A series of 2′,7′‐diarylspiro(cyclopropane‐1,9′‐fluorene) derivatives are efficiently synthesized and characterized to determine the reason for the “green‐light” emission of these compounds. These compounds exhibit bright‐violet to blue photoluminescence (PL) (λPLmax = 353–419 nm) with excellent PL quantum efficiencies (ΦPL = 83–100 %) in solution and show high thermal stabilities (Td = 267–474 °C). The variation of the optical properties of these molecules in the solid state depends on the different stacking modes of these compounds containing different substituents, which are revealed by crystallographic analysis. CH…π hydrogen bonds instead of intermolecular π–π interactions act as the driving force between adjacent fluorenes, even though a very small dialkyl group (cyclopropane) is introduced at the C‐9 position of fluorene. The crosslike molecular stacking efficiently reduces the energy transfer between the herring‐like aggregates and therefore results in the absence of a “green‐light” emission tail. In order to determine the cause of the “green‐light” emission tails, the fluorescence spectra of the films annealed in N2 or in air are recorded. Broad green‐light emission tails were observed for the films annealed in air, which might be caused by fluorenone defects generated during processing or during the course of the photophysical analysis by reaction with residual oxygen. 相似文献
A novel approach of unitarily interpolated array MVDR （UIA-MVDR） is proposed, aiming at avoiding the signal cancellation caused by broadband signal-correlated interferences. UIA-MVDR belongs to the classic approaches of spectral averaging. However, it is distinguished from the conventional interpolated array MVDR （IA-MVDR） by two points： 1） It imposes a unitary constraint on the transform matrices. 2） It only optimizes the worst-case performance of array manifold approximation. As a result, the restriction on the order of Bessel function expansion is released, so that very accurate approximation can be achieved even in the case of small or middle arrays. Compared with many related approaches, UIA-MVDR destroys the correlation more completely and then achieves better performance. Its excellent performance in both correlated and uncorrelated broadband interferences suppression is confirmed via a n umber of numerical examples. 相似文献
Based on a Marx generator and a coaxial pulse forming line, an experimental investigation of surface flashover characteristics in vacuum is conducted by using nanosecond pulses of 10 ns rise time and 30 ns full width at half maximum (FWHM). Insulator dielectrics chosen for this investigation are Teflon, PMMA and Nylon. The tested factors include gas pressure, cone angle of conical frustum, diameter and length of cylindrical insulator, material and shape of electrode, and contact style between insulator and electrodes. The effects of these parameters on the surface flashover characteristics are described and analyzed in this paper. In addition, the character of flashover time lag in the nanosecond range, and surface flashover theory in vacuum charged by nanosecond pulses are also discussed. 相似文献
We report the direct observation of coupling between a single self-assembled InAs quantum dot and a wetting layer, based on strong diamagnetic shifts of many-body exciton states using magneto-photoluminescence spectroscopy. An extremely large positive diamagnetic coefficient is observed when an electron in the wetting layer combines with a hole in the quantum dot; the coefficient is nearly one order of magnitude larger than that of the exciton states confined in the quantum dots. Recombination of electrons with holes in a quantum dot of the coupled system leads to an unusual negative diamagnetic effect, which is five times stronger than that in a pure quantum dot system. This effect can be attributed to the expansion of the wavefunction of remaining electrons in the wetting layer or the spread of electrons in the excited states of the quantum dot to the wetting layer after recombination. In this case, the wavefunction extent of the final states in the quantum dot plane is much larger than that of the initial states because of the absence of holes in the quantum dot to attract electrons. The properties of emitted photons that depend on the large electron wavefunction extents in the wetting layer indicate that the coupling occurs between systems of different dimensionality, which is also verified from the results obtained by applying a magnetic field in different configurations. This study paves a new way to observe hybrid states with zero- and two-dimensional structures, which could be useful for investigating the Kondo physics and implementing spin-based solid-state quantum information processing.
