Poly(trimethylene terephthalate) nanocomposite fibers comprising different organoclays: Thermomechanical properties and morphology

Poly(trimethylene terephthalate) (PTT) nano composites were synthesized by in situ polymerization at high temperature with two thermally stable organoclays: 1,2‐dimethylhexadecylimidazolium‐montmorillonite (IMD‐MMT) and dodecyltriphenyl phosphonium‐MMT (C₁₂PPh‐MMT). PTT hybrid fibers with various organoclay contents were melt‐spun at various draw ratios (DRs) to produce monofilaments. The thermomechanical properties and morphologies of the PTT hybrid fibers were characterized using differential scanning calorimetry, thermogravimetric analysis, wide‐angle X‐ray diffraction, electron microscopy, and mechanical tensile properties analysis. The nanostructure of the hybrid fibers was observed by both scanning and transmission electron microscopy, which showed that the clay layers were well dispersed into the matrix polymer, although some clusters or agglomerated particles were also detected. Unlike the hybrids containing IMD‐MMT, the clay layers of the C₁₂PPh‐MMT hybrid fiber were more dispersed into the matrix polymer. The thermal stability and tensile properties of the hybrid fibers increased with increasing clay content for DR = 1. However, as DR increased from 1 to 9 the ultimate strength and initial modulus of the hybrid fibers with IMD‐MMT increased slightly whereas those of C₁₂PPh‐MMT hybrid fibers decreased slightly. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4535–4545, 2006     

烟气脱硫的发展、技术与产业化探讨

回顾了我国烟气脱硫的发展历程 ,总结了我国烟气脱硫产业化方面取得的成绩和存在的问题 ,介绍了国际上烟气脱硫发展的基本情况     

密炼机转子铜瓦椭圆的修复方法

简要介绍了一种XHM253/20密闭式炼胶机转子铜瓦椭圆的修复方法.该方法简便易行,修复工期短,修复质量高,在实际工作中具有一定参考价值.     

Preparation of poly(ethylene terephthalate) nanocomposite fibers incorporating a thermally stable organoclay

Summary A series of poly(ethylene terephthalate) (PET) nanocomposites containing organically-modified mica (HB-Mica) were prepared by in-situ interlayer polymerization of dimethyl terephthalate and ethylene glycol. The PET nanocomposites, which contained organoclay loadings of 0 to 2 wt %, were melt-spun to produce monofilaments with various draw ratios. Some of the clay particles appeared well dispersed within the PET matrix, while others were found to form agglomerates with sizes greater than 20 nm. The addition of a small amount of organoclay was sufficient to improve the thermo-mechanical properties of the PET hybrid fibers. Both the thermal stability and the mechanical tensile properties increased with increasing clay content for draw ratios of 1–16.     

基于IOS平台的小型仓储管理系统设计

随着数字化、信息化技术在物流领域应用的飞速发展,各种各样的仓储管理系统日益受到关注。本文介绍的基于IOS平台的小型仓储管理系统是利用IOS设备对货物信息进行采集,通过SQLite数据库技术、ZXing库等软硬件方式构建的业务系统,可以较好地适应中小规模用户数据交互的需求。同时,系统具备造价低廉、操作便捷等优点。     

雷达吸波材料的研究现状及发展前景

首先阐述了吸波材料的研究意义,然后综合讨论了吸波材料的工作原理、类型以及研究现状, 最后介绍了吸波材料在军事方面的应用及未来的发展趋势。     

脱乙烷系统参数优化

吉化300kt/a乙烯装置脱乙烷系统采用德国Linde公司双塔双压前脱乙烷技术，自1996年开始以来，运行良好，通过工程技术人员近两年的探索实践，对其工艺参数做了较大的优化调整，取得了较好的经济效益。     

A novel cyclodextrin-derived tellurium compound with glutathione peroxidase activity

A novel dicyclodextrinyl ditelluride (2-TeCD) compound was devised as a functional mimic of the glutathione peroxidase (GPX) enzymes that normally remove hydroperoxides from the cell. The GPX activity of the mimic was found to be 46.7 U microM(-1), which is 46 times as active as Ebselen, a well-known GPX mimic. A detailed steady-state kinetic study was undertaken to probe the reason for the high catalytic efficiency of 2-TeCD. This high efficiency can be explained based on both the binding of the substrate to the cyclodextrin and the catalytic mechanism of 2-TeCD, which is different from that of diselenide compounds. 2-TeCD exhibits good water solubility and is chemically and biologically stable. The biological effect of 2-TeCD was evaluated by its ability to protect mitochondria from oxidative damage. 2-TeCD exhibited excellent antioxidant capacity in comparison with Ebselen.     

Al ionic radius influence on molecular dynamics simulations ofγ-Al2O3

Molecular dynamics (MD) simulations of-Al₂O₃, using a pairwise additive interaction potential of Pauling's type with four different radii for aluminum atoms, were analysed in order to determine the influence of the radius on the modification of coordination numbers of A1 relative to the ideal structure, at two different temperatures of 300 and 1500 K. It is found that the best choice is the radius of penta-coordinated aluminum, reproducing structural and vibrational properties of the compound in excellent agreement with experimentally observed properties.     

Si3N4陶瓷材料的高温氧化理论及其抗氧化研究现状

从热力学、动力学和整体控速过程探讨了氮化硅陶瓷材料高温氧化理论和氧化性质，阐述了表面改性技术对氮化硅抗氧化性能的影响．并对表面改性提高氮化硅抗氧化性能进行了展望。