Light Controlled Biohybrid Microbots

Biohybrid microbots integrate biological actuators and sensors into synthetic chassis with the aim of providing the building blocks of next-generation micro-robotics. One of the main challenges is the development of self-assembled systems with consistent behavior and such that they can be controlled independently to perform complex tasks. Herein, it is shown that, using light-driven bacteria as propellers, 3D printed microbots can be steered by unbalancing light intensity over different microbot parts. An optimal feedback loop is designed in which a central computer projects onto each microbot a tailor-made light pattern, calculated from its position and orientation. In this way, multiple microbots can be independently guided through a series of spatially distributed checkpoints. By exploiting a natural light-driven proton pump, these bio-hybrid microbots are able to extract mechanical energy from light with such high efficiency that, in principle, hundreds of these systems can be controlled simultaneously with a total optical power of just a few milliwatts.     

Photocatalytic activity of a new composite material of Fe (III) oxide nanoparticles wrapped by a matrix of polymeric carbon nitride and amorphous carbon

Polymeric carbon nitride was synthesized from urea and doped with Cu and Fe to act as co-catalysts. The material doped with Fe was a new composite material composed of Fe(III) oxides (acting as a co-catalyst) wrapped by the polymer layers and amorphous carbon. Furthermore, the copper doped material was described in a previous report. The photocatalytic degradation of the azo dye direct blue 1 (DB) was studied using as photocatalysts: pure carbon nitride (CN), carbon nitride doped with Cu (CN-Cu) and carbon nitride doped with Fe (CN-Fe). The catalysts were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), by X-ray photoelectron spectroscopy (XPS) and Brunauer–Emmett–Teller method (BET), etc. The adsorption phenomenon was studied using the Langmuir and Freundlich models. For the kinetic study, a solution of 500 mg L^?1 of DB1 was treated with each catalyst, visible light and H₂O₂. The dye concentration was measured by spectrophotometry at the wavelength of 565 nm, and the removal of the total organic content (TOC) was quantified. BET analysis yielded surface areas of 60.029, 20.116 and 70.662 m²g^?1 for CN, CN-Cu and CN-Fe, respectively. The kinetics of degradation were pseudo-first order, whose constants were 0.093, 0.039 and 0.110 min^?1 for CN, CN-Cu and CN-Fe, respectively. The total organic carbon (TOC) removal reached the highest value of 14.46% with CN-Fe.     

How can Cleaner Production practices contribute to meet ISO 14001 requirements? Critical analysis from a survey with industrial companies

The companies’ needs to adopt changes in their way of production to maximize the environmental performance required by their stakeholders, and at the same time, to maximize their economic and market performance, have made them seek for environmental strategies and certifications. In this sense, the Cleaner Production and the Environmental Management System based on ISO 14001 have been, respectively, presented, since the main objective of this research is to identify and analyze Cleaner Production contributions to comply with ISO 14001 requirements. For such, a survey research has been carried out in Brazilian industrial companies certified by ISO 14001. We have identified the main performance factors by leading practices and variables of Cleaner Production that contribute to the compliance with the standard requirements by companies. Thus, it has been noted that Cleaner Production is an important strategy for the preparation of companies for certification as well as for improving their environmental performance.     

Engineered Multifunctional Albumin‐Decorated Porous Silicon Nanoparticles for FcRn Translocation of Insulin

The last decade has seen remarkable advances in the development of drug delivery systems as alternative to parenteral injection‐based delivery of insulin. Neonatal Fc receptor (FcRn)‐mediated transcytosis has been recently proposed as a strategy to increase the transport of drugs across the intestinal epithelium. FcRn‐targeted nanoparticles (NPs) could hijack the FcRn transcytotic pathway and cross the epithelial cell layer. In this study, a novel nanoparticulate system for insulin delivery based on porous silicon NPs is proposed. After surface conjugation with albumin and loading with insulin, the NPs are encapsulated into a pH‐responsive polymeric particle by nanoprecipitation. The developed NP formulation shows controlled size and homogeneous size distribution. Transmission electron microscopy (TEM) images show successful encapsulation of the NPs into pH‐sensitive polymeric particles. No insulin release is detected at acidic conditions, but a controlled release profile is observed at intestinal pH. Toxicity studies show high compatibility of the NPs with intestinal cells. In vitro insulin permeation across the intestinal epithelium shows approximately fivefold increase when insulin is loaded into FcRn‐targeted NPs. Overall, these FcRn‐targeted NPs offer a toolbox in the development of targeted therapies for oral delivery of insulin.     

