in typical stands representing the full range of canopy densities present in the study area as well as variation in the time since the last fire. Regression models for the prediction of LAI were developed using NBR, the Normalised Difference Vegetation Index (NDVI) or the Simple Ratio (SR) as the independent variable. All three LAI models had equally high coefficients of determination (R²: 0.87) and small root mean squared errors (RMSE: 0.27–0.28). ΔLAI was calculated as the difference between pre- and post-fire LAI, predicted using imagery from January 2004 and February 2005, respectively. The area affected by the January 2005 fire and the burn severity patterns within that area were mapped using ΔLAI and ΔNBR. Landscape patterns of burn severity obtained from differencing pre- and post-fire LAI were similar to those mapped by ΔNBR. We conclude that fire-affected areas and burn severity patterns in the northern jarrah forest can be objectively mapped using remotely-sensed changes in LAI, while offering the important advantage over NBR of being readily interpretable in the wider context of ecological forest management.     

Microneedle Array-Based Platforms for Future Theranostic Applications

Theranostics involves finding the biomarkers of a disease, fighting them through site specific drug delivery and following them for prognosis of the disease. Microneedle array technology has been used for drug delivery and extended for continuous monitoring of analytes present in the skin compartment. We envisage the use of microneedle arrays for future theranostic applications. The potential of combining microneedle array-based drug delivery and diagnostics as part of closed-loop control system for the management of diseases and delivery of precision drugs in individual patients is reported in this paper.     

The effect of Cr alloying on defect migration at Ni grain boundaries

Journal of Materials Science - Mass transport along grain boundaries in alloys depends not only on the atomic structure of the boundary, but also its chemical make-up. In this work, we use...     

Intensive In-Center Hemodialysis for Children: A Case for Longer Dialysis Duration

Background:  Children with renal failure need their dialysis time optimized. Although traditional surrogate markers of outcome in pediatric patients have been growth and development, increasing attention is being focused on cardiovascular risk factors, such as hypertension, volume overload, malnutrition, and elevated calcium (Ca) and phosphorus (P) levels. We have previously shown catch-up growth without growth hormone, in children undergoing long intermittent hemodialysis. Recently we analyzed retrospectively cardiovascular risk factors in patients treated with this regimen.
Methods:  Patients starting dialysis between 1997 and 2001 and on dialysis at least 6 months were evaluated. Charts were reviewed for Ca, P, parathyroid hormone (PTH), albumin, hemoglobin and blood pressure levels, Ca intake, blood pressure medications, dialysis time, and clearance and ultrafiltration rates. Means were calculated for 6- month intervals, up to 36 months.
Results:  Mean equilibrated dialyzer Kt/V _urea ranged from 1.9 to 2.1, and mean weekly dialysis time for oliguric patients varied from 14.8 to 16.3 hr, with average hourly ultrafiltration rates from 0.3 to 0.4 L. Mean values for P and Ca × P were below 1.8 mM and 4.4 mmol   ² /L ² , respectively. Mean hemoglobin levels were 115 to 126 g/L, albumin 39 to 41 g/L, and PTH 156 to 231 pg/mL. Most patients had normal predialysis blood pressures.
Conclusions:  In this pediatric cohort, intensive center hemodialysis was associated with excellent growth, nutrition, Ca, P, and anemia control and reasonable blood pressure values. Large multicenter studies are needed to better determine optimal dialysis therapy for children.