Mg 2+-doped GaN nanoparticles as blue-light emitters: a method to avoid sintering at high temperatures

Bright blue-light emission at 410 nm is observed from Mg(2+)-doped GaN nanoparticles prepared by the nitridation of Ga(2)MgO(4) nanoparticles at 950 degrees C. The sintering of these nanoparticles during high-temperature nitridation was prevented by mixing the Ga(2)MgO(4) precursor nanoparticles with La(2)O(3) as an inert matrix before the nitridation process. The Mg(2+)-doped GaN nanoparticles were isolated from the matrix by etching with 10 % nitric acid. The Mg(2+)-doped GaN nanoparticles were characterized by photoluminescence, atomic force microscopy, X-ray diffraction, and IR analyses.     

Novel Coagulation Method for Direct Coagulation Casting of Aqueous Alumina Slurries Prepared Using a Poly(Acrylate) Dispersant

Coagulation of concentrated aqueous alumina slurries prepared using an ammonium poly(acrylate) dispersant by MgO has been studied for direct coagulation casting (DCC). A small amount of MgO (0.2 wt% of alumina) increased the viscosity of the concentrated alumina slurry with time and finally transformed it into a stiff gel. The mechanism of coagulation is proposed such that the time-delayed in situ generation of Mg²⁺ ions from the sparingly soluble MgO forms Mg–poly(acrylate) with the unadsorbed ammonium poly(acrylate) molecules in solution that shift the poly(acrylate) adsorption equilibrium toward the left by depleting the poly(acrylate) molecules adsorbed on the alumina particle surface. This leads to insufficient dispersant coverage on the particle surface and coagulation of the slurry. DCC using MgO is possible only if the slurry is prepared at a dispersant concentration higher than that required for optimum dispersion as the slurries prepared at the optimum dispersant concentration underwent premature coagulation. The gelation time could be tailored within 20 min to a few hours by maintaining the temperature in the range of 70°–30°C. The wet coagulated bodies prepared from 50 vol% alumina slurry showed a compressive strength of nearly 0.05 MPa.     

Electrospun composite nanofibers for tissue regeneration

Nanotechnology assists in the development of biocomposite nanofibrous scaffolds that can react positively to changes in the immediate cellular environment and stimulate specific regenerative events at molecular level to generate healthy tissues. Recently, electrospinning has gained huge momentum with greater accessibility of fabrication of composite, controlled and oriented nanofibers with sufficient porosity required for effective tissue regeneration. Current developments include the fabrication of nanofibrous scaffolds which can provide chemical, mechanical and biological signals to respond to the environmental stimuli. These nanofibers are fabricated by simple coating, blending of polymers/bioactive molecules or by surface modification methods. For obtaining optimized surface functionality, with specially designed architectures for the nanofibers (multi-layered, core-shell, aligned), electrospinning process has been modified and simultaneous 'electrospin-electrospraying' process is one of the most lately introduced technique in this perspective. Properties such as porosity, biodegradation and mechanical properties of composite electrospun nanofibers along with their utilization for nerve, cardiac, bone, skin, vascular and cartilage tissue engineering are discussed in this review. In order to locally deliver electrical stimulus and provide a physical template for cell proliferations, and to gain an external control on the level and duration of stimulation, electrically conducting polymeric nanofibers are also fabricated by electrospinning. Electrospun polypyrrole (PPy) and polyaniline (PAN) based scaffolds are the most extensively studied composite substrates for nerve and cardiac tissue engineering with or without electrical stimulations, and are discussed here. However, the major focus of ongoing and future research in regenerative medicine is to effectively exploit the pluripotent potential of Mesenchymal Stem Cell (MSC) differentiation on composite nanofibrous scaffolds for repair of organs.     

Processing of sucrose to low density carbon foams

A novel process for preparation low density carbon foams from sucrose has been demonstrated. A resin prepared by heating aqueous acidic sucrose solution when heated in an open Teflon mould at 120 °C undergoes foaming and then setting in to a solid organic foam. The solid organic foam undergoes carbonization in air by dehydration at 250 °C under isothermal condition. Carbon foams thus obtained sintered at temperature in the range 600–1,400 °C showed density in the range 115–145 mg/cc and electrical conductivity in the range 1.5 × 10⁻⁵ to 0.2 ohm⁻¹ cm⁻¹, respectively. The carbon foams contain spherical cells of size in the range 450–850 μm and the cells are interconnected through circular or oval shape windows of size in the range 80–300 μm. The carbon foam samples sintered at 1,400 °C showed compressive strength of 0.89 MPa.     

Age differences in prefrontal cortical activity in working memory.

