Molecular Dynamics Study of Gas–Surface Interactions in a Force-Driven Flow of Argon through a Rectangular Nanochannel

In recent times, flows through micro- and nanochannels have gained prominence due to their applicability to the fast growing fields of micro- and nanotechnology among others. Understanding gas–surface interactions in such flows is crucial, because the size of the micro/nanoscale devices is typically comparable to boundary layer thickness near a wall and the surface starts playing a significant role. An attempt is made to understand these interactions by modeling simple force-driven argon gas flow between two parallel platinum plates by the molecular dynamics method. One of the most important parameters that describes gas–surface interactions—that is, the tangential momentum accommodation coefficient, along with flow properties such as velocity and density—is calculated for a range of Knudsen numbers in the early transitional flow regime. A deeper insight into the flow physics is obtained by considering various case studies for the variation of aforesaid properties with respect to external driving forces and gas–wall interaction strengths.     

Rheological behavior of neat and carbon fiber-reinforced poly(ether ketone ketone) for extrusion deposition additive manufacturing

To develop new materials for extrusion additive manufacturing (AM) systems, a fundamental understanding of rheological properties is essential to correlate the effect of processing on material structure and its properties. In this work, the rheological properties of five different grades of neat and carbon fiber (CF)-reinforced poly(ether ketone ketone) are reported. Rheological properties are essential to understand the effect of reinforcing fibers and AM process parameters such as time, temperature, environment, and shear rate on flow behavior during processing. Small-amplitude oscillatory shear tests and steady shear tests indicated neat grades to exhibit less increase in viscosity over time when processed in air than the CF-filled grades. The filled grades showed greater shear thinning and lower sensitivity to temperature. Overall, this rheological analysis provides a broad framework for determining appropriate processing conditions for extrusion deposition AM of such high-temperature polymer systems.     

Exploring the Bioactive Potentials of C60-AgNPs Nano-Composites against Malignancies and Microbial Infections

At present, the potential role of the AgNPs/endo-fullerene molecule metal nano-composite has been evaluated over the biosystems in-vitro. The intra-atomic configuration of the fullerene molecule (C₆₀) has been studied in-vitro for the anti-proliferative activity of human breast adenocarcinoma (MDA-MB-231) cell lines and antimicrobial activity against a few human pathogens that have been augmented with the pristine surface plasmonic electrons and antibiotic activity of AgNPs. Furthermore, FTIR revealed the basic vibrational signatures at ~3300 cm⁻¹, 1023 cm⁻¹, 1400 cm⁻¹ for O-H, C-O, and C-H groups, respectively, for the carbon and oxygen atoms of the C₆₀ molecule. NMR studies exhibited the different footprints and magnetic moments at ~7.285 ppm, explaining the unique underlying electrochemical attributes of the fullerene molecule. Such unique electronic and physico-chemical properties of the caged carbon structure raise hope for applications into the drug delivery domain. The in-vitro dose-dependent application of C₆₀ elicits a toxic response against both the breast adenocarcinoma cell lines and pathogenic microbes. That enables the use of AgNPs decorated C₆₀ endo fullerene molecules to design an effective anti-cancerous drug delivery and antimicrobial agent in the future, bringing a revolutionary change in the perspective of a treatment regime.     

Heat Transfer Phenomena of Assemblages of Smooth Slip Spheres in Newtonian Fluids

Combined effects of slip velocity and volume fraction of slip spheres on the heat transfer characteristics of multiple slip spheres are numerically investigated within the framework of a free surface cell model combined with a linear slip velocity along the surface of the slip spheres. The governing conservation equations of the mass, momentum, and energy are solved by a segregated approach using a simplified marker and cell algorithm implemented on a staggered grid arrangement in spherical coordinates. The convection and diffusion terms of conservation equations are discretized using quadratic upstream interpolation for convective kinematics and second‐order central differencing schemes, respectively. Prior to obtaining new results, this numerical solver is validated by comparison of present results with the existing literature values. Further new results are obtained for a range of conditions as; Reynolds number, Re: 0.1–200; Prandtl number, Pr: 1–100; volume fraction of slip spheres, Φ: 0.1–0.5 and slip parameter, λ: 0.01–100. The effects of these dimensionless parameters on isotherm contours and local and average Nusselt numbers are thoroughly delineated. Finally, a new empirical correlation for the average Nusselt number of multiple smooth slip spheres is proposed on the basis of present numerical results.     

