Lithium Phenolate Complexes with a Pyridine‐Containing Polymer for Solution‐Processable Electron Injection Layers in PLEDs

A series of (vinylphenyl)pyridine‐based polymer binders, PVPh2Py, PVPh3Py, and PVPh4Py, are designed and synthesized and it is found that mixtures of Liq and the polymers exhibit superior electron injection characteristics as ultrathin (1.6 nm) electron injection layer (EIL) films. They are comparable to those of EILs composed only of Liq. The addition of the polymers does not deteriorate the performance of Liq EILs. Additionally, when the EIL thickness is increased from 1.6 nm to 16 nm, the driving voltages increase and the external quantum efficiencies decrease. The increase in the voltage and decrease in the EQE are suppressed in the device with mixed EILs compared to those observed for the device composed of 100 wt% Liq. Furthermore, the position of the nitrogen in the pyridine ring is considered to influence the electron transport properties of the EILs. The mixing PVPh4Py with Liq improves the driving voltage of the fabricated devices, even with a thick mixed EIL. This reduced dependence of the performance of EILs on their thickness will be advantageous for the coating of large areas using solution processes.     

重叠端口通道的四、五层布线算法

本文提出了一个重叠端口通道的四、五层布线算法,算法的目标是占用尽可能少的通道布线行数,为此算法中采用了扩展布线的概念,将部分线网分配到器件区域中进行布线,在通道内部布线时,引入了重叠端口通道的垂直约束矩阵的概念,并用它来避发式算法的线网布线顺序,算法在任何情况下都能保证布线的成功,从运行实例上来看,算法速度很快,而且结果都是近似最优的（或者是最优,或者是比最优解多一个布线行）。     

A Molecular Brush Approach to Enhance Quantum Yield and Suppress Nonspecific Interactions of Conjugated Polyelectrolyte for Targeted Far‐Red/Near‐Infrared Fluorescence Cell Imaging

A red‐fluorescent conjugated polyelectrolyte (CPE, P2 ) is grafted with dense poly(ethylene glycol) (PEG) chains via click chemistry and subsequently modified with folic acid to form a molecular brush based cellular probe ( P4 ). P4 self‐assembles into a core–shell nanostructure in aqueous medium with an average size of 130 nm measured by laser light scattering. As compared to P2 , P4 possesses not only a substantially higher quantum yield (11%), but also reduced nonspecific interactions with biomolecules in aqueous medium due to the shielding effect of PEG. In conjunction with its high photostability and low cytotoxicity, utilization of P4 as a far‐red/near‐infrared cellular probe allows for effective visualization and discrimination of MCF‐7 cancer cells from NIH‐3T3 normal cells in a high contrast, selective, and nonviral manner. This study thus demonstrates a flexible molecular brush approach to overcome the intrinsic drawbacks of CPEs for advanced bioimaging applications.     

C波段大栅宽GaAs MESFET的研制

采用高质量的 MBE材料 ,成功地制作了单胞栅宽 2 0 mm的芯片。用栅与 n+凹槽自对准和辅助侧墙工艺制作了栅长 0 .45 μm的 Ti Pt Au栅 ,欧姆接触采用 Au Ge Ni合金工艺 ,采用 PECVD Si N钝化 ,空气桥结构及芯片减薄 Via-Hole工艺。经内匹配得到了单胞芯片 3.7～ 4.2 GHz下 Po≥ 7.3W,Gp≥ 8d B,ηadd>2 5 % ;4胞合成器件 Po≥ 2 5 W,Gp>7d B,ηadd>2 5 %的良好结果。     

对策论方法在信息网络资源分配中的应用

在研究复杂信息网络的资源分配问题时,网络资源提供者和用户之间对资源的使用存在不同的优化目标,导致对资源分配策略存在多种评价准则。为便于网络管理者进行分布式的资源管理和计费,采用对策论模型分析用户对资源的竞争和处理网络传输拥塞正日益受到广泛的重视。本文首先指出资源分配和计费管理的几个主要难点,比较了中心化与非中心化控制策略的差别,而后综述了采用对策论模型进行资源分配和管理的优点,重点讨论了在非中心化条件下对策均衡解与资源利用效率以及网络计费管理策略之间的关系,最后对基于对策论模型的信息网络流量控制与管理策略进行总体评述。     

