Highly Cooperative Tetrametallic Ruthenium-mu-Oxo-mu-Hydroxo Catalyst for the Alcohol Oxidation Reaction

The tetrametallic ruthenium-oxo-hydroxo-hydride complex {[(PCy(3))(CO)RuH](4)(mu(4)-O)(mu(3)-OH)(mu(2)-OH)} (1) was synthesized in two steps from the monomeric complex (PCy(3))(CO)RuHCl (2). The tetrameric complex 1 was found to be a highly effective catalyst for the transfer dehydrogenation of alcohols. Complex 1 showed a different catalytic activity pattern towards primary and secondary benzyl alcohols, as indicated by the Hammett correlation for the oxidation reaction of p-X-C(6)H(4)CH(2)OH (rho = -0.45) and p-X-C(6)H(4)CH(OH)CH(3) (rho = +0.22) (X = OMe, CH(3), H, Cl, CF(3)). Both a sigmoidal curve from the plot of initial rate vs [PhCH(OH)CH(3)] (K(0.5) = 0.34 M; Hill coefficient, n = 4.2+/-0.1) and the phosphine inhibition kinetics revealed the highly cooperative nature of the complex for the oxidation of secondary alcohols.     

Heliumlecktestgeräte für die Qualitätsprüfung von Gehäusen für Vakuumverdichter

Helium leak test devices for the quality inspection of housings for vacuum compressors The well‐known and wide‐spread helium leak test method is a safe and fast quality testing method for construction units of any kind. Due to its safe examination and the short time of examination it is predominantly inserted into automated production lines as e.g. in the automobile supporting industry up to the examination by Airbags and rims of wheel. Likewise in addition, for the construction units, machines and devices of the vacuum engineering. From this the demand results simple and in particular economical devices for the helium leak test of construction units with small numbers of items of under 200 pieces per day. For these manufacturing profiles economical ways for the helium leak test are pointed out.     

资秩学院单元07

日益增加的对于艺术的自治和自知，导致出现了这种范例式的建筑：白色立方体（白色的盒子）。这种白色盒子系统的边界被质疑：外部有来自社会的和经济上的压力，内部有在艺术实践中的压力，包括外部形象。本单元的目的是要研究在这些边界冲突的地方建筑的含意，发展一种新的自由诗歌样的系统模式，以及界定开放空间和封闭空间的途径。     

Bemerkungen zum Biot-Savartschen Gesetz

Übersicht Die folgende Arbeit verfolgt u. a. auch didaktische Absichten. Das Biot-Savartsche Gesetz wird oft falsch oder mindestens sehr mißverständlich dargestellt und auch auf unzulässige Weise benutzt. Ausgangspunkt der Mißverständnisse ist die auch in vielen Lehrbüchern anzutreffende unkorrekte Aussage, man könne einem von StromI durchflossenen Linienelement ds ein magnetostatisches Feld dB [entsprechend der Gleichung (32) des folgenden Beitrags] zuordnen. Im folgenden werden derartige Aussagen untersucht und in modifizierter Form korrekt dargestellt.

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Remarks concerning the Law of Biot-Savart

Contents The following paper is at least partly of a didactic nature. The Biot-Savart law of magnetostatics is often interpreted in an illegitimate manner and consequently applied incorrectly. The source of these misunderstandings and errors is the incorrect statement that a magnetic field dB [as given by equation (32) of this paper] is caused by an electric currentI flowing along a line element ds, a statement very popular also in many textbooks. Questions related to this problem are investigated and widespread misleading statements are replaced by correct ones.

     

Guaranteed inclusions for the complex generalized eigenproblem

A method is described which produces guaranteed bounds for a solution of the generalized complex eigenproblem. The method extends a similar approach for general systems of nonlinear equations to the special case of complex pencils, where under weaker assumptions stronger assertions can be proved.     

Modeling and design optimization of switched reluctance machine byboundary element analysis and simulation

Nonlinear boundary element analysis provides a more accurate and detailing tool for the design of switched reluctance machines than conventional equivalent-circuit methods. Design optimization through more detailed analysis and simulation can reduce development and prototyping costs and time to market. Firstly, magnetic field modeling of an industrial switched reluctance machine by the boundary element method is reported in this paper. Secondly, performance prediction and dynamic simulation of motor and control design are presented. Thirdly, magnetic forces that cause noise and vibration are studied, to include the effects of motor and control design variations on noise in the design process. Testing of such a motor in the NEMA 215-Frame size is carried out to verify the accuracy of modeling and simulation     

光纤智能复合材料

对光纤型智能复合材料的工作原理，性能特点和应用前景作了介绍，并讨论了制造成型的技术问题。