Acoustic waves in solids with random cavities,II: Energy density considerations

Summary The propagation of acoustic plane and line-polarized waves in an isotropic solid containing random cavities is studied theoretically and experimentally. The effect of the cavities on the energy density and macroscopic propagation parameters of the acoustic waves is considered and the relationships between the cavities volume concentration, their average dynamic shape factor and the dynamic overall stiffness moduli of the solid are derived in the long wave approximation.     

From Natural Methylation to Versatile Alkylations Using Halide Methyltransferases

Halide methyltransferases (HMTs) enable the enzymatic synthesis of S-adenosyl-l -methionine (SAM) from S-adenosyl-l -homocysteine (SAH) and methyl iodide. Characterisation of a range of naturally occurring HMTs and subsequent protein engineering led to HMT variants capable of synthesising ethyl, propyl, and allyl analogues of SAM. Notably, HMTs do not depend on chemical synthesis of methionine analogues, as required by methionine adenosyltransferases (MATs). However, at the moment MATs have a much broader substrate scope than the HMTs. Herein we provide an overview of the discovery and engineering of promiscuous HMTs and how these strategies will pave the way towards a toolbox of HMT variants for versatile chemo- and regioselective biocatalytic alkylations.     

高强度高压绝缘子产品质量同其结构性能的重要关系(续)——制造者和用户应共同掌握的规则和指标(第二部分)

6　各种电瓷结构分析实例证实结构的差别下面介绍各种电瓷结构分析的结果。从扫描电镜照片 (ＲＥＭ)的判读中可见到这些材料的差别。试样ａ:日本瓷绝缘子Ｃ1 1 0 /1 1 2 ,制造年代 1 997试样ｂ :西门子瓷绝缘子Ｃ1 2 0 ,Ｃ1 3 0 ,制造年代 2 0 0 1试样ｃ:高强度矾土瓷绝缘子 ,西门子 2 0 0 1开发陶瓷岩相试样的制备系经多级金刚石研磨和抛光以及化学浸蚀。为判定气孔状态 ,对磨片作了透光照片 ,在其光亮区放大倍数为 1 0 0∶1 ,而且扫描电镜照片放大倍数为2 0 0∶1。图 5ａ　试样ａ光片的ＬＭ(透光显微镜 )和ＲＥＭ(扫描电镜 )图象 ,放大倍…     

The allelopathic mechanisms of dominance in bracken (Pteridium aquilinum) in Southern California

Bracken,Pteridium aquilinum, exerts a strong dominance over associated plants throughout much of its worldwide range. Associated plants are often severely inhibited or even excluded from dense stands of the fern. This study investigated the various aspects of herb suppression in bracken stands and assessed the contribution of the various forms of interference between plants to the establishment and maintenance of bracken dominance. It was shown that competition for soil moisture, light, and nutrients could not account for the lack of herbs in bracken stands. Further, uniformity of soil pH, texture, water-holding capacity, and organic matter content ruled out variability in physical factors as a cause. Baiting and trapping experiments showed that the higher concentration of animal activity inside the bracken stands contributed significantly to the pattern of herb suppression, but only against select species. The maintenance of this pattern in the animal-free Santa Cruz Island stands indicates the importance of another factor, allelopathy. It was found that phytotoxins leached from the dead, standing bracken fronds with the first few rains of the wet season were largely responsible for herb suppression. These toxins were isolated in raindrip and from soil inside the fern stands. Removal of the fronds from the stand before the rains could leach them resulted in reinvasion by the herbs after several seasons, and, conversely, placing fronds over the herbs in the grassland brought about herb inhibition. A number of known allelopathic chemicals were tentatively identified from bracken leachates. The importance of the interaction of allelopathy with other factors of plant interference is illustrated by bracken.     

护肤品的功效性评价方法综述

现代科学技术,尤其是生物技术和计算机技术的飞速发展和广泛应用,给化妆品行业带来了全新的发展机遇,赋予化妆品以一定的功效性是新世纪化妆品发展的重要趋势.近20年来,人们对化妆品的要求已从洁肤、润肤为目的的基础护肤品向美白、祛皱为目的的功效性化妆品方向发展.     

A geometric solution to the largest-free-sphere problem in zeolite frameworks

We have applied Delaunay triangulation to models of the known zeolite frameworks. We show that this well-established technique from computational geometry provides for each framework; (i) the location and shape of the open pores and channels, (ii) the diameter of the largest possible included sphere, and indirectly (iii) the diameter of the largest-free-sphere that can diffuse through the framework by at least one lattice translation. Since Delaunay triangulation naturally locates the empty spaces within a set of points, it provides a powerful computer-automated tool for determining the physical characteristics of pores and channels of zeolite frameworks. Such tools will further enhance the usefulness of large databases of hypothetical framework materials.

Here, we tabulate results for the 165 zeolite frameworks that are presently listed in the Atlas of Zeolite Frameworks. Of the known zeolites, refined as pure silicates, the largest included sphere occurs in the TSC framework, with a diameter of 16.39 Å. The largest-free-sphere has a diameter of 11.33 Å, for diffusion along the [0 0 1] direction in the VFI framework.     

A mixed boundary-value problem of elasticity with parabolic boundary

Summary The mixed boundary-values problem of elasticity with parabolic boundary when the prescribed displacement is parabolic has been reduced to the solution of the non-homogeneous Hilbert problem following the method of complex variable. The result has been compared with that obtained byParia [5] for parabolic boundary with prescribed constant displacement as a particular case.

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Zusammenfassung Das gemischte Randwertproblem der Elastizitätstheorie wird für parabolische Berandung auf die Lösung des inhomogenen Hilbert-Problems unter Benützung der komplexen Methode zurückgeführt. Die Randverschiebung wird durch ein Polynom zweiten Grades dargestellt. Das Ergebnis wird mit dem vonParia [5] verglichen, das als Sonderfall konstante Verschiebungen am parabolischen Rand vorschreibt.

     

Approximation mit Exponentialsummen

Zusammenfassung Für die Approximation mit Exponentialsummen ist die beste Approximation imTschebyscheffschen Sinne eindeutig, abgesehen von bisher nicht erkannten Ausnahmen. Eindeutigkeit liegt dagegen immer bei der Anpassung mit positiven Exponentialsummen vor. Daß diese Familie eine andere Struktur hat als die bekannten Verallgemeinerungen linearer Funktionenfamilien, zeigt sich am Charakter des Alternantenkriteriums.

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Summary In this paper we investigate the approximation by sums of exponentials in the sense ofChebyshev. The best approximation is shown to be unique apart from exceptions not previously recognized. However, there is always uniqueness, when only sums of positive exponentials are considered. This family has a structure which is different from that of other generalizations of linear families of functions. This feature is reflected in the criterion on the alternations of the error curve.

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Kernforschungszentrum Karlsruhe, Institut für Neutronenphysik und Reaktortechnik