Analysis of a family of unstable lattice orientations in (110) channel die compression

Summary The family of f.c.c. crystal orientations defined by loading direction (110) and any channel die constraint direction between ( ) and ( ) is kinematically unstable. We establish that the experimentally observed finite rotation of the lattice about the loading axis, for initial orientations in this range, is uniquely predicted by the constraints and critical slip-system inequalities without regard to particular hardening theory. We further establish that experimental information on the changing constraint stress would serve to distinguish among theories. Predictions of three specific hardening rules, including classical Taylor hardening and the simple theory, are illustrated for initial constraint directions ( ) and ( ). For the first of these orientations the predictions include constraint stress, lattice rotation, active and latent hardening, and overall crystal shearing to a logarithmic compressive strain of 1.0.     

Isentropic exponents of real gases and application for the air at temperatures from 150 K to 450 K

Summary Three real gas isentropic exponentsk _Tv,k _rv,k _pT are introduced, which when used in place of the classical isentropic exponentk=c _p/c in the ideal gas isentropic change equations, the latter may describe very accurately the isentropic change of real gases. The usual practice of employing exponentk may lead to considerably incorrect results even when the value ofk corresponds to the correct local value ofc _p/c _v of the real gas under examination. The numerical values of the new exponents are calculated in the case of real air for temperatures from 150 K to 450 K and pressures from 1 bar to 1000 bar. It is seen that at low temperatures and high pressures the values of the new exponents differ considerably from the values of the classical exponentk. Therefore, the error resulting by approximating, as is usually the case, the behaviour of real gases by the ideal gas isentropic change equations in a stepwise fashion with exponentk instead of the new exponents, is considerable. It follows that exponentk, which appears in various relations in thermodynamics, fluid mechanics, gasdynamics, heat transfer etc., should be suitably replaced by combinations of the three exponents. Related numerical examples, made in the case of real air, showed that the use ofk leads (in the temperature and pressure ranges examined) to a 5% error in the calculation of blowby rate in internal combustion enginers, high pressure compressors or steam turbines and to a 50% error in the calculation of the isentropic expansion or compression.Nomenclature A _ij,B _i,N _ij,O _ij,Q _ij Coefficients - c Velocity - c _p Specific heat under constant pressure - c _v Specific heat under constant volume - h Specific enthalpy - k Isentropic exponent,k=c _p/c _v - k _pT Real gas isentropic exponent corresponding to the pair of variablesp,T - k _pv Real gas isentropic exponent corresponding to the pair of variablesp, v - k _Tv Real gas isentropic exponent corresponding to the pair of variablesT,v - M Mach number,M=c/ - p Pressure - p _c Pressure at the critical point - R Constant of the air,R=287.22 J/kg K - s Specific entropy - T Temperature - T _c Temperature at the critical point - v Specific volume - v _c Specific volume at the critical point - z Compressibility factor - Sound velocity - T Temperature increment With 14 Figures     

On some new variational formulations and finite element models in classical elastoplasticity

Summary The paper deals with the systematic development of variational methods and associated finite element schemes for the approximate analysis of elastoplastic continua. The major difference between these novel models and existing ones consists in treating the yield condition as an a posteriori (natural) constraint and not as an a priori (essential) constraint. The advantages of this approach over existing ones are pointed out and discussed from a theoretical and a computational standpoint as well.With 1 Figure     

From Natural Methylation to Versatile Alkylations Using Halide Methyltransferases

Halide methyltransferases (HMTs) enable the enzymatic synthesis of S-adenosyl-l -methionine (SAM) from S-adenosyl-l -homocysteine (SAH) and methyl iodide. Characterisation of a range of naturally occurring HMTs and subsequent protein engineering led to HMT variants capable of synthesising ethyl, propyl, and allyl analogues of SAM. Notably, HMTs do not depend on chemical synthesis of methionine analogues, as required by methionine adenosyltransferases (MATs). However, at the moment MATs have a much broader substrate scope than the HMTs. Herein we provide an overview of the discovery and engineering of promiscuous HMTs and how these strategies will pave the way towards a toolbox of HMT variants for versatile chemo- and regioselective biocatalytic alkylations.     

Energieinformatik

Due to the increasing importance of producing and consuming energy more sustainably, Energy Informatics (EI) has evolved into a thriving research area within the CS/IS community. The article attempts to characterize this young and highly dynamic field of research by describing current EI research topics and methods and provides an outlook of how the field might evolve in the future. It is shown that two general research questions have received the most attention so far and are likely to dominate the EI research agenda in the coming years: How to leverage information and communication technology (ICT) to (1) improve energy efficiency, and (2) to integrate decentralized renewable energy sources into the power grid. Selected EI streams are reviewed, highlighting how the respective research questions are broken down into specific research projects and how EI researchers have made contributions based on their individual academic background.     

Geschäftsmodelle

The business model concept, although a relatively new topic for research, has garnered growing attention over the past decade. Whilst it has been robustly defined, the concept has so far attracted very little substantive research. In the context of the wide-spread digitization of businesses and society at large, the logic inherent in a business model has become critical for business success and, hence, a focus for academic inquiry. The business model concept is identified as the missing link between business strategy, processes, and Information Technology (IT). The authors argue that the BISE community offers distinct and unique competencies (e.g., translating business strategies into IT systems, managing business and IT processes, etc.) that can be harnessed for significant research contributions to this field. Within this research gap three distinct streams are delineated, namely, business models in IT industries, IT enabled or digital business models, and IT support for developing and managing business models. For these streams, the current state of the art, suggest critical research questions, and suitable research methodologies are outlined.     

Some theorems of the eddy-current theory

Contents In the paper, theorems for the electric vector potentialT and magnetic scalar potentialU are discussed, which occur in the boundary-value problems for eddy currents induced in a conducting block by an external magnetic field. Uniqueness of the solution is examined. An integral representation of the scalar potentialU is derived for a nonmagnetic conductor. It is shown that for a thin metallic shell the integrodifferential equation results from general formulas related to the block.

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Einige Theoreme der Wirbelstromtheorie

Übersicht In der Arbeit werden drei Theoreme für das elektrische VektorpotentialT und das magnetische SkalarpotentialU beschrieben, die in den Randwertaufgaben für in einem metallischen Block durch das äußere magnetische Feld induzierte Wirbelströme auftreten. Es wird bewiesen, daß eine solche Randwertaufgabe eine eindeutige Lösung hat, wenn das Vektorpotential auf dem Rand gleich Null ist. Eine Integralrepräsentation des Skalarpotentials wird abgeleitet. Es wird gezeigt, daß die Integrodifferentialgleichung für eine dünne metallische Hülle aus allgemeinen, den Block betreffenden Formeln hervorgeht.

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List of principal symbols e coordinate unit vector - H magnetic intensity - J current density - T electric vector potential - U magnetic scalar potential - permeability - conductivity - V boundary of regionV