Enhanced sound absorption properties of porous ceramics modified by graphene oxide films

Under the condition of constant thickness, improving the low-frequency sound absorption performance of conventional sound-absorbing materials is a challenging research topic. To address this issue, a new reduced graphene oxide/polyvinyl alcohol (RGO/PVA) porous composite ceramic was fabricated using freeze-drying and optimized by redesigning the internal connecting pores of porous ceramic matrixes with a reticular microstructure using RGO and PVA. The as-prepared porous structure showed significant enhancement in the low-frequency sound absorption band compared with pristine porous ceramics. In addition, the hybrid porous ceramics exhibited low thermal conductivity. These favorable properties indicate that the hybrid sound-absorbing ceramics have potential application prospects for noise reduction in the fields of construction and electrical and mechanical devices.     

管井降水技术在多种含水介质基坑工程中的应用

结合蚌埠城市中心广场会展中心工程，介绍了管井降水技术在多种含水介质的复杂地质环境下的应用。     

Thermal degradation behavior and gas phase flame‐retardant mechanism of polylactide/PCPP blends

The thermal degradation behavior of the blend based on polylactide (PLA) and poly(1,2‐propanediol 2‐carboxyethyl phenyl phosphinate) (PCPP) was investigated by the thermogravimetric analysis (TGA). Thermal degradation activation energies (E_a) of neat PLA and PLA/15% PCPP blend were calculated via the Flynn–Wall–Ozawa method. The E_a of the blends increased with the addition of PCPP increasing when the conversion was higher than 10%. In addition, the appropriate conversion models for the thermal degradation process of PLA and PLA/15% PCPP were studied via the Criado method. At the same time, the main gaseous decomposition products of PLA and its blend were identified by TGA/infrared spectrometry (TGA–FTIR) analysis. And it revealed that the PCPP improved the flame‐retardant property of PLA via altering the release of the flammable gas and nonflammable gas. Moreover, the PCPP improved the flame‐retardant property of PLA by inhibiting exothermic oxidation reactions in the combustion, which was further proved by pyrolysis–gas chromatography–mass spectrometry analysis. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40480.     

功能化聚苯乙烯复合材料的研究进展

简要阐述了聚苯乙烯的分类、特点及发展趋势。同时,从阻燃性、超疏水性、可降解性、导电性及光催化性等方面对聚苯乙烯功能化复合材料进行了简单介绍。最后,对功能化聚苯乙烯复合材料的研究前景进行了展望。     

吸附器的工程设计

详细介绍了实现变压吸附气体分离技术的关键设备—吸附器的设计,及其制造检验相关的要求。     

Two micrometer fluorescence emission and energy transfer in Yb3+/Ho3+ co-doped lead silicate glass

Enhanced 2.0 μm and visible up-conversion emissions from Ho³⁺ via Yb³⁺ sensitization in lead silicate glasses have been obtained under the excitation of 980-nm laser diode. The possible energy transfer mechanism has been analyzed based on the photoemission spectroscopy and lifetime measurement. The lifetime of Ho³⁺: ⁵I₇ laser upper level has also been measured. Based on the absorption spectra, Judd–Ofelt parameters, spontaneous emission probability, the absorption, emission cross sections, and gain coefficients have been calculated and analyzed. The results indicate that the Yb³⁺/Ho³⁺ co-doped lead silicate glass has potential application in mid-infrared wavelengths.     

Enantioselective One‐Pot Reaction: Organocatalyzed Synthesis of Fully Functionalized Oxabicyclo[2.2.2]octanes with Seven Contiguous Stereocenters

An enantioselective one‐pot Michael/Michael/Henry/hemiacetalization reaction between α,β‐unsaturated aldehydes, α‐ketoamides, and nitroalkenes under mild conditions catalyzed by a diarylprolinol silyl ether has been developed. The sequential methodology provides a direct approach to a wide range of fully substituted chiral oxabicyclo[2.2.2]octanes with seven contiguous stereocenters in moderate to excellent yields (up to 99%), high to excellent diastereoselectivities (up to >25:1 dr), and high to excellent enantioselectivities (up to 99% ee).

     

聚四氟乙烯未烧结带的分类及应用

介绍了聚四氟乙烯分散树脂及未烧结带的特点,综述了聚四氟乙烯未烧结带的分类和应用,指出了其存在的问题,并对未来的发展进行了展望。     

Pharmacokinetic Comparison of Berberine in Rat Plasma after Oral Administration of Berberine Hydrochloride in Normal and Post Inflammation Irritable Bowel Syndrome Rats

In the present study, post inflammation irritable bowel syndrome (PI-IBS) rats were firstly established by intracolonic instillation of acetic acid with restraint stress. Then the pharmacokinetics of berberine in the rat plasma were compared after oral administration of berberine hydrochloride (25 mg/kg) to normal rats and PI-IBS rats. Quantification of berberine in the rat plasma was achieved by using a sensitive and rapid UPLC-MS/MS method. Plasma samples were collected at 15 different points in time and the pharmacokinetic parameters were analyzed by WinNonlin software. Compared with the normal group, area under the plasma concentration vs. time curve from zero to last sampling time (AUC_0–t) and total body clearance (CL/F) in the model group significantly increased or decreased, (2039.49 ± 492.24 vs. 2763.43 ± 203.14; 4999.34 ± 1198.79 vs. 3270.57 ± 58.32) respectively. The results indicated that the pharmacokinetic process of berberine could be altered in PI-IBS pathological conditions.