Size‐dependent optical properties of transparent,spin‐coated polystyrene/ZnO nanocomposite films

Zinc oxide (ZnO) nanoparticles are synthesized using a simple chemical method at room temperature. A variation in molar concentration of the precursor, potassium hydroxide, from 0.25 to 0.01 mol L^?1 is accompanied by a decrease in the average size of the nanoparticles. These nanoparticles are used for the preparation of polystyrene/ZnO nanocomposite films using the spin‐coating technique. These films are found to be highly transparent throughout the visible region and absorb UV light in the region from 395 to190 nm, almost covering the near and middle UV ranges (400 to 200 nm). This observation highlights the possible prospects of these films in UV shielding applications. The wavelength corresponding to the onset of UV absorption is found to be blue shifted with a decrease in size of the ZnO particles in the composite films due to confinement effects. The photoluminescence spectra of the composite films also change as a function of particle size. The emissions at longer wavelength due to defects and impurity‐related states in ZnO are almost quenched as a result of surface modification by the polymer matrix. The observed band‐gap enlargement with a decrease in size of the ZnO particles in the composite films is significant for band‐gap engineering of nanoparticles for various applications. Copyright © 2011 Society of Chemical Industry     

Selective Oxidation of n-Pentane Over V2O5 Supported on Hydroxyapatite

The catalytic efficiency of V₂O₅ supported on hydroxyapatite in controlled oxidation of n-pentane to phthalic anhydride and maleic anhydride is investigated as function of flux rates of the reactants and temperature in the gas- phase in a fixed- bed stainless steel microreactor under steady state conditions. The hydroxyapatite was prepared by co-precipitation and the loaded catalysts by wet impregnation using NH₄VO₃ solution. Selectivity towards the products was influenced by the total flow rate, reaction temperature and V₂O₅ loadings. Good selectivities towards the anhydrides (MA 40% and PA 25%) is obtained with 5.0 and 7.5 wt.% of V₂O₅ at 360 °C.     

Engaging zwitterions in carbon-carbon and carbon-nitrogen bond-forming reactions: A promising synthetic strategy

An Account of carbon-carbon and carbon-nitrogen bond-forming reactions mediated by zwitterions generated by the addition of organic nucleophiles to activated unsaturated systems highlighting their synthetic potential is presented.     

Effect of system optimizing conditions on biohydrogen production from herbal wastewater by slaughterhouse sludge

The study evaluates the biohydrogen production from herbal wastewater as the substrate by the enriched mixed slaughterhouse sludge as the seed source. In the following experiments, batch-fermentations are carried out with the optimum substrate concentrations, fermentation pH and fermentation temperature to observe the effects of H₂ production, hydrogen yield and other fermentation end products at different conditions. The hydrogen production is increased as substrate concentration increased up to 8 g COD/L WW, but drastically decreased at 10 g COD/L WW. When the pH of fermentation is controlled to 6.5, a maximum amount of hydrogen yield could be obtained. The hydrogen production is maximum at 50 °C (930 ± 30 mL/L WW) compared to 30 °C (436 ± 16 mL/L WW). Acid-forming pathway with butyric acid as a major metabolite dominated the metabolic flow during the hydrogen production. The experimental results indicated that effective hydrogen production from the herbal wastewater could be obtained by thermophilic acidogenesis at proper operational conditions.     

Transient Thermal Behavior and Stress Development within a Cylindrical Wooden Disk during Drying in a Fluidized Bed Dryer

Thermal behavior and stresses developed in a wood particle are predicted using a mathematical model formulated for drying in fluidized bed. Drying experiments have been carried out on 10 mm long and 30 mm diameter cylindrical disks at a bed temperature of 403 K (130°C). Drying time, mass reduction, and shrinkage during drying have been measured and used to validate the thermal model. The stress model is validated with an analytical solution available in literature. The drying time is experimentally found to be 630 s. The wood particle shrinks by 4.6% in the radial direction and by 1.0% in the longitudinal direction. The model indicates splitting failure at the circumference, which was also noticed during experiments.     

