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591.
592.
The ratio Cv/Tc for the specific heat jump (Cv) at the superconducting transition temperature (Tc) has been calculated for the correlated electron systems within the van Hove scenario for the normal state electronic density of states. The effect of electron correlations has been taken into account using Gutzwiller variational method. It is found that the interplay between electron–electron interaction and electron–phonon interaction plays an important role in enhancing the ratio Cv/Tc. Our findings should be relevant to a number of superconducting compounds of recent interest.  相似文献   
593.
The knowledge of biopolymer changes by extrusion is very important for a wide range of industrial applications that spreads from extruded food to biodegradable packaging. In this article, the formation of starch–lipid and lipid–protein complexes that occurred during the extrusion cooking of wheat flour with the addition of fatty acids was studied. Results showed that the highest barrel temperature (128.3 °C) promoted the formation of starch–lipid complexes in samples made up of wheat starch and wheat flour with the addition of fatty acids. The maximum formation of protein–lipid complexes (68% fatty acid bound to protein) was observed at the highest barrel temperature and water feed content (<22%). This study is a prerequisite for the optimisation of production of expanded extrudates made up of wheat flour and fatty ingredients and for the study of a biodegradable packaging based on by‐product of milling wheat (and fat).  相似文献   
594.
The cooking quality of pasta based on soft wheat flour and supplemented with three percentages of oat flour was studied. Results showed that oat flour modified deeply the cooking quality of spaghetti in comparison with samples based on only soft wheat flour. These effects were attributed to both starch‐lipid complex formation and presence of β‐glucans that weak gluten network. An increase in optimal cooking time with increase in oat percentages was observed (480 vs. 630 min). Samples enriched with oat flour showed a good‐quality cooking total organic matter (TOM values ranged from 1.4 to 2).  相似文献   
595.
Metal Science and Heat Treatment - The mechanical properties of a powder steel containing 0.06% C, 22% Cr, 13% Ni, 5% Mn and 2% Mo (UNS S20910) and manufactured by mechanical alloying with...  相似文献   
596.
Non-destructive evaluation of defects like voids in syntactic foam reinforced with epoxy compatible chopped strand glass fibres, employing ultrasonic C-scan immersion through transmission method, was under-taken. The results showed that in four of the five similarly processed foam samples, the voids were uniformly spread while in the fifth, which was processed by a different route, a large spread of low dense area was noticed emphasizing the influence that processing technique has on the amount of voids present in the composites.  相似文献   
597.
    
The work was aimed to optimize extraction and recovery of phenolics from turnip greens by-products using eco-sustainable techniques based on the use of microwaves, ultrasound, or enzymes and of water as solvent. The optimization of ultrasound- and microwave-assisted extractions was performed using a 4-factors/3-levels and a 3-factors/3-levels Box–Behnken Design (BBD), respectively and the results of the corresponding trials were fitted to a second order polynomial model. The enzymatic extractions were performed using three different commercial enzymatic preparations, optionally combined with an ultrasound treatment carried out according to the central values of the BBD design. The best results obtained from each green technique were compared with those of the conventional solid–liquid extraction performed with a 70% ethanol aqueous solution. Regarding ultrasounds, the conditions able to maximize the total phenolic concentrations of the extracts (solid–water ratio, 50 g/L; T, 45°C; t, 40 min; power, 24 W) increased the extraction efficiency by about 75% and reduced the extraction times from 2 h to 10 min with respect to the conventional extraction. Concerning microwaves, the optimized conditions (solid-water ratio, 75 g/L; t, 3 min; power, 160 W) allowed the increase of the extraction efficiency by about 48% and the decrease of the extraction times to just a few minutes. For both techniques, the factor that mainly affected extraction yield and antioxidant activity were “solids-to-solvent ratio” and “power,” respectively. According to the results of the enzymatic treatments, the best extraction was that performed with the commercial mix of pectinlyase, polygalacturonase, pectinesterase, and arabinase, which had the same extraction efficiency of microwaves but required longer times (90 min). Furthermore, the combination with ultrasounds did not improve its performances. Extraction technique also affected the phenolic profiles in terms of number and concentration of compounds identified. In conclusion, ultrasounds and microwaves are the best treatments to maximize extraction yield (the first) and minimize extraction time (the second).  相似文献   
598.
    
The present research focuses on examining the thermic response of living tissue in the form of a triple-layered cylindrical structure when subjected to laser light and the compatibility analysis of non-Fourier heat transfer with thermodynamics second law. The temperature field in the triple-layered cylindrical living tissue subjected to laser light is determined by numerically solving the transient radiative transfer equation in conjunction with the dual phase lag (DPL) based bioheat equation. Once the temperature field is known, the equilibrium and nonequilibrium entropy production rate (EPR) is calculated based on the hypothesis of classical irreversible thermodynamics and extended irreversible thermodynamics, respectively. The present results are verified against the data from the literature and found a good match between them. A comparative analysis of the Fourier and non-Fourier models is accomplished. The equilibrium and nonequilibrium EPR values for the Fourier model are found to be positive. While the equilibrium EPR is negative for non-Fourier heat conduction and does not satisfy the thermodynamics second law, nonequilibrium EPR is always a positive value for Fourier, DPL, and hyperbolic models and satisfies thermodynamics second law. It has been investigated how thermal relaxation times affect the temperature field and EPRs in tissue are subjected to laser light.  相似文献   
599.
    
Different variants of Paneer were prepared with cow milk (CM), buffalo milk (BM), skimmed milk powder (SMP) and blends (40:60, 50:50, 60:40) of SMP with CM/BM. The Paneer composition, texture, microstructure and spread of functional groups were correlated with the dielectric capacitance values. Results depicted a strong correlation (R2 > 0.95) between milk used for Paneer making and its proximate composition in terms of the capacitance value, and it was highest for CM followed by BM; 100% SMP Paneer recorded lowest values. Paneer made from blends of SMP and liquid milk had the lowest transmittance value, indicating higher total protein content.  相似文献   
600.
    
Amine-based carbon capture (ABCC) is an advanced and cost-effective technology used to reduce the effects of climate change by capturing CO 2 emitted from different sources. Although it has been demonstrated commercially, amine degradation poses a significant threat to humans and aquatic life. Amine degradation produces a wide variety of complex products such as nitrosamines and some organic acids. Some of these products are carcinogenic and mutagenic in nature and have demonstrated acute toxicity for laboratory animals. In order to mitigate the adverse impact of these compounds on human health and aquatic life, heterogeneous photocatalysis, an advanced oxidation process which can degrade a wide variety of chemical species with potent reactive hydroxyl radicals, was considered for the degradation of these compounds. The photocatalytic degradation of N-nitrosodiethylamine (NDEA), acetic acid, and formic acid were tested using TiO2 and metal-impregnated TiO2 catalysts such as Fe, Co, Ni, and Cu. Various techniques, such as thermogravimetric analysis (TGA), UV–Vis, X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), scanning electron microscopy (SEM), and X-ray fluorescence (XRF) were used to characterize these catalysts. The operational parameters for the photocatalytic degradation process were chosen as solution pH, catalyst dose, and metal impregnation percentage (imp%), and they were optimized using response surface methodology (RSM). pH was found as an important factor, and its impact on the photocatalytic degradation efficiency was more significant than the other operational parameters. The average degradation efficiency of the compounds reached 93.1% for Fe-TiO2, 92.08% for Co-TiO2, 89.09% for Ni-TiO2, 88.81% for Cu-TiO2, and 86.3% for TiO2 at the optimum conditions.  相似文献   
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