Thermal degradation of cellulose and its phosphorylated products in air and nitrogen

The thermal degradation of cellulose and its phosphorylated products (phosphates, diethylphosphate, and diphenylphosphate) were studied in air and nitrogen by differential thermal analysis and dynamic thermogravimetry from ambient temperature to 750°C. From the resulting data various thermodynamic parameters were obtained following the methods of Broido and Freeman and Carroll. The values of E_a for decomposition for phosphorylated cellulose were found to be in the range 55–138 kJ mol^?1 in air and 85–152 kJ mol^?1 in nitrogen and depended upon the percent of phosphorus contents in the samples. The mass spectrum of cellobiose phosphate indicated the absence of the molecular ion, indicating that the compound was thermally unstable. The IR spectra of the pyrolysis residues of cellulose phosphate gave indication of formation of a compound having C?O and P?O groups. A fire retardancy mechanism for the thermal degradation of cellulose phosphate has been proposed.     

Load and directional effects on microhardness and estimation of toughness and brittleness for flux-grown LaBO3 crystals

Results of microhardness measurements on (100) and (110) planes of flux-grown LaBO₃ crystals, in the applied load range of 10–100g, are presented. The microhardness was found to decrease with increasing load in a non-linear manner. By applying Hays and Kendall's law, the materials resistance pressure and other constants of the equation could be calculated. Hardness anisotropy, showing periodic variation of H _v with the maxima and minima repeating at every 15° change in orientation of the indentor, is described and discussed. H _max/H_min are estimated as 1.14 and 1.06 for (100) and (110) planes, respectively. The fracture toughness values, K _c, determined from measurements of crack lengths, are estimated to be 1.6, 1.7 MN m^–3/2 (for (100) planes) and 1.2, 1.5 MN m^–3/2 (for (110) planes) at 90 and 100g loads, respectively. The brittleness index, B _i, is estimated as 4.6, 4.0 m^–1/2 (for (100) planes) 6.0, 4.6 m^–1/2 (for (110) planes) at 90 and 100g, loads respectively.     

Prudence in vacillatory language identification

This paper settles a question about prudent vacillatory identification of languages. Consider a scenario in which an algorithmic deviceM is presented with all and only the elements of a languageL, andM conjectures a sequence, possibly infinite, of grammars. Three different criteria for success ofM onL have been extensively investigated in formal language learning theory. IfM converges to a single correct grammar forL, then the criterion of success is Gold's seminal notion ofTxtEx-identification. IfM converges to a finite number of correct grammars forL, then the criterion of success is calledTxtFex-identification. Further, ifM, after a finite number of incorrect guesses, outputs only correct grammars forL (possibly infinitely many distinct grammars), then the criterion of success is known asTxtBc-identification. A learning machine is said to beprudent according to a particular criterion of success just in case the only grammars it ever conjectures are for languages that it can learn according to that criterion. This notion was introduced by Osherson, Stob, and Weinstein with a view to investigating certain proposals for characterizing natural languages in linguistic theory. Fulk showed that prudence does not restrictTxtEx-identification, and later Kurtz and Royer showed that prudence does not restrictTxtBc-identification. This paper shows that prudence does not restrictTxtFex-identification.     

Mechanical and Thermophysical Properties of Cerium Monopnictides

The ultrasonic attenuation due to phonon–phonon interaction, thermoelastic relaxation and dislocation damping mechanisms has been investigated in cerium monopnictides CeX (X: N, P, As, Sb and Bi) for longitudinal and shear waves along \({\langle }100{\rangle }\), \({\langle }110{\rangle }\) and \({\langle }111{\rangle }\) directions. The second- and third-order elastic constants of CeX have also been computed in the temperature range 0 K to 500 K using Coulomb and Born–Mayer potential upto second nearest neighbours. The computed values of these elastic constants have been applied to find out Young’s moduli, bulk moduli, Breazeale’s non-linearity parameters, Zener anisotropy, ultrasonic velocity, ultrasonic Grüneisen parameter, thermal relaxation time, acoustic coupling constants and ultrasonic attenuation. The fracture/toughness ratio is less than 1.75, which shows that the chosen materials are brittle in nature as found for other monopnictides. The drag coefficient acting on the motion of screw and edge dislocations due to shear and compressional phonon viscosities of the lattice have also been evaluated for both the longitudinal and shear waves. The thermoelastic loss and dislocation damping loss are negligible in comparison to loss due to Akhieser damping (phonon–phonon interaction). The obtained results for CeX are in qualitative agreement with other semi-metallic monopnictides.     

Physiatric research fellows'' perceptions of the quality of their training

After being poisoned by eating the mushroom species Cortinarius speciosissimus, a twin developed interstitial nephritis with acute renal failure. He received a renal transplant from his living twin brother, who was presumed dizygotic on phenotypic grounds. Fifteen years later, the twins were zygosity tested by DNA "fingerprint analysis" and found to be monozygotic, despite important phenotypic discordances. The recipient has discontinued immunosuppression therapy and remains well after 9 months. We suggest that, for medical and other reasons, zygosity should be determined at birth on all like-sexed twins.     

Uncountable automatic classes and learning

In this paper we consider uncountable classes recognizable by ω-automata and investigate suitable learning paradigms for them. In particular, the counterparts of explanatory, vacillatory and behaviourally correct learning are introduced for this setting. Here the learner reads in parallel the data of a text for a language L from the class plus an ω-index α and outputs a sequence of ω-automata such that all but finitely many of these ω-automata accept the index α if and only if α is an index for L.It is shown that any class is behaviourally correct learnable if and only if it satisfies Angluin’s tell-tale condition. For explanatory learning, such a result needs that a suitable indexing of the class is chosen. On the one hand, every class satisfying Angluin’s tell-tale condition is vacillatorily learnable in every indexing; on the other hand, there is a fixed class such that the level of the class in the hierarchy of vacillatory learning depends on the indexing of the class chosen.We also consider a notion of blind learning. On the one hand, a class is blind explanatorily (vacillatorily) learnable if and only if it satisfies Angluin’s tell-tale condition and is countable; on the other hand, for behaviourally correct learning, there is no difference between the blind and non-blind version.This work establishes a bridge between the theory of ω-automata and inductive inference (learning theory).     

A clustering performance measure based on fuzzy set decomposition

Clustering is primarily used to uncover the true underlying structure of a given data set and, for this purpose, it is desirable to subject the same data to several different clustering algorithms. This paper attempts to put an order on the various partitions of a data set obtained from different clustering algorithms. The goodness of each partition is expressed by means of a performance measure based on a fuzzy set decomposition of the data set under consideration. Several experiments reported in here show that the proposed performance measure puts an order on different partitions of the same data which is consistent with the error rate of a classifier designed on the basis of the obtained cluster labelings.     

Optimal quadtrees for image segments

Quadtrees are compact hierarchical representations of images. In this paper, we define the efficiency of quadtrees in representing image segments and derive the relationship between the size of the enclosing rectangle of an image segment and its optimal quadtree. We show that if an image segment has an enclosing rectangle having sides of lengths x and y, such that 2N-1 × max (x, y) ? 2N, then the optimal quadtree may be the one representing an image of size 2N × 2N or 2N+1 × 2N+1. It is shown that in some situations the quadtree corresponding to the larger image has fewer nodes. Also, some necessary conditions are derived to identify segments for which the larger image size results in a quadtree which is no more expensive than the quadtree for the smaller image size.