1-乙基-3-甲基咪唑四氟硼酸盐离子液体结构性质的模拟计算

离子液体以其独特的性质广受关注,被称为"绿色设计者溶剂",人们对其潜在的应用价值做了大量的研究.实验采用HyperChem软件构建了1-乙基-3-甲基咪唑四氟硼酸盐([EMIM][BF4])离子液体分子结构的3D模型,并用PM3法进行预优化,然后应用Gaussian 03w程序分别在RHF/6.31G(d)和BLYP/6-31G(d)计算水平上进行量子化学计算,并经振动频率和强度分析得到理论红外谱图.结果表明,[EMIM][BF4]离子液体的阴阳离子存在着氢键等弱相互作用.     

电容器引线焊接机冲压切边凸轮的三维精确造型

根据电容器引线焊接机冲压切边模具中的凸轮设计要求,利用Pro/ENGINEER软件找出凸轮随动件滚子中心的轨迹,通过可变截面扫描间接得到凸轮的三维精确模型。为类似零件的建模提供一种行之有效的方法,并为后续的仿真分析和制造加工提供一种依据。     

Robust sparse principal component analysis

The model for improving the robustness of sparse principal component analysis（PCA） is proposed in this paper. Instead of the l2-norm variance utilized in the conventional sparse PCA model,the proposed model maximizes the l1-norm variance,which is less sensitive to noise and outlier. To ensure sparsity,lp-norm（0 p 1） constraint,which is more general and effective than l1-norm,is considered. A simple yet efficient algorithm is developed against the proposed model. The complexity of the algorithm approximately linearly increases with both of the size and the dimensionality of the given data,which is comparable to or better than the current sparse PCA methods. The proposed algorithm is also proved to converge to a reasonable local optimum of the model. The efficiency and robustness of the algorithm is verified by a series of experiments on both synthetic and digit number image data.     

窄带滤光片光学极值法直接监控的光学设计

窄带滤光片是应用于光谱学、激光、天文物理学、通信等各个领域的光学组件,精确控制每一层膜厚是制备滤光片的困难所在.采用光学极值法直接监控工件,可以同时制备多件滤光片.设计了监控光路和信号获得电路,通过探测到的测试信号,监控薄膜膜厚,实现了直接监控.     

Weathering modification of acrylic emulsion by introducing UV absorbing groups

A new kind of UV-absorbing silicon-fluorinated acrylic emulsion was prepared by emulsion polymerization with 4-allyloxy-2-hydroxybenzophenone, 3-methacryloxypropyltrimethoxysilane (MPS) and hexafluorobutyl methacrylate (HFMA) as functional monomers. The emulsion and its coating were characterized by transmission electron microscope, Fourier transform infrared spectrum (FTIR), X-ray photoelectron spectroscopy, ultraviolet absorption spectrum,thermo-gravimetric analysis, water contact angle (CA), and artificial accelerated aging test. The results indicated that the emulsion with core-shell structure was synthesized and showed prominent absorption peaks at 320 and 350 nm. The water CA of the coating was increased from 70.2° to 86.7° because of the incorporated HFMAs and MPSs. Both of the initial and final decomposition temperatures of the coating were increased by more than 20°C compared with those of the unmodified coating. After 10 days of accelerated aging, the color difference (ΔE) and rate of loss of gloss (ΔG) were only 2.78% and 5.22%, while those of the unmodified coating were as high as 22.94% and 78.57%, respectively. Because of the UV absorbers were incorporated by chemical reaction, the new coating had a more durable and effective anti-ultraviolet performance compared with the coatings the UV absorbers were introduced by physical blending.     

基于嵌入式的电网自动调度信息分级采集系统设计

传统系统在电网调度信息采集的过程中,未对其进行分级,导致系统采集数据误差较大,准确度较低.为了提高电网自动调度信息分级采集能力,提出基于嵌入式的电网自动调度信息分级采集系统.构建电网自动调度信息的大数据挖掘模型,结合嵌入式调度方法,实现电网自动调度信息分级采集和优化检索.仿真结果表明,电网自动调度信息分集采集的准确度较高,自适应性较好,具有一定可行性,数据准确性满足系统设计需要,达到实用效果.     

TiCp/Al预制块在Mg中熔化过程研究

将TiCp／Al预制块以不同的工艺加入到Mg液中进行熔化试验。结果表明，未搅拌时TiCp／Al预制块在800℃的Mg液中保温60min后仍不熔化，采用合适的搅拌工艺可使TiCp／Al预制块熔化，并且使TiC粒子在熔体中均匀分布。TiCp／Al预制块在Mg液中的熔化过程机理为：基体Al通过熔化和对淹扩散进入到Mg液中，TiC粒子间的结合力需通过搅拌产生的剪切力才能破坏，并随Mg液流动进入到Mg液中，机械搅拌可使TiC粒子Mg液中均匀分布。     

蠕墨铸铁的优势和技术关键

介绍了蠕墨铸铁的优势和生产中的几个技术关键问题。     

一种面向空地一体化组网的体系架构

空间网络是空地一体化组网中地面网络延伸的重要组成部分。针对空间网络为移动星座的场景,传统的空地一体化组网模型将空间网络视为独立自治域,利用边界网关协议将空间网络与地面自治域互联起来,最大化同地面网络保持兼容。然而,传统组网模型存在边界网关面临频繁会话中断或大量路由更新等问题。通过重新审视空间网络的角色定位和边界划定问题,提出一种面向空地一体化组网的体系架构Slink。Slink的核心思想是空间网络为地面网络提供互联通道,利用星地网关隔离空地两网间的路由更新。实验仿真表明,Slink体系架构能够有效减小对空间路由器的路由存储空间需求,降低星地网络间的带宽消耗。