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51.
N. M. Agh-Atabay W. Edward Lindsell Peter N. Preston Peter J. Tomb 《Polymer International》1993,31(4):367-374
Symmetrically substituted 1,3-diynes containing hydroxyalkyl ( 1a-d ), bromoalkyl ( 1e-h ) (diphenylphosphinyl) ( 1i-k ) and carboxyalkyl ( 2a-d ) substituents have been prepared and characterised; the phosphine derivative ( 1k ) has been converted with alkyl iodides ( RI ; R = Me, Et) into bis(phosphonium) salts ( 1l and m ). During preparation of the diynedioic acid. ( 2a ), the non-centrosymmetrical diyne, HO2CCH2C?C—C?C(CH2)2OH ( 3 ), was also isolated. 60Co γ-Irradiation of diacetylene monomers ( 2a – d ) and 10,12-tricosadiyn-1-oic acid gave the corresponding polydiacetylene derivatives ( 4a – d and 5 ), respectively. Rubidium salts of ( 4c ) and ( 4d ), a barium salt of ( 4c ), and a potassium salt of ( 5 ) were prepared and isolated; soluble potassium salts of the carboxylic acid polymers ( 4 ) were generated in aqueous solution. The effects of changes in pH on the UV/visible absorption spectra of aqueous solutions of selected carboxylic acid polydiacetylenes have been recorded, and are discussed. 相似文献
52.
Peter Hall 《International Planning Studies》1996,1(1):7-15
Melvin Webber's seminal papers of 1963/64, which posited the arrival of a Nonplace Urban Realm and called upon planners to abandon their obsession with space, have proved highly prescient: metropolitan areas have deconcentrated and spread as he suggested, and the arrival of the informational age further reinforces these trends by creating a spaceless economy. But urban agglomeration economies do continue to operate, and traditional urban nodes will remain important in the new space‐economy. 相似文献
53.
The general mixed μ problem has been shown to be NP hard, so that the exact solution of the general problem is computationally intractable, except for small problems. In this paper we consider not the general problem, but a particular special case of this problem, the rank one mixed μ problem. We show that for this case the mixed μ problem is equivalent to its upper bound (which is convex), and it can in fact be computed easily (and exactly). This special case is shown to be equivalent to the so-called ‘affine parameter variation’ problem (for a polynomial with perturbed coefficients) which has been examined in detail in the literature, and for which several celebrated ‘Kharitonov-type’ results have been proven. 相似文献
54.
Remote sensing of species mixtures in conifer plantations using LiDAR height and intensity data 总被引:2,自引:0,他引:2
Daniel N.M. Donoghue Peter J. Watt Nicholas J. Cox Jimmy Wilson 《Remote sensing of environment》2007,110(4):509-522
In even-aged, single species conifer plantations LiDAR height data can be modelled to provide accurate estimates of tree height and volume. However, it is apparent that growth models developed for single species stands are not directly transferable to a more general situation of mixed species plantations. This paper evaluates the ability of small footprint, dual-return, pulsed airborne LiDAR data to estimate the proportion of the productive species when mixed with a nurse crop in closed canopy plantations. A study area located in Galloway Forest District in Scotland is used as an example of Lodgepole pine and Sitka spruce mixed plantation; this area contains good examples of a wide range of pure and mixed species plantation types. Three species groups are studied: areas of pure Sitka spruce, areas of pure Lodgepole pine and areas where the two species have been planted together. Two approaches are assessed for detection of plantation mixtures: the first uses LiDAR intensity data to separate spruce and pine species and the second uses LiDAR-derived canopy density measures, coefficient of variation, skewness, percent of ground returns (which provides a measure of canopy openness) and the mean canopy height, which enables areas with height variations to be identified. From analysis of LiDAR data extracted from 54 study plots using logistic regression, the coefficient of variation and LiDAR intensity data provide the most useful predictors of the proportion of spruce in a pine/spruce mixture with coefficients of determination (R2) of 0.914 and 0.930 respectively. The method could be developed as a mapping tool, which in combination with existing inventory data should help to improve timber volume forecasting for mixed species even-aged plantations. 相似文献
55.
Interest in advanced modulation formats for optical communication systems has so far experienced two major waves. The first one was motivated by the potential to enhance receiver sensitivity of thermal noise-limited systems using coherent detection in combination with phase shift keying. It ended with the advent of optical amplification, enabling high sensitivities together with polarization insensitive, simple and stable direct detection. The second wave is still rolling, fueled by the potential of advanced modulation formats to increase robustness of optical transmission systems against signal distortions. Due to performance limitations given by direct detection and nonlinear effects in the transmission fiber, it is not decided yet, whether there will be widespread application in carrier networks. 相似文献
56.
This paper deals with the problem of finding graph layerings restricted to a given maximal width. However, other than previous approaches for width-restricted layering, we take into account the space for dummy nodes, which are introduced by edges crossing a layer. The main result is that the problem of finding a width-restricted layering under consideration of dummy nodes is NP-complete even when all regular nodes have the same constant width and all dummy nodes have the same constant width. 相似文献
57.
