Estimating the number of faults: efficiency of removal, recapture,and seeding

Various experimental designs for estimating the number of faults in a system are studied including: (1) removal of each fault as it is detected; (2) marking of each fault as it is detected; and (3) introduction of a known number of faults into the system followed by (1) or (2). A unified framework is developed for comparing these designs; it also produces simplified estimators having high efficiency relative to maximum likelihood estimators. The designs are compared in terms of: (1) statistical accuracy; and (2) the number of failures that need to occur to achieve a given accuracy. On the basis of these comparisons, some general recommendations are made on the level of seeding as well as the choice of removal or recapture designs. When the testing effort is sufficient so that roughly two thirds of the faults are detected, the removal-design is preferred over the recapture-design, and there are no gains from seeding. However, this conclusion depends on assigning unit cost to all fault detections, which might not always be reasonable     

Ultra-Stable oligonucleotide-gold and -silver nanoparticle conjugates prepared by a facile silica reinforcement method

We report a simple method of enhancing the chemical stability of monothiol-modified oligonucleotide-gold and -silver nanoparticle conjugates by a thin silica reinforcement coating. Conventional conjugates prepared by chemisorption of monothiol-modified oligonucleotides onto nanoparticle surfaces undergo rapid aggregation in the presence of thiol-containing small molecules (e.g., dithiothreitol) due to ligand exchange reactions. When the conjugates are treated with (3-mercaptopropyl)trimethoxysilane, a thin silica layer is formed on the nanoparticle surface, thereby entrapping and reinforcing the thiol-gold/-silver linkage. These silica-modified oligonucleotide-gold and -silver nanoparticle conjugates become much more stable toward dithiothreitol as compared to the unmodified conjugates. Moreover, the silica layer significantly hinders the gold/silver core from oxidative dissolution by sodium cyanide. Importantly, the unique hybridization-induced color change property of the oligonucleotide-gold and -silver nanoparticle conjugates is preserved even under harsh condition (i.e., high concentrations of dithiothreitol). Taken together, these ultra-stable oligonucleotide-nanoparticle conjugates hold promise for new diagnostics and therapeutics.      

Opaline backreflector coating in dye-sensitized solar cell

Photonic crystals are ordered nanostructures that are designed to manipulate the propagation of light. The periodicity of a photonic crystal can be engineered to be highly reflective at selected wavelengths. In this work, a mono-layer and double-layer colloidal photonic crystal film were self-assembled on a glass substrate to be used as backreflectors in a dye-sensitized solar cell (DSSC). The colloidal photonic crystal film consists of different polystyrene monodispersed particles with sizes between 200 nm and 290 nm. Making use of flow controlled vertical deposition (FCVD) method, opaline films of Bragg's reflection wavelength between 450 nm to 750 nm were achieved. These wavelengths were designed to match the absorption spectrum of the Ruthenium-complex dye used in DSSC. An enhancement in incident photon-to-current conversion efficiency (IPCE) of the opaline backreflector DSSC of about 30% at Bragg's peak wavelength has been achieved.     

An energy‐based damage parameter for the life prediction of AISI 304 stainless steel subjected to mean strain

Abstract

This study extends the plastic strain energy approach to predict the fatigue life of AISI 304 stainless steel. A modified energy parameter based on the stable plastic strain energy density under tension conditions is proposed to account for the mean strain and stress effects in a low cycle fatigue regime. The fatigue life curve based on the proposed energy parameter can be obtained directly by modifying the parameters in the fatigue life curve based on the stable plastic strain energy pertaining to fully reversed cyclic loading. Hence, the proposed damage parameter provides a convenient means of evaluating fatigue life on the mean strain or stress effect. The modified energy parameter can also be used to explain the combined effect of alternating and mean strain/stress on the fatigue life. In this study, the mean strain effects on the fatigue life of AISI 304 stainless steel are examined by performing fatigue tests at different mean strain levels. The experimental results indicate that the combination of an alternating strain and a mean strain strongly influences the fatigue life. Meanwhile, it is found that the change in fatigue life is sensitive to changes in the proposed damage parameter under the condition of a constant strain amplitude at various mean strain levels. A good agreement is observed between the experimental fatigue life and the fatigue life predicted by the proposed damage parameter. The damage parameter proposed by Smith et al. (1970) is also employed to quantify the mean strain effect. The results indicate that this parameter also provides a reasonable estimate of the fatigue life of AISI 304 stainless steel. However, a simple statistical analysis confirms that the proposed damage parameter provides a better prediction of the fatigue life of AISI 304 stainless steel than the SWT parameter.     

Dantzig–Wolfe decomposition and plant-wide MPC coordination

Due to the enormous success of model predictive control (MPC) in industrial practice, the efforts to extend its application from unit-wide to plant-wide control are becoming more widespread. In general, industrial practice has tended toward a decentralized MPC architecture. Most existing MPC systems work independently of other MPC systems installed within the plant and pursue a unit/local optimal operation. Thus, a margin for plant-wide performance improvement may be available beyond what decentralized MPC can offer. Coordinating decentralized, autonomous MPC has been identified as a practical approach to improving plant-wide performance. In this work, we propose a framework for designing a coordination system for decentralized MPC which requires only minor modification to the current MPC layer. This work studies the feasibility of applying Dantzig–Wolfe decomposition to provide an on-line solution for coordinating decentralized MPC. The proposed coordinated, decentralized MPC system retains the reliability and maintainability of current distributed MPC schemes. An empirical study of the computational complexity is used to illustrate the efficiency of coordination and provide some guidelines for the application of the proposed coordination strategy. Finally, two case studies are performed to show the ease of implementation of the coordinated, decentralized MPC scheme and the resultant improvement in the plant-wide performance of the decentralized control system.     

