Biobased thermosets from the free‐radical copolymerization of conjugated linseed oil

New polymeric thermosets were prepared through the bulk free‐radical copolymerization of 100% conjugated linseed oil, acrylonitrile, and divinylbenzene. Under the appropriate reaction conditions and with the appropriate curing sequence, 61–96 wt % of the oil was incorporated into the crosslinked thermosets. The resulting yellow, transparent thermosets varied from being soft and flexible to being hard and brittle. Dynamic mechanical analysis and thermogravimetric analysis showed that these thermosets had good mechanical properties and thermal stability. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 979–985, 2007     

Charakterisierung und Störstoffanalyse von rückgewonnenen Stoffströmen aus Wärmedämmverbundsystemen

Due to the growing energy requirements, the proportion of external thermal insulation composite systems (ETICS) installed has increased significantly during the past 50 years. Due to the longevity of these systems, ETICS waste is currently accumulating. Owing to the complex construction as well as a multitude of differently installed materials and substances of the past generations, there are many uncertainties and problems with the clean and low-pollutant processing of such systems. In the frame of this work, the ETICS were processed and sorted before being screened for ingredients or pollutants as well as for the purity of the recovered material fractions.     

Effects of human activities on benthic macroinvertebrate community composition and water quality in the upper catchment of the Mara River Basin,Kenya

Land‐use changes in the upper reaches of the Mara River Basin have modified their biophysical and hydrological processes, resulting in water quality degradation in streams. This study was conducted to investigate the effects of human activities on water quality and macroinvertebrates along the Nyangores River, one of the main tributaries of the Mara River, Kenya. Seven sampling sites were chosen to correspond to the loss of riparian cover, livestock watering and human activities (e.g. laundry washing, bathing, cultivation, wastewater inputs, dumping of solid wastes from urban areas and settlements along the river). Physical–chemical variables and water samples for nutrient analyses were collected monthly from February to July 2012. Benthic macroinvertebrates also were collected at the same sites as for the water quality samples. Two‐way analysis of variance tested the significant differences for each variable among the sites. Similarity percentages (SIMPER) analysis was used to identify the key taxa contributing to differences between minimally disturbed and most disturbed conditions in the study area. The results indicated increased nutrient concentrations in agricultural and settlement areas. Significant (P < 0.05) spatial–temporal variations in water quality variables were observed. A total of 42 macroinvertebrate genera were encountered, with Ephemeroptera, Plecoptera and Trichoptera orders dominating the minimally disturbed areas, and Diptera dominating the disturbed areas receiving point and no‐point solid and liquid wastes, including nutrients, from urban areas and settlements. Canonical correspondence analysis (CCA) revealed significant relationships between macroinvertebrate communities and measured physicochemical variables. The results of this study indicate the need for protection of riparian zones and treatment of sewerage wastes before their release into waterways. The dumping of solid wastes near streams and rivers also is discouraged, to maintain the quality of surface waters and aquatic organisms.     

E-recruitment and the benefits of organizational web appeal

This study examined the influences of website design on prospective job seekers. A total of 182 participants accessed and reviewed an online job ad. Afterwards, they rated: (a) the attractiveness of the ad’s formatting, (b) the usability of the website, (c) overall evaluations of the organization’s web appeal, (d) impressions of the organization, and (e) willingness to pursue employment with the hiring organization. Although both the formatting attractiveness and usability of online recruitment materials influenced participants’ inclinations to pursue jobs, formatting was more important than usability. Moreover, impressions of the employer mediated the relationship between satisfaction with the website and willingness to pursue employment with the organization. Overall, this research advances knowledge by applying signaling theory to the web-based recruitment domain and by testing a mediated relationship implied therein. In addition, this is the first study to introduce relative weights analysis to the recruitment literature.     

一种新的语义对象行为语言

针对人类用自然语言与机器交互所面临的巨大鸿沟,提出了一种基于类自然语言的语义对象行为语言。SOBL是一种宣称式的陈述语言,用于开发数据库驱动的应用,支持复杂的用户交互,主要由一个Semantic Objects^TM的对象关系开发框架所支持。该语言扩展结构化自然语言,携带语义信息,能够面向非程序员使用,降低了软件的开发难度。最后通过一个具体的实例验证了该语言的有效性。     

3D Printable One-Part Carbon Nanotube-Elastomer Ink for Health Monitoring Applications

3D printing of conductive elastomers is a promising route to personalized health monitoring applications due to its flexibility and biocompatibility. Here, a one-part, highly conductive, flexible, stretchable, 3D printable carbon nanotube (CNT)-silicone composite is developed and thoroughly characterized. The one-part nature of the inks: i) enables printing without prior mixing and cures under ambient conditions; ii) allows direct dispensing at ≈100 µm resolution printability on nonpolar and polar substrates; iii) forms both self-supporting and high-aspect-ratio structures, key aspects in additive biomanufacturing that eliminate the need for sacrificial layers; and iv) lends efficient, reproducible, and highly sensitive responses to various tensile and compressive stimuli. The high electrical and thermal conductivity of the CNT-silicone composite is further extended to facilitate use as a flexible and stretchable heating element, with applications in body temperature regulation, water distillation, and dual temperature sensing and Joule heating. Overall, the facile fabrication of this composite points to excellent synergy with direct ink writing and can be used to prepare patient-specific wearable electronics for motion detection and cardiac and respiratory monitoring devices and toward advanced personal health tracking and bionic skin applications.     

Document‐centric XML workflows with fragment digital signatures

The use of digital document management and processing is increasing. Traditional workflows of paper forms are being replaced by electronic workflows of digital documents. These workflows often require multiple signatures to be added to the documents for authorization and/or integrity. We describe examples of digital workflows that illustrate problems with digital signatures: i.e. the use of digital signatures across entire documents results in signatures that can be unnecessarily invalidated by subsequent modification of the document. We propose the use of fragment signatures, which reduce unnecessary invalidation of signatures and enable greater concurrency in workflows. Our approach is document‐centric and does not use a centralized database. We report on an implementation that allows fragment signatures over document fragments as well as the attachment (or embedding) of other documents. This allows collaborative or cooperative editing to occur on parts of a document without disturbing unrelated signatures. We describe the lessons learned from our deployments and offer further ways to embed such signatures into other document types. Copyright © 2010 John Wiley & Sons, Ltd.     

Cameo: an alternative model of concurrency for Eiffel

We present a new concurrency model for the Eiffel programming language. The model is motivated by describing a number of semantic problems with the leading concurrency model for Eiffel, namely SCOOP. Our alternative model aims to preserve the existing behaviour of sequential programs and libraries wherever possible. Comparison with the SCOOP model is made. The concurrency aspects of the alternative model are presented in CSP along with a model of exceptions. The results show that while the new model provides increased parallelism, this comes with the price of increased overhead due to lock management.