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971.
Yong-Zhao Wang Yong-Xiang Zhao Chun-Guang Gao Dian-Sheng Liu 《Catalysis Letters》2007,116(3-4):136-142
Without use of any surfactant or oxidant, a series of Co3O4 catalysts have been prepared from cobalt nitrate aqueous solution via a very simple liquid-precipitation method with ammonium
acid carbonate followed by calcination at various temperatures. The catalytic performance of the Co3O4 for CO oxidation has been studied with a continuous flowing laboratory microreactor system. The results show that the CO
conversion of all the samples can reach 100% at ambient temperature. The catalyst calcined at 300 °C is able to maintain its
activity for CO complete oxidation more than 500 min at 25 °C and about 240 min even at −78 °C. High reaction temperature
results in a high catalytic stability, while the catalytic stability decreases with further increasing the reaction temperature.
Characterizations with X-ray powder diffraction and transmission electron microscopy suggest that all the samples exist as
a pure Co3O4 phase with the spinel structure, the samples are apt to aggregate and the specific surface area gradually decreases with
increasing the calcination temperature, which directly leads to the decrease of catalytic stability. Furthermore, the amount
of active oxygen species measured by CO titration experiments appears to be critical for catalytic performance. 相似文献
972.
Ye Wan Wenhui Guo Jin Xiao Dazhou Yan Xiong Zhao Shuhu Guo Jianhua Liu Qifan Zhong Tao Yang Yu Zhao Xin Chang Xin Gao 《中国化学工程学报》2020,28(9):2248-2255
Ultra-high-purity silicon tetrachloride (SiCl4) is demanded as an electronic-grade chemical to meet the stringent requirements of the rapidly developing semiconductor industry. The high requirement for ultra-high-purity SiCl4 has created the need for a high-efficient process for reducing energy consumption as well as satisfying product quality. In this paper, a mass of production technology of ultra-high-purity SiCl4 was successfully developed through chlorination reaction in the ultraviolet (UV)-based photo microreactor coupled with the distillation process. The influences of key operational parameters, including temperature, pressure, UV wavelength and light intensity on the product quality, especially for hydrogen-containing impurities, were quantified by the infrared transmittance of Fourier transform infrared spectroscopy (FT-IR) at 2185 cm−1 and 2160 cm−1 indicating that characteristic vibrational modes of SiH bonds, as well as the operating conditions of distillation were also investigated as key factors for metal impurities removing. The advanced intensification of SiCl4 manufactured by the integration of photo microreactor and distillation achieves the products with superior specifications higher than the standard commercial products. 相似文献
973.
轻质油品氧化脱硫技术进展 总被引:9,自引:1,他引:9
介绍了国内外轻质油品氧化脱硫技术的研究进展情况,分析了选择性氧化脱硫、超声波氧化脱硫、光催化氧化脱硫、等离子体液相氧化脱硫等技术的优缺点,展望了氧化脱硫技术应用前景。 相似文献
974.
Hua Zhao 《Chemical Engineering Communications》2006,193(12):1660-1677
Over the past decade, ionic liquids (ILs) have become one of the fastest growing “green” media for chemists and engineers due to their superb physicochemical properties. The applications of these remarkable salts in reactions and extraction processes have been extensively investigated and reviewed. This review, however, highlights recent advances of ILs as versatile “green” engineering liquids in a variety of industrial applications including heat transfer fluids, azeotrope-breaking liquids, lubricants, electrolytes, liquid crystals, supported IL membranes, plasticizers, and more. This review is not intended to be comprehensive, but rather to discuss the potentials of ILs for diverse industrial applications. 相似文献
975.
976.
自行设计了一台单填料函滑动管板式换热器代替进口设备,运转良好。本文着重介绍该设备密封结构的设计。 相似文献
977.
介绍了在直接纺丝设备上,通过工艺调整与设备改进,成功开发129dtex/144f涤纶细旦POY的经验。 相似文献
978.
The chemical composition and quantitative molar ratios among all components of biodegradable polyphosphoester copolymers of DL ‐lactide and ethylphosphate were determined by a comprehensive set of NMR spectroscopic methods. The polyphosphoester copolymers studied were synthesized using condensation polymerization of oligomeric DL ‐lactide prepolymers and ethyl dichlorophosphate. Conclusive identification of the chemical shift patterns of all functional groups in the copolymers required additional NMR methods such as 31P‐NMR and two‐dimensional 1H–1H COSY NMR, in addition to the synthesis and comparative NMR analysis of model compounds possessing identical phosphoester linkages in the polyphosphoester copolymers. For the polymers synthesized using the bulk polycondensation process, 1H–1H COSY NMR analysis revealed the presence of a small amount of side products that were undetected by 1H‐NMR alone. These side reactions most likely occurred between the pendant ethoxy group of the phosphoesters and the hydrogen chloride gas generated in the bulk polycondensation process. 31P‐NMR spectra of the copolymers revealed a consistent triple‐peak pattern characteristic of phosphoesters linked to a racemic mixture of D,L ‐lactides. These results offered new insight into the side reactions occurring in bulk polymerization of polyphosphoesters and provided a powerful tool of characterizing complex biodegradable polymers. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 4021–4031, 2003 相似文献
979.
980.
山西长治钢铁(集团)瑞昌水泥有限公司矿渣粉磨生产线,自2003年8月25日试生产以来,广大工程技术人员对工艺参数不断进行优化,生产日趋正常,台时产量120t,比表面积≥450m^2/kg实现达产达标。笔者有幸参与LM56.2 2S立磨矿渣粉磨系统调试工作,现将调试及生产过程中发现问题作一总结,供同行参考。 相似文献