Large-scale and uniform preparation of pure-phase wurtzite GaAs NWs on non-crystalline substrates

One of the challenges to prepare high-performance and uniform III-V semiconductor nanowires (NWs) is to control the crystal structure in large-scale. A mixed crystal phase is usually observed due to the small surface energy difference between the cubic zincblende (ZB) and hexagonal wurtzite (WZ) structures, especially on non-crystalline substrates. Here, utilizing Au film as thin as 0.1 nm as the catalyst, we successfully demonstrate the large-scale synthesis of pure-phase WZ GaAs NWs on amorphous SiO₂/Si substrates. The obtained NWs are smooth, uniform with a high aspect ratio, and have a narrow diameter distribution of 9.5 ± 1.4 nm. The WZ structure is verified by crystallographic investigations, and the corresponding electronic bandgap is also determined to be approximately 1.62 eV by the reflectance measurement. The formation mechanism of WZ NWs is mainly attributed to the ultra-small NW diameter and the very narrow diameter distribution associated, where the WZ phase is more thermodynamically stable compared to the ZB structure. After configured as NW field-effect-transistors, a high I_ON/I_OFF ratio of 10⁴ − 10⁵ is obtained, operating in the enhancement device mode. The preparation technology and good uniform performance here have illustrated a great promise for the large-scale synthesis of pure phase NWs for electronic and optical applications.     

Open-ended TiO2 nanotubes formed by two-step anodization and their application in dye-sensitized solar cells

We demonstrate a simple method to fabricate open-ended TiO(2) nanotube (NT) based dye-sensitized solar cells (DSSCs), where the NTs are attached to either TiO(2) nanorods (NRs) grown on fluorine-doped tin oxide (FTO) or FTO directly by nanoparticles (NPs). A completely hole-through TiO(2) NT layer is fabricated via a two-step anodization with heat treatment immediately after the first anodization. DSSCs with the open-ended NTs show better photovoltaic performance than those with close-ended NTs, due to the enhanced charge transport in the open-ended structure. Under optimum conditions, DSSCs fabricated with the open-ended NT layer exhibit a short circuit current density (J(sc)) of 19.10 mA cm(-2), an open circuit voltage (V(oc)) of 0.68 V, a fill factor (FF) of 0.49, and a power conversion efficiency (eff) of 6.3%.     

Halogen-free solvent processing for sustainable development of high efficiency organic solar cells

Eliminating processing with halogenated solvents is desirable to achieve sustainable large-scale fabrication of organic solar cells. This work demonstrates a device processing approach completely free of halogenated solvents to yield high-performance (power conversion efficiency, η_P > 6%) polymer:fullerene bulk-heterojunction solar cells comprising a conjugated polymer PIDT-phanQ and [6,6]-phenyl-C71-butyric acid methyl ester (PC₇₁BM). Introducing 2% 1-methylnaphthalene (Me-naph) as a processing additive to toluene alleviates PC₇₁BM solubility problems, reduces phase domain size by two orders of magnitude, and boosts efficiency from η_P = 0.02% to 6.10%. Both AFM and TEM imaging show that the Me-naph additive promotes a more finely phase-separated morphology in spin-coated films, while photoluminescence quenching and photoinduced absorption spectroscopy confirm that this finer morphology results in both better exciton quenching and more efficient charge separation.     

Boosting Infrared Light Harvesting by Molecular Functionalization of Metal Oxide/Polymer Interfaces in Efficient Hybrid Solar Cells

Hybrid solar cells based on light absorbing semiconducting polymers infiltrated in nanocrystalline TiO₂ electrodes, have emerged as an attractive concept, combining benefits of both low material and processing costs with well controlled nano‐scale morphology. However, after over ten years of research effort, power conversion efficiencies remain around 0.5%. Here, a spectroscopic and device based investigation is presented, which leads to a new optimization route where by functionalization of the TiO₂ surface with a molecular electron acceptor promotes photoinduced electron transfer from a low‐band gap polymer(poly[2,6‐(4,4‐bis‐(2‐ethylhexyl)‐4H‐cyclopenta[2,1‐b;3,4‐b0]dithiophene)‐alt‐4,7‐(2,1,3‐benzothiadia‐zole)] (PCPDTBT) to the metal oxide. This boosts the infrared response and the power conversion efficiency to over 1%. As a further step, by “co‐functionalizing” the TiO₂ surface with the electron acceptor and an organic dye‐sensitizer, panchromatic spectral photoresponse is achieved in the visible to near‐IR region. This novel architecture at the heterojunction opens new material design possibilities and represents an exciting route forward for hybrid photovoltaics.     

The Interfacial Bond Strength in Glass Fibre-Polyester Resin Composite Systems

The interfacial bond strength in glass fibre-polyester resin composites has been investigated using various experimental techniques. These included blocks of resin containing fibre (in which, depending on the geometry of the specimen, failure occurs in either a shear or tensile mode) the pullout of a fibre from a disc of resin and a short beam shear test for interlaminar shear strength determination.

Low power optical microscopy and optical retardation measurements of stress induced birefringence were used to detect the difference between intact and debonded fibre resin interfaces. The shear modulus and shear strength of the resin were obtained from torsion tests on cylindrical rods of the resin.

The single fibre shear debonding specimen and the short beam shear test are shown to be the most viable test methods but interpretation of the results is complicated by the various modes of failure possible and by the different stress states which exist in the area of the specimen where debonding starts. Stress concentration factors obtained by finite element analysis and photoelastic analysis have been applied to the results from these tests and the corrected interfacial bond strengths are in close agreement.

The real interfacial bond strengths of well bonded glass-fibre polyester resin systems is shown to be of the order of 70 MN m^?2.