Chemiotropic behavior of female olive fly (Bactrocera oleae GMEL.) onOlea europaea L

An interpretation is given of a number of observations on the chemiotropic behavior ofBactrocera oleae in connection with olive maceration water and the fly's return to the olive groves after the first summer rains. To this end, the headspace of both maceration water and leaf leaching water, simulating rainfall, were examined. In both cases, the presence of ammonia, which is generally known to attract fruit flies (Diptera, Tephritidae), was detected and, for the first time, in addition to other compounds that are inert for the fly, the presence of styrene was also detected. This aromatic hydrocarbon was found to be a strong attractant. It is shown that both ammonia and styrene are products of the metabolism of microbial flora present on the olive and leaf surface.     

On the Construction of Classes of Suffix Trees for Square Matrices: Algorithms and Applications

We provide a uniform framework for the study of index data structures for a two-dimensional matrixTEXT[1:n, 1:n] whose entries are drawn from an ordered alphabetΣ. An index forTEXTcan be informally seen as the two-dimensional analog of the suffix tree for a string. It allows on-line searches and statistics to be performed onTEXTby representing compactly theΘ(n³) square submatrices ofTEXTin optimalO(n²) space. We identify 4ⁿ⁻¹families of indices forTEXT, each containing ∏ⁿ_i=1 (2i−1)! isomorphic data structures. We also develop techniques leading to a single algorithm that efficiently builds any index in any family inO(n² log n) time andO(n²) space. Such an algorithm improves in various respects the algorithms for the construction of the PAT tree and the Lsuffix tree. The framework and the algorithm easily generalize tod>2 dimensions. Moreover, as part of our algorithm, we provide new algorithmic tools that yield a space-efficient implementation of the “naming scheme” of R. Karpet al.(in“Proceedings, Fourth Symposium on Theory of Computing,” pp. 125–136) for strings and matrices.     

Comparing Syntactic and Semantic Action Refinement

The semantic definition of action refinement on labelled configuration structures is compared with the notion ofsyntactic substitution, which can be used as another notion of action refinement in a process algebraic setting. The comparison is done by studying a process algebra equipped with sequential composition, parallel composition with an explicit synchronisation set, and an operator for action refinement. On the one hand, the language (including the refinement operator) is given a configuration structure semantics. On the other hand, a reduction procedure transforms a process termPinto aflatterm (i.e., with the refinement operator not occurring in it)red(P) by means of syntactic substitution, defined in a structural inductive way. The main aim of the paper is to investigate general conditions under which the termsPandred(P) have the same semantics. The results we present are essentially dependent on the question whether the refined action can be synchronised or not. In the latter case,Pandred(P) give rise to isomorphic configuration structures under mild assumptions. The former case is considerably more difficult, since then refinement cannot be expected to distribute over parallel composition. We give necessary and sufficientsemanticconditions under which distribution still holds up to semantic equivalence. Subsequently, we also give sufficient (but not necessary)syntacticconditions for reducible terms. Finally, we generalise these results to a language with recursion.     

A non-intrusive estimation for high-quality Internet TV services

This paper presents a non-intrusive estimator for Internet TV services based on streaming technology. Analyzing the video packets received by the client application, the estimator is capable of selecting the most suitable encoding bitrate for the available bandwidth in the end-to-end path. The estimator has been integrated in a real client/server architecture and evaluated with different network traffic situations. The results of the performed evaluation have revealed the stability and adaptation speed as the best qualities of our proposal.     

An online tool to identify white-collar worker profiles in relation to their ICT skills and mental strain

The introduction of Internet and Information and communication Technologies (ICT) in offices is a global phenomenon that transformed white-collar worker job demands. Although there are several studies of e-skills and mental workload for central countries, there is a lack of similar studies for the Latin American context. An online snowball sampled (n = 352) survey was developed and validated by the authors (internal consistency = 0.7). We characterized ICT worker profiles from e-skills and these dimensions: attitudes toward, resources usage and technology dependency. Mental Strain was assessed with raw task load index (RTLX) and correlated with the proposed profiles by means of paired T-tests and Mann–Whitney Tests. The sample was characterized by 7.2% of non visual display terminal users and 92.8% of visual display terminal, ICT skilled users. Of the latter, 30.7% were ICT practitioners, 30.4% were ICT Users and 27.2% were E-Business Users. Non VDT users’ mental strain was statistically meaningful smaller than VDT–ICT skilled users’ mental workload. No statistical differences were found in RTLX results when comparing ICT skilled user profiles. Non VDT users can be identified from ICT skilled Users by their lower ITC Dependency and minor use of ICT resources. There were no differences in those dimensions among ICT skilled Profiles. Attitude toward these technologies was a distinct factor for ICT Users in relation to ICT Practitioners and ITC Business Users. The application of this tool in peripheral and central countries would allow a complete ergonomical characterization of white-collar workers within the Information Society.