A new FEBIAD-type ion source for use at the reactor-based ISOL facility TRISTAN

To use a FEBIAD-type ion source at a reactor-based on-line isotope separator facility, several modifications are desirable. Since more beam time is usually available at a reactor than at an accelerator, most of the changes to the ion source were those that make it possible to extend the source lifetime. The modifications described in this paper make it possible to operate a FEBIAD ion source for 1500 continuous hours without a failure. Beams of Zn, Ga, Ge, Br, Kr, Rb, Ag, Cd, In, Sn, Sb, Te, I, Xe, and Cs were obtained from the source and yields are presented for some of these elements. The effect of target outgassing on the operating conditions of the source are discussed and a Penning-ionization mode of operation is postulated.     

Theoretical comparison of the band broadening in nonretained electrically and pressure-driven flows through an ordered chromatographic pillar packing

Using a well-validated computational fluid dynamics simulation method, based on a multi-ion transport model, a detailed analysis of the differences in band broadening between pressure-driven (PD) and electrically driven (ED) flows through perfectly ordered, identical chromatographic pillar packings has been made. It was found that, although the eddy-diffusion band-broadening contributions were nearly completely absent in the considered structure, the ED flow still yields much smaller plate heights than the PD flow. This difference could be fully attributed to the different ways in which the ED and PD velocity profiles reshape when passing through a tortuous pore structure with undulating cross section. Whereas in the PD case the parabolic tip of the band front is continually squeezed and extended each time it passes a pore constriction, the ED flow displays some kind of band front restoring mechanism, with which the fluid elements of the band front are (at least partly) laterally re-aligned after each pore constriction passage. This could be clearly visualized from a series of step-by-step images of the progression of a sharply "injected" species band moving through the packing under ED and PD conditions.     

A correlation for the pressure drop in monolithic silica columns

To gain insight into how the pressure drop in monolithic silica columns is determined by the microscopic details of the pore structure, a series of well-validated computational fluid dynamics simulations has been performed on a simplified model structure, the so-called tetrahedral skeleton column. From these simulations, a direct correlation between the pressure drop and two main structural properties (skeleton thickness and column porosity) of the monolithic skeleton could be established. The correlation shows good agreement with the experimental pressure-drop data available from the literature on silica monoliths, especially when a correction for the flow-through pore size heterogeneity is made. The established correlation also yields a much more accurate representation of the relation between the flow resistance and the bed porosity than does the Kozeny-Carman model, making it much better suited for porosity optimization calculations.     

Goursat Flags: Classification of Codimension-One Singularities

A distribution D of corank on a manifold M is Goursat when its Lie square [D, D] is a distribution of constant corank r-1, the Lie square of [D, D] is of constant corank r-2 and so on. Any such D, according to von Weber [21] and E. Cartan [3], behaves in a well-known way at generic points of M: in certain local coordinates it is the chained model (C) given below, a classical object in the control theory. Singularities concealed in Goursat distributions have emerged for the first time in [8]; by now the complete local classification of these objects of coranks not exceeding 7 is known, plus some isolated facts for coranks 8, 9, and 10. In the present paper we deal with the Goursat distributions of any corank r and obtain a complete classification of the first occurring singularities of them, located at points outside a stratified codimension-2 submanifold of M. Off this set there are (on top of (C)) only r-2 non-equivalent singular behaviours possible.     

Quadrupole-based glow discharge mass spectrometer: Design and results compared to secondary ion mass spectrometry analyses

A design of quadrupole-based glow discharge mass spectrometer is briefly presented. A glow discharge occurs when a DC voltage (up to 3 kV) is applied between two electrodes in a cell filled with Ar at ∼1 hPa pressure. In this configuration, the sample acts as the cathode, and its surface (∼12 mm²) is sputtered by impacting Ar ions. The sputtered neutral atoms are ionised downstream in the plasma, and are extracted through a diaphragm to an energy filter and quadrupole spectrometer (6 mm rods) in high vacuum. The processes of sputtering and ionisation are separated, therefore reducing matrix effects.Preliminary results of elemental analysis of stainless steel, chromium-vanadium steel, Al-Mg-Cu and Armco alloys are presented. These results are compared to secondary ion mass spectrometry (SIMS) results obtained for the same set of samples using a 5 keV Ar⁺ ion beam and a quadrupole mass analyser (16 mm rods). The glow discharge mass spectrometry (GDMS) results allowed us to find SIMS relative sensitivity factors (RSF) for the analysed materials. Simple design and quick analysis time makes the new GDMS analyser an attractive tool in material technology.     

Maximum matchings in planar graphs via gaussian elimination

We present a randomized algorithm for finding maximum matchings in planar graphs in timeO(n ^ω/2), whereω is the exponent of the best known matrix multiplication algorithm. Sinceω<2.38, this algorithm breaks through theO(n ^1.5) barrier for the matching problem. This is the first result of this kind for general planar graphs. We also present an algorithm for generating perfect matchings in planar graphs uniformly at random usingO(n ^ω/2) arithmetic operations. Our algorithms are based on the Gaussian elimination approach to maximum matchings introduced in [16]. This research was supported by KBN Grant 4T11C04425.     

Experimental transient performance of a heat pump equipped with a distillation column

A series of experiments were conducted on a heat pump equipped with a distillation column. The system was operated with R32 and with a 30/70% by mass mixture of R32/134a to examine the difference between the transient performance trends with a pure fluid (R32), and those with a zeotropic mixture (R32/134a). Additionally, the effects of varying heat transfer fluid mass flow, compressor speed, and accumulator sump heat input were examined. Each test was 1 h in duration. The heat pump capacities did not generally achieve steady state during the R32/134a tests. Steady state was generally achieved during the R32 tests. As a percentage of the final (end-of-test) capacity, the rate of capacity increase was greater during the R32/134a tests than during those conducted with the pure fluid. The R32/134a tests exhibited capacity oscillations early in each transient that were not present during the R32 tests. The results show that circulating refrigerant mass and composition are the primary controlling factors with regard to transient capacity.     

基于生物复合材料的双曲面分段式壳体展馆

生物复合材料由于成本低、可再生和对环境友好的特性,在建筑中获得了新颖又广泛的应用。通过一对一的双曲面、参数化设计形成的分段式壳体,来展示生物材料在承重结构中的应用。这种结构由轻质的单向弯曲木和生物复合材料组成,其中,木质纤维基核心由长木纤维以单板形式加固。进一步探讨了高 3.6 m,面积 55 m2 的展馆的建造技术以及生物复合材料应用的可能性。