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991.
煤直接液化中SO2-4 /ZrO2固体酸的催化作用 总被引:1,自引:0,他引:1
以二苯甲烷、苯乙醚为煤的模型化合物,以四氢萘(THN)为溶剂,进行中高压加氢液化实验,结合产物的气相色谱和质谱分析,考察了SO2-4/ZrO2固体酸对煤直接液化的催化作用及加氢液化机理.实验结果表明,SO2-4/ZrO2固体酸对模型化合物的转化具有良好的催化活性,与非催化液化相比,400 ℃、H2初压5 MPa、30 min时二苯甲烷的转化率由8.96%提高到61.75%,且模型化合物的存在促进了溶剂THN的转化,上述条件下THN的转化率也达到10.92%;模型化合物及THN的转化主要包括氢解、异构、氢转移及烷基化等反应;SO2-4/ZrO2固体酸的催化作用主要为酸催化的离子反应机理,增强催化剂的酸性有利于煤的催化液化. 相似文献
992.
References: 《中国炼油与石油化工》2007,(3):35-42
The proton nuclear magnetic resonance spectroscopy (1H-NMR), the synchronous fluorescence spectrometry (SFS) and the ruthenium ions catalyzed oxidation (RICO) method were used to determine the chemical structure of polyaromatic nucleus in Oman residue fractions. The results of 1H-NMR analyses showed that the average numbers of aromatic rings in the aromatics, resins and asphaltenes units were 3.2, 5.6 and 8.2, respectively. SFS was used to investigate the distribution of aromatic rings in residue fractions, the main distribution range of aromatic rings in aromatics, resins and asphaltenes were 3 4 rings, 3--5 rings and more than 5 rings, respectively. The aromatic network in residue fractions was oxidized to produce numerous carboxylic acids. The types and content of benzenepolycarboxylic acids, such as phthalic acid, benzenetricarboxylic acids, benzenetetracarboxylic acids, benzenepentacarboxylic acid and benzenehexacarboxylic acid disclosed the condensed types of aromatic nuclei in the core. The biphenyl fraction (BIPH), the cata-condensed fraction (CATA), the peri-condensed fraction (PERI) and the condensed index (BCI) were calculated based on the benzenepolycarboxylic acids formed. The results implied that there was less biphenyl type structures in all residue fractions. The aromatics fraction was almost composed of the cata-condensed type system, and the asphaltenes fraction was wholly composed of the peri-condensed type system, while in the resins fraction co-existed the two types, herein the peri-con- densed type was predominant over the cata-condensed type. Based on the analytical results obtained in the study, the components --aromatics, resins and asphaltenes -- were given the likely structural models. 相似文献
993.
Jing Wang Walker D.M. Xiang Lu Majhi A. Kruseman B. Gronthoud G. Villagra L.E. van de Wiel P.J.A. Eichenberger S. 《Design & Test of Computers, IEEE》2007,24(3):226-234
Excessive power supply noise during test can cause overkill. This article discusses two models for supply noise in delay testing and their application to test compaction. The proposed noise models avoid complicated power network analysis, making them much faster than existing power noise analysis tools. can cause performance degradation and 相似文献
994.
An analytical current-voltage (I -V ) model for planar-doped HEMTs is developed. This compact model covers the complete range of I -V characteristics, including the current saturation region and parasitic conduction in the electron-supplying layer. Analytical expressions for the small-signal parameters and current-gain cutoff frequency are derived from the I -V model. Modeling results for a 0.1-μm-gate planar-doped AlInAs-GaInAs HEMT show excellent agreement with measured characteristics. Threshold voltages and parasitic conduction in planar-doped and uniformly doped HEMTs are also compared and discussed 相似文献
995.
本文分析了Seya-Namioka系统光学参数与离焦量的关系,为选取最佳光学参数提供了依据。同时,简要说明了影响谱线质量及波长读数精度的因素,并讨论了补偿波长读数误差的方法。 相似文献
996.
当前水价改革中迫切需要注意的问题 总被引:5,自引:0,他引:5
加强水价改革,提高水价,促进节约用水,已经成为全社会关注的焦点。在节约用水和水资源优化配置条件下如何确定水价,水价构成及供水企业的合理成本与利润,以及资源水价的分配和用途是当前水价改革中亟须研究探讨和重视的问题。商品水价应该包括三个部分:一是资源水价,二是工程水价,三是环境水价。只有包括资源因素的水价,才能真正发挥水价在水资源的优化配置和合理利用方面的调节作用。 相似文献
997.
A newly developed catalyst type DVR-1 for catalytic cracking of Daqing vacuum resid was put into use in a commercial VRFCC unit,This catalyst features uniquely active matrix and modified ultra-stable zeolite.The commercial application results show that the DVR-1 type catalyst has the advantage of high heavy oil conversion,good metal tolerance nd gooed stability for catalyst regeneration,The FCC tests have shown Favorable product distribution,acceptable product quality and enormaous economic benefits whe processing the feedstock containin 75%-100% Daqing VR. 相似文献
998.
Multicasting in a class of multicast-capable WDM networks 总被引:1,自引:0,他引:1
Yang Wang Yuanyuan Yang 《Lightwave Technology, Journal of》2002,20(3):350-359
Multicast is the ability to transmit information from a single source node to multiple destination nodes. Multicast can be supported more efficiently in optical domain by utilizing the inherent light-splitting capacity of optical switches than by copying data in electronic domain. In this paper, we study multicast communication in a class of multicast-capable WDM networks (i.e., the networks that have light splitting switches) with regular topologies under some commonly used routing algorithms. Upper and lower bounds on the minimum number of wavelengths required are determined for a network to be rearrangeable for arbitrary multicast assignments, and compared with those WDM networks without light splitting switches. Our results indicate that in most of the networks we study, the number of wavelengths required can be significantly reduced by utilizing light splitting switches 相似文献
999.
1000.
Integrating heterogeneous distributed COTS discrete-event simulation packages: an emerging standards-based approach 总被引:2,自引:0,他引:2
Taylor S.J.E. Xiaoguang Wang Turner S.J. Low M.Y.H. 《IEEE transactions on systems, man, and cybernetics. Part A, Systems and humans : a publication of the IEEE Systems, Man, and Cybernetics Society》2006,36(1):109-122
This paper reports on the progress made toward the emergence of standards to support the integration of heterogeneous discrete-event simulations (DESs) created in specialist support tools called commercial-off-the-shelf (COTS) discrete-event simulation packages (CSPs). The general standard for heterogeneous integration in this area has been developed from research in distributed simulation and is the IEEE 1516 standard The High Level Architecture (HLA). However, the specific needs of heterogeneous CSP integration require that the HLA is augmented by additional complementary standards. These are the suite of CSP interoperability (CSPI) standards being developed under the Simulation Interoperability Standards Organization (SISO-http://www.sisostds.org) by the CSPI Product Development Group (CSPI-PDG). The suite consists of several interoperability reference models (IRMs) that outline different integration needs of CSPI, interoperability frameworks (IFs) that define the HLA-based solution to each IRM, appropriate data exchange representations to specify the data exchanged in an IF, and benchmarks termed CSP emulators (CSPEs). This paper contributes to the development of the Type I IF that is intended to represent the HLA-based solution to the problem outlined by the Type I IRM (asynchronous entity passing) by developing the entity transfer specification (ETS) data exchange representation. The use of the ETS in an illustrative case study implemented using a prototype CSPE is shown. This case study also allows us to highlight the importance of event granularity and lookahead in the performance and development of the Type I IF, and to discuss possible methods to automate the capture of appropriate values of lookahead. 相似文献