Mechanical stability of trimethylolpropane trimethacrylate-based polymers

Trimethylolpropane trimethacrylate (TRIM) was homopolymerized and copolymerized with methyl methacrylate (MMA), glycidyl methacrylate (GMA), and acrylamide (AA), respectively, in various solvents and at various temperatures. For comparison, poly(styrene-co-divinyl benzene) [poly(S-co-DVB)] gels were selected. The mechanical stability was measured by compression of the swollen gels. The porogen served as swelling agent. The compression moduli increased with increasing TRIM concentration in the polymerization. The compression moduli of poly(TRIM) could be increased by copolymerization with low concentrations of comonomer. Low polymerization temperature decreased the mechanical strength of poly(TRIM). A good solvent increased the compression modulus. TRIM-based gels were at least as mechanically stable as were poly(S-co-DVB) gels.     

Surface Modification of Polycarbonate by Ultraviolet Radiation and Ozone

The effect of ultraviolet (UV) radiation in the presence of ozone as a surface treatment for polycarbonate is examined in regards to changes in the wettability, adhesion, and surface mechanical properties. Standalone, 175-µm-thick films of a commercially available polycarbonate were exposed to UV radiation from sources of different power with various treatment times in the presence of supplemental ozone. Significant decreases in the water contact angle were observed after exposure to UV radiation in the presence of ozone. After several variations in the experimental setup, it was determined that the change in water contact angle is a function of the UV irradiance and the work of adhesion follows a master curve versus UV irradiance. Nanoindentation experiments revealed that the modulus of the top 500 nm of the surface is increased following UV exposure, attributable to surface cross-linking. Adhesion tests to the surface (conducted by a pneumatic adhesion tensile test instrument) showed little change as a function of UV exposure. Analysis of adhesion test failure surfaces with X-ray Photoelectron Spectroscopy (XPS) showed the locus of bond failure lay within the bulk polycarbonate and the measured bond strength is limited by the bulk properties of the polycarbonate and/or the creation of a weak boundary layer within the polymer.     

Distribution of selected anthropogenic radionuclides (137Cs, 238Pu, (239,240)Pu and 241Am) in marine sediments with emphasis on the Spitsbergen-Bear Island area

Measurements of anthropogenic radionuclides in marine sediments can provide good estimates of past and present radioactive contamination of the marine environment. The Barents Sea is one of the world's richest ocean areas, and it is therefore of major interest for Norwegian fisheries to document the levels of radioactive contamination of this and adjacent ocean areas. In this study, concentrations of 137Cs, 238Pu, (239,240)Pu and 241Am were measured in marine sediments collected mainly in the Spitsbergen-Bear Island region. Additional samples collected in the deep Norwegian Sea and near the Greenland ice-edge have been included for comparison. The highest radionuclide levels were found near Spitsbergen, reaching over 50% higher than in adjacent areas. Determinations of the mineral content and particle size distribution indicate a relation between the content of clay minerals and radionuclide levels. The present study confirms earlier observations of elevated levels of 137Cs in sediments in the Spitsbergen-Bear Island area and documents elevated levels of 238Pu, (239,240)Pu and 241Am in these sediments. Using an exponential curve fit based on determinations of unsupported 210Pb in sediment cores, sedimentation rates of 0.28, 0.05 and 0.26 cm year(-1) were calculated at locations south of Spitsbergen, near the Greenland ice-edge and in the deep Norwegian Sea, respectively.     

建筑教育2007

在博洛尼亚宣言的背景下,为了在各学校之间建立一个积极的和共同的联系,欧洲建筑教育联合会将继续发挥重要作用。提出欧洲建筑教育主要的教学挑战和希望是:新的开放局面,新的见识以及所有通过机械发明的物质潜力将具有一个清晰的基础,而且从人文环境中汲取灵感。     

Gas temperature measurements using fibre Bragg grating during fire experiments in a tunnel

Gas temperature measurements with thermocouples are affected by radiation. This effect means that the temperature measured by a thermocouple can be far from the actual gas temperature. To study this effect and to compare the thermocouple readings with the readings of a fibre Bragg grating (FBG) sensor, fire experiments were performed in a model-scale tunnel. In this paper the results from two such fire experiments are presented. The temperatures measured using thermocouples with different diameters and the FBG sensor are compared and discussed. The “true” gas temperature, corrected for radiation effects from the thermocouples, was calculated from the results from the thermocouples with different diameters. The results show that the temperature measured by the FBG sensor is closer to the “true” gas temperature than is the case for any of the thermocouples used in these tests.     