Working memory (WM) declines with advancing age. Brain imaging studies indicate that ventral prefrontal cortex (PFC) is active when information is retained in WM and that dorsal PFC is further activated for retention of large amounts of information. The authors examined the effect of aging on activation in specific PFC regions during WM performance. Six younger and 6 older adults performed a task in which, on each trial, they (a) encoded a 1- or 6-letter memory set, (b) maintained these letters over 5-s, and (c) determined whether or not a probe letter was part of the memory set. Comparisons of activation between the 1- and 6-letter conditions indicated age-equivalent ventral PFC activation. Younger adults showed greater dorsal PFC activation than older adults. Older adults showed greater rostral PFC activation than younger adults. Aging may affect dorsal PFC brain regions that are important for WM executive components. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Emulsion electrospun vascular endothelial growth factor encapsulated poly(<Emphasis Type="SmallCaps">l</Emphasis>-lactic acid-<Emphasis Type="Italic">co</Emphasis>-ε-caprolactone) nanofibers for sustained release in cardiac tissue engineering

Emulsion electrospinning is a novel approach to fabricate core–shell nanofibers, and it is associated with several advantages such as the alleviation of initial burst release of drugs and it protects the bioactivity of incorporated drugs or proteins. Aiming to develop a sustained release scaffold which could be a promising substrate for cardiovascular tissue regeneration, we encapsulated vascular endothelial growth factor (VEGF) with either of the protective agents, dextran or bovine serum albumin (BSA) into the core of poly(l-lactic acid-co-ε-caprolactone) (PLCL) nanofibers by emulsion electrospinning. The morphologies and fiber diameters of the emulsion electrospun scaffolds were determined by scanning electron microscope, and the core–shell structure was evaluated by laser scanning confocal microscope. Uniform nanofibers of PLCL, PLCL–VEGF–BSA, and PLCL–VEGF–DEX with fiber diameters in the range of 572 ± 92, 460 ± 63, and 412 ± 61 nm, respectively were obtained by emulsion spinning. The release profile of VEGF in phosphate-buffered saline for up to 672 h (28 days) was evaluated, and the scaffold functionality was established by performing cell proliferations using human bone marrow derived mesenchymal stem cells. Results of our study demonstrated that the emulsion electrospun VEGF containing core–shell structured PLCL nanofibers offered controlled release of VEGF through the emulsion electrospun core–shell structured nanofibers and could be potential substrates for cardiac tissue regeneration.     

Animation toolkit based on a database approach for reusing motions and models

As animations become more readily available, simultaneously the complexity of creating animations has also increased. In this paper, we address the issue by describing an animation toolkit based on a database approach for reusing geometric animation models and their motion sequences. The aim of our approach is to create a framework aimed for novice animators. Here, we use an alternative notion of a VRML scene graph to describe a geometric model, specifically intended for reuse. We represent this scene graph model as a relational database. A set of spatial, temporal, and motion operations are then used to manipulate the models and motions in an animation database. Spatial operations help in inserting/deleting geometric models in a new animation scene. Temporal and motion operations help in generating animation sequences in a variety of ways. For instance, motion information of one geometric model can be applied to another model or a motion sequence can be retargeted to meet additional constraints (e.g., wiping action on a table can be retargeted with constraints that reduce the size of the table). We present the design and implementation of this toolkit along with several interesting examples of animation sequences that can be generated using this toolkit.     

Effect of Non-Stoichiometry Oxygen Content on the Magnetization of La<Subscript>1.5</Subscript>Sr<Subscript>0.5</Subscript>NiO<Subscript>4+<Emphasis Type="Italic">δ</Emphasis></Subscript>

We report on magnetization measurements of La_1.5Sr_0.5NiO_4+δ for δ=0.01 and δ=−0.01. Zero field-cooled and field-cooled bulk magnetization measurements were performed parallel to the Ni–O planes of single crystals, and on a polycrystalline δ=0.01 sample. Striking differences in the magnetization curves are observed between the two doping levels that are identifiable in polycrystalline δ=0.01. The bulk magnetization differences indicate a crossover in the magnetic properties of La_2−x Sr _x NiO_4+δ at half doping level, which can be used as a simple non-destructive way to determine whether La_1.5Sr_0.5NiO_4+δ is under or over half doping.     

Effect of Polymer Form and its Consolidation on Mechanical Properties and Quality of Glass/PBT Composites

The aim of this study was to understand the role of the processing in determining the mechanical properties of glass fibre reinforced polybutylene terephthalate composites (Glass/PBT). Unidirectional (UD) composite laminates were manufactured by the vacuum consolidation technique using three different material systems included in this study; Glass/CBT (CBT160 powder based resin), Glass/PBT (prepreg tapes), and Glass/PBT (commingled yarns). The different types of thermoplastic polymer resin systems used for the manufacturing of the composite UD laminate dictate the differences in final mechanical properties which were evaluated by through compression, flexural and short beam transverse bending tests. Microscopy was used to evaluate the quality of the processed laminates, and fractography was used to characterize the observed failure modes. The study provides an improved understanding of the relationships between processing methods, resin characteristics, and mechanical performance of thermoplastic resin composite materials.