Percussion hole drilling of metals with a fourth-harmonic Nd:YAG laser studied by defocused laser speckle correlation

Defocused speckle correlation is introduced as a tool for measuring the response in metal sheets during percussion laser drilling. For this procedure the fourth-harmonic Nd:YAG wavelength (266 nm) was used in pulsed mode. The method provides a cost-efficient and robust alternative to speckle interferometry for the study of the small deformations that appear during laser processing. The accuracy was shown to be of the order of a few tens of microradians for the tilt component that is measured, which translates to a few nanometers in deflection when the component is spatially integrated. In the measurements, deflections in the form of craters as large as 50 nm were detected on the back sides of silver and copper sheets. The diameters of the craters were 300 microm in the silver and 150 microm in the copper sheet; the output diameter of the hole was -5 microm.     

Modelling and simulation results for a domestic exhaust-air heat pump heating system

Energy consumption in residential buildings has gained an increasing interest the latest years due to the rising demand for efficient energy use and higher comfort standards. In tight building constructions with controlled ventilation, heat recovery with exhaust-air heat pump connected to floor heating is regarded as energy efficient heating system that optimises the energy use in buildings while maintaining an acceptable level of thermal comfort. In this study, we use the computational tools TRNSYS and EES to model and analyse the performance of a residential house, its ventilation system and its floor heating system based on an exhaust air heat pump. The system analysis focuses particularly on the influence of internal and solar gains on the operation of the heating system and the thermal comfort of the house. Furthermore, the way that gains influences the performance of the floor heating system is examined. Overall, the results bring to light the impact of factors that are not easy to predict on the indoor climate and the thermal comfort.     

Time Compact High Order Difference Methods for Wave Propagation, 2D

In earlier papers we have constructed difference methods that are fourth-order accurate both in space and time for wave propagation problems. The analysis and numerical experiments have been limited to one-dimensional problems. In this paper we extend the construction and the analysis to two space dimensions, and present numerical experiments for acoustic problems in discontinuous media.     

Antifeedants against <Emphasis Type="Italic">Hylobius abietis</Emphasis> Pine Weevils: An Active Compound In Extract of Bark of <Emphasis Type="Italic">Tilia cordata</Emphasis> Linden

Linden (Tilia cordata) bark was shown to contain an antifeedant effective against the large pine weevil, Hylobius abietis. Soxhlet extraction of inner and outer bark resulted in an extract that showed antifeedant activity in a microfeeding assay. The extract was fractionated by chromatography on silica gel using gradient elution with solvents of increasing polarity. The content of the fractions obtained was monitored by thin layer- and gas chromatography. Fractions of similar chemical composition were merged. Two of the 17 fractions showed antifeedant activity in the microfeeding assay. Nonanoic acid was identified in both of these fractions. Subsequent testing in the microfeeding assay showed that nonanoic acid possessed strong antifeedant activity against H. abietis adults.     

Fractionation of surface sediment fines based on a coupled sieve-SPLITT (split flow thin cell) method

In traditional sediment grain-size separation using sieve technique, the bulk of the organic matter passes through the smallest mesh size (generally 38 microm) and is not further fractionated. In this study, a common sieve separation has therefore been coupled with an extra high capacity split flow thin cell fractionation (EHC-SPLITT) instrument to separate the bulk surface sediment not only into size-based sieve fractions (> 100, 63-100, 38-63 and < 38 microm) but particularly to further fractionate hydrodynamically the fine fraction (< 38 microm) using the EHC-SPLITT. Compared to the few previous studies using a smaller high capacity (HC) SPLITT cell, the EHC-SPLITT evaluated in detail here has several advantages (e.g., 23 times higher throughput and allowance for large particle diameters). First, the EHC-SPLITT was calibrated with particle standards. Then, its ability to fractionate fine surface sediments hydrodynamically was demonstrated with material from biogeochemically distinct regimes using two cutoff velocities (1 and 6 m d(-1)). The results from particle standards indicated a good agreement between theory and experiment and a satisfactory mass recovery for the sieve-SPLITT method (80-97%) was observed for sediment samples. The mass distributions revealed that particles < 38 microm were predominant (70-90%), indicating the large need for a technique such as the EHC-SPLITT to further fractionate the fine particles. There were clearly different compositions in the EHC-SPLITT-mediated sub-fractions of the sediment fines as indicated by analyses of organic and inorganic parameters (POC, Si, Fe and Al). The EHC-SPLITT technique has the potential to provide information of great utility to studies of benthic boundary layer transport and off-shelf export and how such processes fractionate geochemical signals.     

Partially dehydrochlorinated PVC. II. Reactions with dienophiles and hydroxylating agents

Samples of poly(vinylchloride) containing polyene sequences were made by partial dehydrochlorination by alkali in tetrahydrofuran solution, by alkali in dioxane, and thermally in dimethyl-formamide. The reactions of polyene PVC were followed by UV spectrophotometry. Dienophiles were found to have relative reactivities similar to those found in reactions with low molecular-weight dienes. The reaction with maleic anhydride yielded polymers which after hydrolysis contained carboxyl groups. Hydroxylation was made with osmium tetraoxide and performic acid. With the latter reagent the reaction proceeded to complete disappearance of the UV-absorption peaks from trienes and higher polyenes: Gel permeation chromatography analysis showed that hydroxylation could be made with only minor changes in molecular-weight distribution. The formation of gel upon thermal dehydrochlorination in DMF was shown to be due to physical cross linking probably arising by crystallization of polyene segments. The adhesion of the hydroxylated and carboxylated polymers to glass and stainless-steel surfaces was investigated. Films adhered stronger as the degree of dehydrochlorination of the polyene PVC used to make the derivative increased. Samples with long sequences adhered much stronger than those containing short sequences of corresponding degrees of total substitution.     

Influence of early pH decline on calpain activity in porcine muscle

This study investigated the influence of post-mortem pH decline on calpain activity and myofibrillar degradation. From 80 pigs, 30 Longissimus dorsi (LD) muscles were selected on the basis of pH values at 3 h post-mortem and classified into groups of 10 as fast, intermediate and slow pH decline. The rate of pH decline early post-mortem differed between the three groups, but the ultimate pH values were similar at 24 h. Calpain activity and autolysis from 1 to 72 h post-mortem were determined using casein zymography and studied in relation to myofibrillar fragmentation.