Fire Emissions of Organics into the Atmosphere

The mass of dioxins, PAH (polycyclic aromatic hydrocarbons) and VOC (volatile organic compounds) emitted from fires to the atmosphere in Sweden per year has been estimated. The estimate is based on the number of fires in buildings, vehicles, waste and forest fires in Sweden in 1999. It is estimated that the total emission of dioxins from fires is in the range 0.5–1.4 g TEQ. The total emissions of PAH and VOC are in the ranges 2–12 ton and 13–200 ton, respectively. The estimated emission of dioxins from fires approximately corresponds to the total emission from traffic or half the emissions from municipal waste combustion (Swedish data from 1993). The fire statistics show that the mass of material combusted in building fires during a year is approximately 7500 ton, while that from forest fires is 2600 ton. Additionally, 2000–3000 tons are combusted in vehicle fires, fires in containers, etc. In addition to the more common types of fires during a year, individual large incidents may contribute significantly to the total emission. Such incidents include fires in municipal landfills or specific waste storage facilities (such as those for used tyres). An assessment of the consequences of such incidents has been made. This assessment implies that a large contribution to the emission of dioxins could be expected from fires in landfills and from fires in waste plastics (PVC) and tyres. Fires in deposits of wood chips and tyres are also significant potential sources of PAH and VOC.     

Hydrodynamic control of nitrogen and phosphorus turnover in an eutrophicated estuary in the Baltic

The turnover of phosphorus and nitrogen have been studied in a low salinity estuary in the Bothnian Sea. The estuary, G?rdsfj?rden, has a high loading of nutrients from a pulp and paper mill which supplies the estuary with three times the annual natural input of phosphorus and nitrogen, respectively. The turnover of nutrients was to a great extent determined by hydrodynamic variations. During periods of intense resuspension there was a net export of particulate bound nutrients from the estuary to the sea but since these periods were short there was an overall net retention of particulate nutrients. The estuary was a source for dissolved phosphorus to the sea. The major source of phosphorus export was release of dissolved P from anoxic sediments. G?rdsfj?rden was a sink for dissolved nitrogen which most likely escaped the estuary by denitrification. Nitrate was supplied by degradation of particulate organic nitroge'n but the main source was import from the sea.     

Flocculation of activated sludge flocs by stimulation of the aerobic biological activity

Activated sludge flocs are known to deflocculate under short-term anaerobic conditions, but little is known about possible reflocculation under subsequent aerobic conditions. When activated sludge flocs from two wastewater treatment plants deflocculated under anaerobic conditions with well-defined shear conditions, they could be almost, but not completely, reflocculated by aeration for 1-2 h under the same shear conditions. If the biological activity was reduced by adding azide, chloramphenicol or by decreasing the temperature, no or only very little reflocculation took place. This indicated that the reflocculation was under direct or indirect microbial control. Only a small part of the reflocculation was due to improved flocculation properties obtained by oxidation of Fe(II) to Fe(III), which is a better flocculant. Fe(II) was produced under the anaerobic conditions by microbial iron reduction, and it was oxidized to Fe(III) within less than one hour after the aeration was started. However, by comparing two different sludges with different capabilities for iron reduction, iron oxidation and responses to substrate addition, it was found that the aerobic biological activity most likely was of greatest significance for the observed reflocculation and floc formation under aerobic conditions. This was further supported by adding organic substrates (glucose or ethanol) during the aerobic reflocculation phase, which promoted reflocculation. However, some substrates had the opposite effect (acetate and lactate), where a deterioration of the reflocculation was observed, probably due to different responses from different groups of microorganisms in the sludges.