测控天线射电星角度标校方法分析

通过对常见射电源辐射特性进行梳理,分析了星体角径、空域分布及天线口径对角度标校的影响,提出了确定目标星体中心点的天线扫描方法以及天线和差电轴不一致性补偿方法,利用最小二乘法完成角度轴系误差修正系数的解算,并采用不同频段、不同口径天线进行射电星无塔角度标校的测试验证,检验了该方法的适用性和有效性.     

一种用于FTTH的实用塑料光纤连接器的研究

塑料光纤以其芯径大、柔韧性好、连接方便和耦合效率高等优点,为光纤到户(FTTH)接入问题提供了很好的解决方案.文章通过MATLAB对塑料光纤连接器中的光纤耦合效率问题进行了模拟仿真.提出了一种用于FTTH的实用塑料光纤连接器结构,该连接器具有连接损耗低、操作简单、安装方便和性价比高等特点.     

基于AlxNy绝缘介质膜的新型窗口大功率半导体激光器

提升半导体激光器的腔面抗光学灾变(COD)损伤的能力,改善半导体激光器的工作特性,一直是大功率半导体激光器器件工艺研究的难点.基于薄膜应力使基底半导体材料带隙变化的原理,采用直流磁控溅射方法在不同条件下溅射生成不同内应力的AlxNy绝缘介质膜.通过研究大功率半导体激光器腔面退化机理,借助AlxNy等应力膜设计制作了一种新型非吸收透明窗口结构的宽条形半导体激光器,使器件平均最大输出功率提高46.5%,垂直发散角达到21°,水平发散角达到6.1°,2000 h加速老化试验,其千小时退化速率小于0.091%.     

Advent of 2D Rhenium Disulfide (ReS2): Fundamentals to Applications

Rhenium disulfide (ReS₂) is a two‐dimensional (2D) group VII transition metal dichalcogenide (TMD). It is attributed with structural and vibrational anisotropy, layer‐independent electrical and optical properties, and metal‐free magnetism properties. These properties are unusual compared with more widely used group VI‐TMDs, e.g., MoS₂, MoSe₂, WS₂ and WSe₂. Consequently, it has attracted significant interest in recent years and is now being used for a variety of applications including solid state electronics, catalysis, and, energy harvesting and energy storage. It is anticipated that ReS₂ has the potential to be equally used in parallel with isotropic TMDs from group VI for all known applications and beyond. Therefore, a review on ReS₂ is very timely. In this first review on ReS₂, we critically analyze the available synthesis procedures and their pros/cons, atomic structure and lattice symmetry, crystal structure, and growth mechanisms with an insight into the orientation and architecture of domain and grain boundaries, decoupling of structural and vibrational properties, anisotropic electrical, optical, and magnetic properties impacted by crystal imperfections, doping and adatoms adsorptions, and contemporary applications in different areas.     

A 3D Hybrid of Chemically Coupled Nickel Sulfide and Hollow Carbon Spheres for High Performance Lithium–Sulfur Batteries

Lithium–sulfur batteries are a promising next‐generation energy storage device owing to their high theoretical capacity and the low cost and abundance of sulfur. However, the low conductivity and loss of active sulfur material during operation greatly limit the rating capabilities and cycling stability of lithium–sulfur batteries. In this work, a unique sulfur host hybrid material comprising nanosized nickel sulfide (NiS) uniformly distributed on 3D carbon hollow spheres (C‐HS) is fabricated using an in situ thermal reduction and sulfidation method. In the hybrid material, the nanosized NiS provides a high adsorption capability for polysulfides and the C‐HS serves as a physical confinement for polysulfides and also a 3D electron transfer pathway. Moreover, NiS has strong chemical coupling with the C‐HS, favoring fast charge transfer and redox kinetics of the sulfur electrode. With a sulfur loading of up to 2.3 mg cm^?2, the hybrid material‐based lithium–sulfur batteries offer a capacity decay as low as 0.013% per cycle and a capacity of 695 mA h g^?1 at 0.5 C after 300 cycles. This unique 3D hybrid material with strong chemical coupling provides a promising sulfur host for high performance lithium–sulfur batteries.     

