Hydrothermal products of the C3MS2-C12A7-MgO system

The autoclave products of reduced steel-slag of an electronic furnace mainly containing C₃MS₂ phase were detected. The hydrothermal products of this slag included calcio-chondrodite, brucite, and hydrogarnet phases. When suitable (CaO + MgO)/SiO₂ molar ratios were chosen, C₃MS₂ can react with SiO₂ to produce calcium silicate hydrates tobermorite, xonotlite, gyrolite, and truscottite phases with different saturated water vapor pressures. The phase brucite was present along with tobermorite, whereas phases Mg-xonotlite, Mg-gyrolite, and Mg-truscottite can rarely coexist with brucite. Hydrogarnet phase disappeared when Mg-truscottite was formed.     

孔雀绿分光光度法测定炭素制品中微量铅的研究

采用分光光度法来测定炭素制品中微量铅的含量。经比较实验确定了该方法最佳的实验奈件。该方法操作简便、快速、检出限低、灵敏度高，是检测微量铅含量一种较理想的方法。     

添加辣椒碱类化合物合成抗菌高吸水树脂

以过硫酸铵、亚硫酸氢钠作为引发剂，N，N’-亚甲基双丙烯酰胺作为交联剂，将木薯淀粉与丙烯酸、辣椒碱在水溶液中接枝共聚，合成了具有抗菌性的高吸水性树脂。文章主要考察了添加辣椒碱形式、反应温度、反应时间、引发剂用量、丙烯酸中和度、交联剂用量对合成产物吸水性能的影响。     

改进β-紫罗兰酮的合成方法

以氢氧化锂/助催化剂为催化剂体系,柠檬醛为原料合成β-紫罗兰酮。此催化剂体系有良好选择性,用量少、成本低、对环境污染小。同时对反应溶剂、温度、反应时间等因素进行优化,使其适用于工业生产,最终摩尔收率可达86%以上。     

Effects of the electrospray ionization parameters on the formation and morphology of colloidal microspheres of polyacrylonitrile

Polyacrylonitrile colloidal microspheres have been successfully prepared with different concentrations of electrospraying polyacrylonitrile solutions. The morphology of the colloidal spheres has two kinds of structures and is strongly affected by electrospray‐ionization parameters, such as the polymer concentration, applied voltage, and distance between the electrodes. The solvent can also affect the morphology of polyacrylonitrile. The optimum conditions for preparing colloidal spheres have been found, and differential scanning calorimetry results indicate that polyacrylonitrile colloid spheres are amorphous. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 2889–2893, 2006     

二甲醚燃烧用掺杂钡、镍六铝酸盐催化剂的研究

二甲醚是易液化，便于运输，清洁化的新能源。当作为燃料使用时，采用催化燃烧的方法能使得燃烧的起燃温度降低和提高燃烧转化率，克服了普通燃烧的缺点，实现了清洁燃烧。对二甲醚催化燃烧用的催化剂BaNiAl11O19-δ进行了制备与研究。采用溶胶-凝胶法制备六铝酸盐催化剂BaNiAl11O19-δ,考察其对新能源二甲醚催化燃烧反应的活性，并用TG—DTA对催化剂的性质进行考察。结果表明，加入经800℃焙烧4h后又在1200℃焙烧了2h的催化剂，比未加催化剂的燃烧体系T10降低了50℃。用溶胶一凝胶法制备的六铝酸盐催化剂BaNiAl11O19-δ对二甲醚催化燃烧反应具有较高的催化活性。     

蒽醌法生产过氧化氢研究进展

过氧化氢是一种重要的无机化工产品，在工业上有着广泛的应用。而蒽醌法以其相对成熟的工艺成为当今世界过氧化氢的主要生产方法。综述了近些年来蒽醌法生产过氧化氢在工作液、氢化催化剂、氧化过程等方面的进展情况，并对其发展方向作一展望。     

Self-assembly and crystallization behavior of a double-crystalline polyethylene-block-poly(ethylene oxide) diblock copolymer

The self-assembly and crystallization behavior of a well-defined low molecular weight polyethylene-block-poly(ethylene oxide) (PE-b-PEO) diblock copolymer was studied. The number-average degrees of polymerization for the PE and PEO blocks were 29 and 20, respectively. The molecular weight distribution was 1.04 as determined by size-exclusion chromatography. The PE-b-PEO sample exhibited two melting points at 28.7 and 97.4 °C for the PEO and the PE crystals, respectively. The crystallization of the PE blocks was unconfined, while the crystallization of the PEO blocks was confined between pre-existing PE crystalline lamellae, as demonstrated by simultaneous small-angle X-ray scattering (SAXS) and wide-angle X-ray diffraction (WAXD) studies. In the fully crystalline state, both PE and PEO blocks formed extended-chain crystals with PE chains tilted ∼22° from the lamellar normal and PEO chains parallel to the lamellar normal, as evidenced by two-dimensional WAXD study of shear-oriented samples. Regardless of hydrogen bonding among hydroxyl chain ends in the PEO blocks, interdigitated, single-crystalline layer morphology was observed for both PE and PEO crystals. The partial crystalline morphology, where the PE crystallizes and the PEO is amorphous, had the same overall d-spacing as the fully crystalline morphology. A double-amorphous PEO layer sandwiched between neighboring PE crystalline layers was deduced based on a chain conformation study using Fourier transform infrared. The confined crystallization kinetics for PEO blocks was investigated by differential scanning calorimetry, which could be explained by a heterogeneous nucleation mechanism. The slower crystallization rate in the PEO-block than the same molecular weight homopolymer was attributed to the effects of nanoconfinement and PEO chains tethered to the PE crystals.     

产地不同的两种香蓼的挥发性成分研究

本文通过分析检索,从香蓼1#样中鉴定出33个挥发性成分,从香蓼2#样中鉴定出36个挥发性成分。1#样中主要有十二烷醛、癸醛、草蒿脑、石竹烯氧化物、十二烷醇、癸醇等。2#样中主要有十二烷醛、癸醛、十三碳烯、十二烷醇等。二者相同的化学成分有17种,主要是癸醛、十二烷醛、十二烷醇等。     

离子色谱法测定配煤、焦炭和焦油中的氯含量

研究了用带电导检测器的离子色谱对配煤、焦炭和焦油中的Cl- 进行测定的方法。在YSA型8126A-4# 阴离子分离柱上用3.5mmol/LNa2CO3、5.3mmol/LNaHCO3做淋洗液对Cl-进行测定,方法简便快速。Cl-的检出限为2×10-6。该法也适用于F-、NO2-、NO3-、SO42-等的测定。