甲苯稀释对AlCl3-EMIC型离子液体电镀铝工艺氢脆性的影响

采用甲苯作为AlCl3-EMIC(1-乙基-3-甲基咪唑)型离子液体的稀释剂,其中纯态离子液体由物质的量比为2∶1的无水AlCl3和EMIC组成。对比了纯态和按稀释剂与离子液体体积比为1∶1稀释后电镀铝的外观、微观形貌和氢脆性。结果表明,采用甲苯稀释离子液体虽然可以降低镀液的黏度,改善镀层外观和微观形貌,但对离子液体电镀铝工艺的氢脆性有负面影响。     

Enhanced Thermal Stability of Zinc-Based Titanate (Dielectric) Ceramics Prepared by the Modified Sol–gel Route

A multi-component substitution of Co and Ni was incorporated into ZnTiO₃ to form pure hexagonal Zn_{1− x} (Co_1/2Ni_1/2) _x TiO₃ ( x =0,0.8,0.9,1.0) dielectric ceramic powders by a modified sol–gel route, following heat treatments at 600°C for 3 h and at 800°C for 6 h. Differential scanning calorimetry measurements revealed that the order of increasing thermal stability of solid solution compound Zn_{1− x} (Co_1/2Ni_1/2) _x TiO₃ was ZnTiO₃ (945°C), Zn_0.1Ni_0.9TiO₃ (1346°C), Zn_0.1(Co_1/2Ni_1/2)_0.9TiO₃ (1390°C), and Zn_0.1Co_0.9TiO₃ (>1400°C). Both the dielectric constant and loss tangent reached a maximum at x =0.8 and then decreased with solubility, x , and measurement frequency.     

A general non-local denoising model using multi-kernel-induced measures

Noises are inevitably introduced in digital image acquisition processes, and thus image denoising is still a hot research problem. Different from local methods operating on local regions of images, the non-local methods utilize non-local information (even the whole image) to accomplish image denoising. Due to their superior performance, the non-local methods have recently drawn more and more attention in the image denoising community. However, these methods generally do not work well in handling complicated noises with different levels and types. Inspired by the fact in machine learning field that multi-kernel methods are more robust and effective in tackling complex problems than single-kernel ones, we establish a general non-local denoising model based on multi-kernel-induced measures (GNLMKIM for short), which provides us a platform to analyze some existing and design new filters. With the help of GNLMKIM, we reinterpret two well-known non-local filters in the united view and extend them to their novel multi-kernel counterparts. The comprehensive experiments indicate that these novel filters achieve encouraging denoising results in both visual effect and PSNR index.     

Ink‐eliminated waste paper sludge flour‐filled polypropylene composites with different coupling agent treatments

Ink‐eliminated sludge flour (IESF), waste residue from the recycling treatments of waste paper, was utilized as a new kind of filler to reinforce polypropylene (PP) in this research work. Different coupling agents, including maleated anhydride grafted PP (MAPP), stearic acid (SA), and titanate (NDZ‐101), were used to increase the compatibility between IESF and PP. By using different measurements, the microstructure, morphology, thermal behaviors, and mechanical properties of the IESF/PP composites were investigated in detail. It was found that IESF, as a nucleation agent, not only induced the crystallization orientation of PP but also accelerate the crystallization rate of PP. Just as indicated in the experiments, the presence of IESF has shown the advantages of increasing the dimensional stability, the hardness and the flexural property, and the presence of coupling agents has a favorable effect on the improvement of dimensional stability. Moreover, the coupling agent has minor influence on the mechanical property, even causes some decrease in the impact strength. Among these three coupling agents, MAPP is found to be the best coupling agent for increasing the interfacial adhesion between IESF and PP, and the MAPP addition makes the PP composite possess the quickest crystallization rate and greatest tensile strength. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 513–520, 2003     

微波辐射磷钨酸催化合成环己酮1,2-丙二醇缩酮

在微波辐射下,以磷钨酸为催化剂,对以环己酮和1,2-丙二醇为原料合成环己酮1,2-丙二醇缩酮进行了研究.较系统的研究了反应物投料比、微波辐射功率、微波辐射时间、催化剂用量、带水剂用量诸因素对产品收率的影响.最佳反应条件为:环己酮为0.2mol,n(环己酮):n(1,2-丙二醇)=1.0:1.5,微波辐射功率600W,辐射时间16min,催化剂用量为反应物总质量的0.5%,带水剂(环己烷)15mL.在此条件下,环己酮1,2-丙二醇缩酮的产率可达82.0%.     

化学镀法制备SiC/Cu金属陶瓷复合粉体工艺的研究

为改善SiC与其他金属的结合性能，采用化学镀法在SiC粉体上镀Cu，制备包覆型陶瓷颗粒。通过精选、粗化、敏化、活化表面镀前处理，用硫酸铜镀液成功地得到在SiC上均匀镀Cu的包覆粉体，利用Olympus显微镜观察到包覆程度可达95％，通过详细讨论镀液的配方、pH值、镀液与SiC粉体的配比与对包覆效果的影响，最终得到硫酸铜用量控制在10—15g／l能得到我们所控制的沉积反应速度；包覆反应过程中pH值控制在11—13之间较为合适。     

弹性纳米粒子/纳米TiO2/聚丙烯复合材料的研究

采用专利技术制备了弹性纳米粒子(ENP)／纳米二氧化钛(TiO2)复合材料，并使用这种复合材料改性聚丙烯(PP)，制备了具有较高韧性和较好灭菌性能的PP纳米复合材料。当丁苯ENP的用量为2％，平均粒径为50nm的金红石型TiO2用量为1％时，所研制的PP纳米复合材料的冲击强度可提高30％以上，灭菌率可达60％。     

基于Push-Model的遥感生态产品生产监控的设计与实现

针对生态环境遥感产品生产系统的架构,结合遥感生态产品的特点,提出了以多线程方式为运行机制的Push-Model的产品生产监控系统,用以实时、有效地对产品生产过程进行进度监控和人工交互消息的控制。生产监控系统的实现与运行,证实了该方案下产品生产监控信息的实时性及人工交互消息控制的有效性。     

银掺杂对二氧化钛晶型转变的影响

采用溶胶-凝胶法制备了银掺杂的TiO2粉末,用XRD分析了掺银TiO2胶体经不同温度热处理后的晶型转变。结果表明:与未掺银的TiO2粉末相比,掺银TiO2从锐钛矿相向金红石相转变的起始温度较高,而且锐钛矿-金红石相变的温区范围变窄,晶型转变过程较快。     

In situ composite of nano SiO2-P(VDF-HFP) porous polymer electrolytes for Li-ion batteries

Nano SiO₂-P(VDF-HFP) composite porous membranes were prepared as the matrix of porous polymer electrolytes through in situ composite method based on hydrolysis of tetraethoxysilane and phase inversion. SEM, TEM, DSC and AC impedance analysis were carried out. It is found that the in situ prepared nano silica was homogeneously dispersed in the polymeric matrix, enhanced conductivity and electrochemical stability of porous polymer electrolytes, and improved the stability of the electrolytes against lithium metal electrodes. The in situ composite method was found to be much better than the direct composite method in lowering the interfacial resistance between electrolyte and lithium metal electrode. Moreover, cycle test of lithium batteries using lithium metal as anode and sulfur composite material as cathode showed that the electrolyte based on in situ composite of silica presented stable charge-discharge behavior and little capacity loss of battery.