Jennifer G. Winter M. Catherine Eimers Peter J. Dillon Lem D. Scott Wolfgang A. Scheider Campbell C. Willox 《Journal of Great Lakes research》2007,33(2):381-396
Total phosphorus (TP) inputs to Lake Simcoe have led to hypolimnetic dissolved oxygen (DO) depletion and loss of cold water fish habitat. Since 1990, efforts have been made to reduce the total TP input to the lake below a defined target of 75 t/year, which was predicted to lead to reductions in spring TP concentration and improvements in end-of-summer hypolimnetic DO concentrations. The total TP load to the lake during the most recent period of record (1998/99-2003/04) ranged from 53 to 76 t/yr and averaged 67 t/yr, compared to an average of 114 t/yr estimated between 1990/91 and 1997/98 (range 85-157 t/yr). Reductions in TP loads from the catchment via tributary discharge (∼26 t) accounted for the majority of the decrease in total load between the two time periods. Total P concentrations decreased significantly in four out of six long-term monitored tributaries; however, concentrations in all six tributaries remain above the level recommended to avoid nuisance plant growth (30 μg/L). Although TP loads to the lake are currently below the target 75 t/yr, excessive growths of filamentous algae and macrophytes continue to be a problem in the nearshore zone. End-of-summer minimum hypolimnetic DO concentrations (average 4.3 mg/L, 1998/99-2003/04) remain substantially below the level (7 mg/L) that is considered protective of lake trout. Efforts to reduce TP loads to the lake therefore need to continue. 相似文献
58.
Aus Betriebsergebnissen bei der Pfannenentschwefelung ist ein negativer Einfluß oxidierender Gasphasen bekannt. Daher war es das Ziel der eigenen Untersuchungen in einer geeigneten Apparatur die Wirkung oxidierender Bedingungen in der Gasphase sowohl auf den Verlauf des Schwefelabbaues in der Schlacke als auch des Schwefeltransportes aus dem Roheisen in die Schlacke zu untersuchen. Oxidierende Gasphasen erwirken bei der Pfannenentschwefelung an der Phasengrenze Schlacke/Gas eine Oxidation des Schwefels aus der Schlacke, ohne jedoch bei ruhender Schlackenschicht ein Oxidationspotential in der Schlacke aufzubauen, das bis zur Phasengrenze Roheisen/Schlacke durchgreift und dort die Entschwefelung des Roheisens durch die Siliciumgehalte stört. Sowohl die Entschwefelung des Roheisens als auch die Oxidation des Schwefels aus der Schlacke werden durch höhere Temperaturen und durch eine Rührwirkung gefördert. Der Schwefeltransport wird bei den ungerührten wie bei den gerührten Schmelzen durch Diffusionsvorgänge gesteuert und auch hier durch steigende Temperaturen und rührende Kräfte begünstigt. 相似文献
59.
Peter Su Adrian Gerlich Motomichi Yamamoto Thomas H. North 《Journal of Materials Science》2007,42(24):9954-9965
The formation of local melted films during friction stir spot welding of as-cast AZ91D and thixomolded AZ91 material is investigated.
The average temperatures close to the tip of the rotating pin vary from 438 to 454 °C during the dwell period in friction
stir spot welding. These measured temperature values are higher than the melting temperature of α-Mg + Mg17Al12 eutectic (437 °C). It is suggested that the temperature in the stir zone during the dwell period is determined by the relative
proportions of α-Mg and (α-Mg + Mg17Al12) eutectic material, which are incorporated during friction stir spot welding. Based on the stir zone temperature measurements
and a detailed examination of material located at the root of the pin thread it is suggested that material is moved downwards
via the pin thread and into the stir zone during the dwell period in friction stir spot welding. Evidence of local melted
film formation is observed in the stir zone of AZ91 spot welds. It is suggested that melted films are retained since their
dissolution rate is much slower in the high temperature stir zone than it is when melted films is formed in the stir zone
during Al 7075-T6 friction stir spot welding. The spontaneous melting temperature, solute diffusion rate and the thermodynamic
driving force for droplet dissolution are much higher during Al 7075-T6 friction stir spot welding. 相似文献
60.
Peter Eaton Andrea Ragusa Caroline Clavel Cristina T Rojas Paul Graham Raúl V Durán Soledad Penadés 《IEEE transactions on nanobioscience》2007,6(4):309-318
Glyconanoparticles which present carbohydrate and amino groups motifs at their surface were produced. These particles were highly stable and soluble in aqueous solutions. The presence of the carbohydrate groups also allowed the inclusion of more strongly binding groups, without affecting solubility. The binding of a model DNA, plasmid by these nanoparticles was studied by atomic force microscopy, transmission electron microscopy, and gel electrophoresis. Significant differences between the nanoparticles based on their affinities for the DNA were found, with implications for their potential use as nonviral gene delivery agents. 相似文献