Computational study on metal hydride based three-stage hydrogen compressor

A mathematical model for predicting the performances of a three-stage metal hydride based hydrogen compressor (MHHC) is presented. The performance of the MHHC is predicted by solving the unsteady heat and mass transfer characteristics of the coupled metal hydride beds of cylindrical configuration. The governing equations for energy, momentum and mass conservations, and reaction kinetic equations are solved simultaneously using the finite volume method. Metal hydrides chosen for a three-stage MHHC are LaNi₅, MmNi_4.6Al_0.4 and Ti_0.99Zr_0.01V_0.43Fe_0.99Cr_0.05Mn_1.5. Numerical results obtained for a single-stage MHHC using MmNi_4.6Al_0.4 are in good agreement with the experimental data reported in the literature. Using three-stage compression, a maximum pressure ratio of 28 is achieved for the supply conditions of 20 °C absorption temperature and 2.5 bar supply pressure. A maximum delivery pressure of 100 bar is obtained for the operating conditions of 20 °C absorption temperature and 120 °C desorption temperature.     

A review of technology diffusion models with special reference to renewable energy technologies

Diffusion of renewable energy technologies (RETs) are driven by policies and incentives due to their inherent characteristics such as high upfront costs, lack of level playing field but distinct advantages from energy security, environmental and social considerations. Even after three decades of their promotion, only 20–25% of their potential has been realized. The theory of diffusion modeling allows analysis of diffusion processes and study of growth rates of different technologies and underlying diffusion factors. Their applications have focused on commercial and consumer products such as television, automobiles and IT products and their applications to RETs have been limited. Diffusion analysis of RETs have been based on barriers’ to RET adoption and techno–economic, learning and experience curve approaches. It is observed that these diffusion models when applied to commercial products do not deal with the issues of policy influences which are critical to RET diffusion. Since policies drive RET diffusion, the models for analyzing RET diffusion should allow establishing explicit relationships between the diffusion parameters and policies and their impact on diffusion rates. Given the potential of renewable energy technologies for sustainable development, the aim of this paper is to review different diffusion theory based models and their applicability to RET diffusion analysis.     

Immunological properties of human decidual macrophages--a possible role in intrauterine immunity

Our aim was to investigate the contribution of decidual macrophages, which constitute an important immune component of the decidua in late gestation, to intrauterine defence mechanisms. Using flow cytometry we examined the ability of decidual macrophages, isolated from term decidua, to bind and phagocytose fluorescence-labelled bacterial and yeast bioparticles. We also assessed their ability to generate superoxide radicals and tumour necrosis factor-alpha following lipopolysaccharide challenge. Decidual macrophages bound bacterial and yeast particles in a dose-dependent manner, which subsequently led to phagocytosis. These macrophages also produced superoxide radicals and the pro-inflammatory cytokine TNF-alpha when challenged with bacterial lipopolysaccharides. These results suggest a role for decidual macrophages in pathogen recognition and clearance during pregnancy, and, therefore, they are likely to protect the fetus against intrauterine infections which might otherwise lead to preterm labour.     

Preparation and characterization of spray-deposited Cu2ZnSnS4 thin films

Thin films of Cu₂ZnSnS₄ (CZTS), a potential candidate for absorber layer in thin film heterojunction solar cell, have been successfully deposited by spray pyrolysis technique on soda-lime glass substrates. The effect of substrate temperature on the growth of CZTS films is investigated. X-ray diffraction studies reveal that polycrystalline CZTS films with better crystallinity could be obtained for substrate temperatures in the range 643-683 K. The lattice parameters are found to be a=0.542 and c=1.085 nm. The optical band gap of films deposited at various substrate temperatures is found to lie between 1.40 and 1.45 eV. The average optical absorption coefficient is found to be >10⁴ cm⁻¹.     

迎向更环保的明天：半导体让汽车更环保

低价位新车打入印度汽车市场,印度的汽车总数将于2012年超过4000万辆。空气质量已成为印度政府关注的首要课题,而针对省油引擎管理系统的重要性,