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181.
立方相GaN的持续光电导 总被引:1,自引:1,他引:0
研究了金属有机物化学气相外延 (MOVPE)方法生长的非故意掺杂的立方相 Ga N的持续光电导效应 .在六方相 Ga N中普遍认为持续光电导效应与黄光发射有关 ,而实验则显示在立方 Ga N中 ,持续光电导效应与其中的六方相 Ga N夹杂有关系 ,而与黄光发射没有关系 .文中提出 ,立方相 Ga N与其中的六方相 Ga N夹杂之间的势垒引起的空间载流子分离是导致持续光电导现象的物理原因 .通过建立势垒限制复合模型 ,解释了立方相 Ga N的持续光电导现象的物理过程 ,并对光电导衰减过程的动力学作了分析 .对实验数据拟合的结果证明以上的模型和推导是与实验相符的 . 相似文献
183.
Five new salts based on 1-alkyl-2-methyl pyrrolinium ion are reported, two involving the iodide ion and three involving the bis(trifluoromethanesulfonyl) amide ion. The iodide salts have melting points around 100 °C, while the amide salts have melting points around room temperature. Two of the amide salts can be easily quenched into the glassy state and exhibit glass transition temperatures around −70 °C. The 2-methyl pyrrolinium cation bears structural similarities to the aromatic imidazolium cations on one hand and the cyclic ammonium cation family based on the pyrrolidinium cation on the other. The properties of the salts reported here are compared within these two related families of salts. 相似文献
184.
Elastic solutions of a cylindrical rod containing periodically distributed inclusions with axisymmetric eigenstrains 总被引:1,自引:0,他引:1
Summary. In this paper, we give the elastic solution for a special type of microstructure – a circular cylindrical rod containing periodically distributed inclusions along its axial direction. Each inclusion has the same uniform axisymmetric transformation strain (eigenstrain). Analytical elastic solutions are obtained for the displacements, stresses and elastic strain energy of the rod. The effects of microstructure and its evolution (growth of inclusions) on the elastic stress and strain fields as well as the strain energy of the rod are quantitatively demonstrated. As a result of such microstructure evolution nominal stress-strain relation with strain softening is derived for a rod under uniaxial tension. 相似文献
185.
186.
Pressure-sensitive acrylic adhesives for application to skin are made from 2-ethylhexyl acrylate, isooctyl acrylate or n-butyl acrylate copolymerized with polar functional monomers such as acrylic acid, methacrylic acid, vinyl acetate, methyl acrylate, N-vinylcaprolactam, or hydroxyethyl methacrylate. Functional comonomers increase cohesive strength, provide surface polarity, and enhance wear performance. Tack, adhesion to skin, adhesive transfer to skin, and wear performance of the adhesive are governed by the molecular weight, glass transition temperature, and the viscoelastic behavior of the adhesive. Viscoelastic properties of the adhesive as measured by the Williams plasticity number (WPN), dynamic storage modulus (G′), dynamic loss modulus (G″), and tan δ are important polymer properties for good wear performance. Sweating skin, a moist environment, and physical activity are the most important factors influencing the failure of an adhesive tape during wear. A medicalgrade adhesive for application to human skin should be hypoallergenic. Medical-grade adhesives are utilized in making surgical tapes for holding dressings in place, adhesive bandages, adhesive dressings to cover wounds, and surgical operating drapes. 相似文献
187.
Summary Sedimentation experiments and X-ray photoelectron spectroscopy (XPS or ESCA) analyses have been used to study the effect of poly(methylmethacrylate) (PMMA) tacticity on aluminum oxide powder dispersion stability in a common solvent medium. The relative trends from sedimentation densities, and from surface analyses after solvent washing show that (PMMA) adsorption is greatest with isotactic polymer, where isotactic>atactic>syndiotactic adsorption. These results suggest that surface adsorption and hence dispersion stability can be influenced by polymer chain configuration as well as by chain conformation. 相似文献
188.
乙烯-1-辛烯共聚物增韧应用研究 总被引:3,自引:0,他引:3
介绍了聚烯烃系弹性体(POE)的特点及其在PP增韧改性中的应用,同时还报道了马来酸酐接枝的POE在极性聚合物复合体系中的应用研究。 相似文献
189.
Using a linear voltage ramp method, ultraslow dielectric relaxation processes of La-doped BaTiO3 boundary layer (BL) capacitors are measured at room temperature. For the electric polarization model of a double-layer dielectric, a procedure to calculate the electrical parameters of grain and grain boundary has been developed. Calculated results suggest that there is a shell on the surface of the grain. TEM images of the BL capacitor also show a lot of microregions with minor structural modifications. Relaxation times are estimated from the equivalent circuit and are in agreement with fitted results. 相似文献
190.
En-Hai Sun Yong-Ho Choa Tohru Sekino Tomohiko Adachi Koichi Niihara 《Materials Research Innovations》2002,6(3):105-111
Cordierite/ZrO2 composites with 5 to 25 wt% ZrO2 were fabricated by conventional powder mixing and pressureless sintering method. Their densification behavior, microstructure,
mechanical and thermal properties were studied. By dispersing 25 wt% (9.57 vol%) ZrO2, densified cordierite/ZrO2 composite with a relative density of 98.5% was obtained at an optimum sintering condition of 1440 °C and 2 h. ZrO2 particles were homogenously dispersed within matrix grains and at the grain boundaries. The intragranular particles were
finer than 100 nm and the intergranular particles were coarser. Both fracture strength and toughness could be enhanced more
than two times higher, compare to those of monolithic cordierite, by dispersing 25 wt% ZrO2 into the cordierite matrix. The toughening mechanism in the present composites was mainly attributed to martensitic transformation
due to ZrO2 dispersion.
Electronic Publication 相似文献