48 fs,108 MHz色散管理孤子掺Er3+光纤激光器

提出了一种基于商售光纤构建的适用于精密光谱光频梳应用的100 MHz重复频率色散管理孤子光纤激光器的设计方案.通过采用低负色散光纤调控重复频率、高正色散光纤增大腔内脉冲呼吸比,构建了重复频率为108 MHz、中心波长为1550 nm的基于正色散掺铒光纤的色散管理孤子光纤激光器,该激光器腔内净色散为-0.0023 ps2,直接输出脉冲宽度为70 fs,经光纤压缩后脉冲宽度为48 fs,且脉冲中心波长处在1550 nm.     

RTD在压力下的弛豫振荡特性

报道了共振隧穿二极管(RTD)在压力下的弛豫振荡特性.采用Pspice 8.0软件仿真并设计了振荡电路,测得其振荡频率达200kHz.在(100)半绝缘(SI)GaAs衬底上利用分子束外延(MBE)技术生长了AlAs/InxGa1-xAs/GaAs双势垒共振隧穿结构(DBRTS),并采用Au/Ge/Ni/Au金属化和空气桥结构成功加工出了RTD.由于RTD的压阻效应,采用显微喇曼光谱仪标定所加应力大小,对RTD在加压条件下的振荡特性进行了研究,结果表明其弛豫振荡频率大致有-17.9kHz/MPa的改变量.     

局域寿命控制NPT-IGBTs稳态模型

提出了局域寿命控制下的NPT-IGBT稳态模型.通过与二维器件数值仿真比较,表明模型结果和仿真结果能较好地吻合.基于该模型,详细地分析了局域寿命区的参数对器件正向特性的影响.通过对基区空穴浓度的分析,澄清了长期以来对于最优局域低寿命区位置的不同看法,将各种结论统一起来.     

A NIR-II AIEgen-Based Supramolecular Nanodot for Peroxynitrite-Potentiated Mild-Temperature Photothermal Therapy of Hepatocellular Carcinoma

Compared to conventional photothermal therapy (PTT) which requires hyperthermia higher than 50 °C, mild-temperature PTT is a more promising antitumor strategy with much lower phototoxicity to neighboring normal tissues. However, the therapeutic efficacy of mild-temperature PTT is always restricted by the thermoresistance of cancer cells. To address this issue, a supramolecular drug nanocarrier is fabricated to co-deliver nitric oxide (NO) and photothermal agent DCTBT with NIR-II aggregation-induced emission (AIE) characteristic for mild-temperature PTT. NO can be effectively released from the nanocarriers in intracellular reductive environment and DCTBT is capable of simultaneously producing reactive oxygen species (ROS) and hyperthermia upon 808 nm laser irradiation. The generated ROS can further react with NO to produce peroxynitrite (ONOOˉ) bearing strong oxidization and nitration capability. ONOOˉ can inhibit the expression of heat shock proteins (HSP) to reduce the thermoresistance of cancer cells, which is necessary to achieve excellent therapeutic efficacy of DCTBT-based PTT at mild temperature (<50 °C). The antitumor performance of ONOOˉ-potentiated mild-temperature PTT is validated on subcutaneous and orthotopic hepatocellular carcinoma (HCC) models. This research puts forward an innovative strategy to overcome thermoresistance for mild-temperature PTT, which provides new inspirations to explore ONOOˉ-sensitized tumor therapy strategies.     

Ni3N–CeO2 Heterostructure Bifunctional Catalysts for Electrochemical Water Splitting

Developing low-cost and high-efficient bifunctional catalysts for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is greatly significant for water electrolysis. Here, Ni₃N-CeO₂/NF heterostructure is synthesized on the nickel foam, and it exhibits excellent HER and OER performance. As a result, the water electrolyzer based on Ni₃N-CeO₂/NF bifunctional catalyst only needs 1.515 V@10 mA cm⁻², significantly better than that of Pt/C||IrO₂ catalysts. In situ characterizations unveil that CeO₂ plays completely different roles in HER and OER processes. In situ infrared spectroscopy and density functional theory calculations indicate that the introduction of CeO₂ can optimizes the structure of interface water, and the synergistic effect of Ni₃N and CeO₂ improve the HER activity significantly, while the in situ Raman spectra reveal that CeO₂ accelerates the reconstruction of O_V (oxygen vacancy)-rich NiOOH for boosting OER. This study clearly unlocks the different catalytic mechanisms of CeO₂ for boosting the HER and OER activity of Ni₃N for water splitting, which provides the useful guidance for designing the high-performance bifunctional catalysts for water splitting.