Magnetocontrollable Droplet and Bubble Manipulation on a Stable Amphibious Slippery Gel Surface

Smart manipulation of liquid/bubble transport has garnered widespread attention due to its potential applications in many fields. Designing a responsive surface has emerged as an effective strategy for achieving controllable transport of liquids/bubbles. However, it is still challenging to fabricate stable amphibious responsive surfaces that can be used for the smart manipulation of liquid in air and bubbles underwater. Here, amphibious slippery surfaces are fabricated using magnetically responsive soft poly(dimethylsiloxane) doped with iron powder and silicone oil. The slippery gel surface retains its magnetic responsiveness and demonstrates strong affinity for bubbles underwater but shows small and switching resistance forces with the water droplets in air and bubbles underwater, which is the key factor for achieving the controllable transport of liquids/bubbles. On the slippery gel surface, the sliding behaviors of water droplets and bubbles can be reversibly controlled by alternately applying/removing an external magnetic field. Notably, compared with slippery liquid‐infused porous surfaces, the slippery gel surface demonstrates outstanding stability, whether in air or underwater, even after 100 cycles of alternately applying/removing the magnetic field. This surface shows potential applications in gas/liquid microreactors, gas–liquid mixed fluid transportation, bubble/droplet manipulation, etc.     

Analysis of the properties of soft morphological filtering usingthreshold decomposition

We present the properties of soft morphological operations and the new definitions of binary soft morphological operations. It is shown that soft morphological filtering an arbitrary signal is equivalent to decomposing the signal into binary signals, filtering each binary signal with a binary soft morphological filter, and then reversing the decomposition. This equivalence allows problems in the analysis and the implementation of soft morphological operations in real time by using only logic gates for binary signals instead of sorting the numbers. The architectures of logic-gate implementation of soft morphological operations are also presented. Furthermore, unlike standard morphological filters, the soft morphological closing and opening are in general not idempotent. We develop the conditions and properties for a new class of idempotent soft morphological filters     

应用于微型PCR芯片的微加热器特性研究

设计制作了一种应用于微型聚合酶链式反应(PCR)芯片的微加热器。然后按照PCR循环温度的要求,利用该加热器进行了PCR温度实验。微加热器采用与MEMS工艺兼容的溅射方法在Si基上制作,微加热器材料为金属Pt。通过控制施加电压大小及时间,进行了变性温度、退火温度和延伸温度实验。结果表明:在25 V和32 V电压控制下的温升速度分别为0.68℃/s和1.23℃/s。在断电自然冷却下的降温速度均达到1℃/s。在一个PCR循环周期中每个反应仓的平均功耗为50 mW,最大功耗80 mW,整个10 mm×10 mm芯片的最大功耗为0.96 W。完成第一次PCR温度循环需要220 s,之后的每次循环仅需要175 s。     

一种微型Pt温度传感器及其读出电路的研究

基于电阻温度系数(TCR)原理及微机电系统技术,设计并制作了一种用于微型聚合酶链式反应(PCR)芯片的Pt温度传感器及其读出电路。利用溅射和剥离技术将厚度为100 nm的弯曲条形Pt传感器制作在硅衬底上。其长度和宽度分别为2 030μm和10μm。设计了基于四线法温度测量的读出电路,该电路主要包括一个恒流源电路和一个电压放大电路。测试结果表明,该传感器的电阻温度系数为1.48×10-3℃-1,其电阻变化随着温度的变化具有良好的线性度,当温度在27～100℃变化时,电阻范围在653.5～716.5Ω变化。在接出一个8位的模数转换器以后,整个传感器和读出电路能确保一个精度为0.2℃的温度控制,满足一般PCR测量需要。