Effect of replacement of castor oil and polychloroprene by chlorinated paraffin in butyl compounds of tyre‐curing bladder

Ways are explored to increase the life and to reduce the cost of tyre‐curing bladders by improving their mechanical and ageing properties. Nine formulations have been designed which involve the partial replacement of polychloroprene (PC) and castor oil (CO), both individually and simultaneously, by chlorinated paraffin (CP) in the butyl bladder compound. The compounds have been tested for various cure properties such as initial torque, minimum torque, scorch time, optimum cure time, cure rate, maximum torque and reversion time. The vulcanized samples have been tested for mechanical properties such as tensile stress at 300 % elongation, tensile strength at break, ultimate elongation, rubber deterioration by dynamic fatigue test and Shore‐A hardness before and after ageing. The results show that tensile strength at break and ultimate elongation decrease, while tensile stress at 300 % elongation increase except in one case (when PC was partially replaced by CP). Simultaneous and individual replacement of CO by CP results in a decrease in hardness of up to 3 phr (base recipe CO 5 phr), whereas further replacement of CO by CP results in an increase in hardness. Tensile stress at 300 % elongation and Shore‐A hardness increase up to a limit while tensile strength at break and ultimate elongation decrease with ageing. © 2000 Society of Chemical Industry     

Viscosity of SiO2-“FeO”-Al2O3 System in Equilibrium with Metallic Fe

The present study delivered the measurements of viscosities in SiO₂-“FeO”-Al₂O₃ system in equilibrium with metallic Fe. The rotational spindle technique was used in the measurements at the temperature range of 1473 K to 1773 K (1200 °C to 1500 °C). Molybdenum crucibles and spindles were employed in all measurements. The Fe saturation condition was maintained by an iron plate placed at the bottom of the crucible. The equilibrium compositions of the slags were measured by EPMA after the viscosity measurements. The effect of up to 20 mol. pct Al₂O₃ on the viscosity of the SiO₂-“FeO” slag was investigated. The “charge compensation effect” of the Al₂O₃ and FeO association has been discussed. The modified quasi-chemical viscosity model has been optimized in the SiO₂-“FeO”-Al₂O₃ system in equilibrium with metallic Fe to describe the viscosity measurements of the present study.     

Bismuth Sulfonate Immobilized on Silica Gel for Allylation of Aldehydes and Synthesis of Homoallylic Amines

Catalytic allylation of aldehydes and the synthesis of homoallylic amines using bismuth sulfonate immobilized on silica gel in presence of allyltributylstannane are reported for the first time. The reaction proceeds smoothly with the aid of benzoic acid as an additive and provides corresponding homoallylic alcohols and homoallylic amines in good yields. The catalyst can be reused five times without significant loss of the catalytic activity. Bismuth Sulfonate Immobilized on Silica gel for Allylation of Aldehydes and Synthesis of Homoallylic Amines.     

Stochastic and Robust Multi-Objective Optimal Management of Pumping from Coastal Aquifers Under Parameter Uncertainty

Combined simulation-optimization approaches have been used as tools to derive optimal groundwater management strategies to maintain or improve water quality in contaminated or other aquifers. Surrogate models based on neural networks, regression models, support vector machies etc., are used as substitutes for the numerical simulation model in order to reduce the computational burden on the simulation-optimization approach. However, the groundwater flow and transport system itself being characterized by uncertain parameters, using a deterministic surrogate model to substitute it is a gross and unrealistic approximation of the system. Till date, few studies have considered stochastic surrogate modeling to develop groundwater management methodologies. In this study, we utilize genetic programming (GP) based ensemble surrogate models to characterize coastal aquifer water quality responses to pumping, under parameter uncertainty. These surrogates are then coupled with multiple realization optimization for the stochastic and robust optimization of groundwater management in coastal aquifers. The key novelty in the proposed approach is the capability to capture the uncertainty in the physical system, to a certain extent, in the ensemble of surrogate models and using it to constrain the optimization search to derive robust optimal solutions. Uncertainties in hydraulic conductivity and the annual aquifer recharge are incorporated in this study. The results obtained indicate that the methodology is capable of developing reliable and robust strategies for groundwater management.