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101.
Lei Zhao Tien Duy Vo Marcel Kaiser Prof. Dr. Helge B. Bode 《Chembiochem : a European journal of chemical biology》2020,21(9):1288-1292
A new cyclic lipopeptide, phototemtide A ( 1 ), was isolated from Escherichia coli expressing the biosynthetic gene cluster pttABC from Photorhabdus temperata Meg1. The structure of 1 was elucidated by HR-ESI-MS and NMR experiments. The absolute configurations of amino acids and 3-hydroxyoctanoic acid in 1 were determined by using the advanced Marfey's method and comparison after total synthesis of 1 , respectively. Additionally, three new minor derivatives, phototemtides B–D ( 2 – 4 ), were identified by detailed HPLC–MS analysis. Phototemtide A ( 1 ) showed weak antiprotozoal activity against Plasmodium falciparum, with an IC50 value of 9.8 μm . The biosynthesis of phototemtides A–D ( 1 – 4 ) was also proposed. 相似文献
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Software and Systems Modeling - Automotive software architectures describe distributed functionality by an interaction of software components. One drawback of today’s architectures is their... 相似文献
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Catalytic performance of methacrylate‐based poly‐4‐(dialkylamino)‐pyridines: activity prediction via NMR shifts 下载免费PDF全文
The synthesis of the 4‐(dialkylamino)pyridine derivative 3‐(4‐(pyridin‐4‐yl)piperazin‐1‐yl)propyl methacrylate and its copolymerization with n‐butyl methacrylate are presented. The catalytic activity was evaluated in the acylation of tert‐butanol with acetic anhydride yielding tert‐butyl acetate. It is observed that the activity of polymer‐attached 4‐(dimethylamino)pyridine analogues correlates remarkably well with the chemical shift of the β‐pyridyl protons. Differences in catalytic efficiency result from distinct electronic densities of the pyridine ring, while embedding the catalytically active moiety into a polymeric structure has nearly no deleterious effect on the performance. © 2015 Society of Chemical Industry 相似文献
106.
Quan-Bao Ma Jürgen Ziegler Bernhard Kaiser Dominic Fertig Wolfram Calvet Eswaran Murugasen Wolfram Jaegermann 《International Journal of Hydrogen Energy》2014
The electrochemical properties of single-crystalline p-type 3C-SiC films on p-Si substrate were investigated as an electrode in H2SO4 aqueous solutions in dark and under white light illumination. The photoelectrochemical (PEC) measurements indicates the p-type 3C-SiC film on p-Si substrate can generate a cathodic photocurrent as a photocathode, which corresponds to hydrogen production, and generate an anodic photocurrent as a photoanode, which corresponds to oxygen evolution. The surface chemical states of the films were investigated by XPS. In order to observe the surface chemical state changes after PEC test, the range of applied potential to the electrode was divided into three zones: −3.6 to 0 V, 0–1.5 V and 1.5–4 V vs. Ag/AgCl. After separated PEC tests in these three areas, XPS shows the surface of the SiC film in the range of −3.6 to 0 V and 0–1.5 V was stable without oxidation except the band bending occurred. But in the range of 1.5–4 V the film surface was oxidized due to anodic oxidation. 相似文献
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Rotor‐stator‐machinery is characterized in continuous operation by a homogeneous power input and a defined residence time. The influence of the equipment configuration and process design in the laminar flow regime was considered little till now. In order to fill this knowledge gap, the process behavior of this type of device was systematically investigated experimentally under axial flow conditions, as well as an energetic optimization of the machine configuration was performed. 相似文献