Design of Lu2O3-reinforced Cf/SiC-ZrB2-ZrC ultra-high temperature ceramic matrix composites: Wetting and interfacial reactivity by ZrSi2 based alloys

The wettability and infiltration of molten ZrSi₂ and ZrSi₂-Lu₂O₃ alloys into C_f/SiC and B₄C-infiltrated C_f/SiC composites were investigated to understand the interfacial interactions that occur during the development of C_f/SiC-ZrC and C_f/SiC-ZrB₂-ZrC-Lu₂O₃ materials. A significant evaporation of Si from the liquid affected the wetting behaviour of the alloy when tested in a vacuum at 1670 °C. The better wetting and spreading of the alloy over the surface was observed for the composites with lower overall porosity (12 %). On the other hand, the formation of an outer dense layer, followed up by the uniform infiltrated region up to ～ 1 mm was observed for the C_f/SiC with higher porosity (21 %). The infiltrated alloy reacted with SiC matrix to form ZrC or with B₄C-infiltrated SiC matrix to form ZrB₂-ZrC-SiC. The Lu₂O₃ particles were not wetted by the melt, and were pushed away of the reaction zone by the solidification front.     

Mild Stereoselective Intermolecular Acetoxylation and Azidation of α‐C−H Bonds in Tröger's Bases

Introduction of oxygen and nitrogen into organic molecules is one of the fundamental strategies for their functionalization. Traditional approaches rely on the formation of an activated intermediate, which is then modified in a subsequent step. Here we report a simple direct oxidative α‐acetoxylation and azidation of α‐C−H bonds in Tröger's base analogues promoted by N‐bromosuccinimide (NBS) and palladium(II)acetate [Pd(OAc)₂] under mild conditions. This approach is pivotal on NBS oxidizing the carbon atoms next to the nitrogen atoms in the presence of Pd(OAc)₂ followed by a reaction with oxygen‐ or nitrogen‐centred nucleophiles such as KOAc or NaN₃ to yield either the mono‐ and bisacetoxylated or azidated Tröger's base derivatives in a stereo‐ and chemoselective manner. The obtained products can be efficiently modified to access synthetically meaningful structures.

     

Neutron Powder Diffraction Study of Y-Sialon with La2O3 or Nd2O3 Addition

Neutron diffraction data of α-sialon and complementary phases were collected on the neutron powder diffraction (NPD) diffractometer installed in the NFL Studsvik, at a wavelength of 1.470 Å. Calculations were carried out by using the FullProf 2000 utilizing the crystal structure of the yttrium α-sialon phase. Selected profile and structure parameters were refined in the calculations. The calculated data showed that either La or Nd were also present in the α-sialon crystal structure in the presence of Y. The comparison of the present phases' weight contents, which were determined by the qualitative phase analysis between NPD and X-ray diffraction data, was carried out.     

Effects of Salvia officinalis and Thymus vulgaris on oxidant-induced DNA damage and antioxidant status in HepG2 cells

Salvia officinalis (SO) and Thymus vulgaris (TV) are medicinal plants well known for their curative powers. However, the molecular mechanisms responsible for these abilities of sage and thyme have not been fully understood yet. In this study we investigated the composition and the quantitative estimation of plant extracts, the protective effects of plant extracts against hydrogen peroxide- and 2,3-dimethoxy-1,4-naphthoquinone-induced DNA damage, and levels of enzymatic and non-enzymatic antioxidants (superoxide dismutase, glutathione peroxidase, glutathione) in human HepG2 cells. To measure antioxidative activity of plant extracts we used three assays: 1,1-diphenyl-2-picrylhydrazyl (DPPH), ferric reducing antioxidant power (FRAP) and 2,2′-azinobis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS). The results showed that the oxidant-induced DNA lesions were significantly reduced in cells pre-treated with the plant extracts studied. The observed DNA-protective activity could be explained by both elevation of GPx activity in cells pre-treated with SO and TV and antioxidant activity of SO and TV.     

Design procedure of simple and accurate model of electric double layer capacitor (EDLC) targeting fast verification purposes of heat transfer simulations

From the macrostructure of electric double layer capacitor (EDLC) and from heat transfer point of view, the volumetric properties of EDLC act as surrounding anisotropy. The core of the supercapacitor is made of coil, which is composed of a number of turns. This coil is from the physical aspect represented as a anisotropic structure that has to be considered during the design of a 3D model. Such structure of capacitor’s core is then in axial direction geometrically and physically different comparing to radial direction. This results in diverse expression of thermal conductivities in the mentioned directions. Therefore, it is necessary to analytically determine axial and radial parts of heat conduction thus avoiding high degree of thermal model’s complexity. After mathematical analysis, this paper will also describe the procedure of design of the EDLC thermal simulation model. During development of EDLC thermal model, and for computational and simulation purposes, the CFD software, COMSOL 3.5a, has been used. The principal aim was to reach very close proximity of the simulation results as compared to measurements, and simultaneously achieve very low computational time. Targeting high degree of model’s accuracy, several alternatives of model complexity will be shown.     

Experimental Method for Complex Thermo-mechanical Material Analysis

An experimental system for complex thermo-mechanical material analysis is presented in this article. The system provides simultaneous measurements of tensile properties as well as heat generation in the process of tensile deformation. The cooling curve of the sample after its reversible deformation was measured. On the basis of an exponential model of a cooling body with respect to the Biot number Bi, it is possible to calculate the specific heat capacity c _p , the thermal diffusivity α, and the thermal conductivity k. The method had been tested on a variety of materials and the results were compared to those in the technical literature or obtained by reference independent experiments and showed very good agreement.     

Bestimmung von feuchtetechnischen Materialparametern ausgewählter Baumaterialien für die rechnerische Bewertung von Baukonstruktionen unter den Bedingungen in der Slowakei

Für die Bewertung des Bestandes mit nichtstationären Verfahren sind genaue und umfangreiche Eingabedaten erforderlich. Neben fehlenden Klimadaten sind die unvollständigen Materialdaten häufige Ursache für die schleppende Überführung moderner Rechenverfahren in die Praxis. Es wurden Parameter für ausgewählte, im Plattenbau typische Baumaterialien bestimmt. Determining the moisture parameters of selected building materials for the computational assessment of constructions under the conditions in Slovakia. Accurate and extensive input data are required for assessing existing buildings, using dynamic procedures. Missing meteorological data as well as incomplete materials data are often the reason why people are slow to put modern calculation methods into practice. Parameters were determined for selected building materials typical of buildings constructed from large prefabricated concrete slabs.     

An interpretation of the changes in demographic behaviour at a sub-national level using spatial measures in post-socialist countries: A case study of the Czech Republic and Slovakia

The transformation of fertility and family behaviour in post-socialist countries was quick and the changes were striking. An account of the changes is the subject of dispute and the mechanisms have still not been explained in a fully satisfying manner. Relatively little attention has been paid to the changes in spatial aspects concerning the broadening of changes in family behaviour. The aim of this paper is to answer the question as to whether changes spread stochastically in post-socialist countries or if there are obvious spatial patterns. The study tries to answer the questions whether there are any cores of changes which may be understood as innovations, if there is any spatial clustering and if the extent is hierarchically arranged.