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Achieving High‐Performance Nondoped OLEDs with Extremely Small Efficiency Roll‐Off by Combining Aggregation‐Induced Emission and Thermally Activated Delayed Fluorescence 下载免费PDF全文
Jingjing Guo Xiang‐Long Li Han Nie Wenwen Luo Shifeng Gan Shimin Hu Rongrong Hu Anjun Qin Zujin Zhao Shi‐Jian Su Ben Zhong Tang 《Advanced functional materials》2017,27(13)
Luminescent materials with thermally activated delayed fluorescence (TADF) can harvest singlet and triplet excitons to afford high electroluminescence (EL) efficiencies for organic light‐emitting diodes (OLEDs). However, TADF emitters generally have to be dispersed into host matrices to suppress emission quenching and/or exciton annihilation, and most doped OLEDs of TADF emitters encounter a thorny problem of swift efficiency roll‐off as luminance increases. To address this issue, in this study, a new tailor‐made luminogen (dibenzothiophene‐benzoyl‐9,9‐dimethyl‐9,10‐dihydroacridine, DBT‐BZ‐DMAC) with an unsymmetrical structure is synthesized and investigated by crystallography, theoretical calculation, spectroscopies, etc. It shows aggregation‐induced emission, prominent TADF, and interesting mechanoluminescence property. Doped OLEDs of DBT‐BZ‐DMAC show high peak current and external quantum efficiencies of up to 51.7 cd A?1 and 17.9%, respectively, but the efficiency roll‐off is large at high luminance. High‐performance nondoped OLED is also achieved with neat film of DBT‐BZ‐DMAC, providing excellent maxima EL efficiencies of 43.3 cd A?1 and 14.2%, negligible current efficiency roll‐off of 0.46%, and external quantum efficiency roll‐off approaching null from peak values to those at 1000 cd m?2. To the best of the authors' knowledge, this is one of the most efficient nondoped TADF OLEDs with small efficiency roll‐off reported so far. 相似文献
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Using Bulk Heterojunctions and Selective Electron Trapping to Enhance the Responsivity of Perovskite–Graphene Photodetectors 下载免费PDF全文
Liang Qin Liping Wu Bhupal Kattel Chunhai Li Yong Zhang Yanbing Hou Judy Wu Wai‐Lun Chan 《Advanced functional materials》2017,27(47)
Graphene field effect transistor sensitized by a layer of semiconductor (sensitizer/GFET) is a device structure that is investigated extensively for ultrasensitive photodetection. Among others, organometallic perovskite semiconductor sensitizer has the advantages of long carrier lifetime and solution processable. A further step to improve the responsivity is to design a structure that can promote electron–hole separation and selective carrier trapping in the sensitizer. Here, the use of a hybrid perovskite–organic bulk heterojunction (BHJ) as the light sensitizer to achieve this goal is demonstrated. Our spectroscopy and device measurements show that the CH3NH3PbI3–PCBM BHJ/GFET device has improved charge separation yield and carrier lifetime as compared to a reference device with a CH3NH3PbI3 sensitizer only. The key to these enhancement is the presence of [6,6]‐phenyl‐C61‐butyric acid methyl ester (PCBM), which acts as charge separation and electron trapping sites, resulting in a 30‐fold increase in the photoresponsivity. This work shows that the use of a small amount of electron or hole acceptors in the sensitizer layer can be an effective strategy for improving and tuning the photoresponsivity of sensitizer/GFET photodetectors. 相似文献
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Facile Two‐Step Synthesis of All‐Inorganic Perovskite CsPbX3 (X = Cl,Br, and I) Zeolite‐Y Composite Phosphors for Potential Backlight Display Application 下载免费PDF全文
Jia‐Yi Sun Freddy T. Rabouw Xian‐Feng Yang Xie‐Yi Huang Xi‐Ping Jing Shi Ye Qin‐Yuan Zhang 《Advanced functional materials》2017,27(45)
Recently developed CsPbX3 (X = Cl, Br, and I) perovskite quantum dots (QDs) hold great potential for various applications owing to their superior optical properties, such as tunable emissions, high quantum efficiency, and narrow linewidths. However, poor stability under ambient conditions and spontaneous ion exchange among QDs hinder their application, for example, as phosphors in white‐light‐emitting diodes (WLEDs). Here, a facile two‐step synthesis procedure is reported for luminescent and color‐tunable CsPbX3–zeolite‐Y composite phosphors, where perovskite QDs are encapsulated in the porous zeolite matrix. First zeolite‐Y is infused with Cs+ ions by ion exchange from an aqueous solution and then forms CsPbX3 QDs by diffusion and reaction with an organic solution of PbX2. The zeolite encapsulation reduces degradation and improves the stability of the QDs under strong illumination. A WLED is fabricated using the resulting microscale composites, with Commission Internationale de I'Eclairage (CIE) color coordinates (0.38, 0.37) and achieving 114% of National Television Standards Committee (NTSC) and 85% of the ITU‐R Recommendation BT.2020 (Rec.2020) coverage. 相似文献
186.
A new satellite communication bandwidth allocation combined services model and network performance optimization 下载免费PDF全文
Wenliang Lin Zhongliang Deng Qin Fang Ning Li Ke Han 《International Journal of Satellite Communications and Networking》2017,35(3):263-277
With the rapid development of online to offline economy, new services compositions would take up a great part in the satellite communication. More and more new services compositions request more bandwidth and network resources, which lead to serious traffic congestion and low channel utilization. Suffering from isolated link connection and changeable delay under the satellite environment, current bandwidth allocation schemes could not satisfy with the demand of low delay and high assess rate for new satellite services. This paper focuses on bandwidth allocation method for satellite communication services compositions. The novel models of services compositions with single‐hop Poisson distribution are designed to simulate original traffic arrival. Isolated independent coefficients take an original distribution to adapt to isolated disconnections. Services queue waiting time would be judged by acceptable delay threshold. Models provide new services compositions with more precise arrival distributions. In order to improve traffic congestion, the method combined services models, and a network performance is proposed. Optimal reserved bandwidth is set according to the priority and arrival distribution of different services compositions, which classify services with feedback transmission performance. We design minimum fuzzy delay tolerant intervals to calculate delay tolerant threshold, which adapt random delay changes in the services network with delay tolerant features. The simulation in OPNET demonstrates that the proposed method has a better performance of queuing delay by 16.3%, end‐to‐end delay by 18.7%, and bandwidth utilization by 13.2%. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
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采用电子回旋共振-等离子体增强金属有机物化学气相沉积(ECR-PEMOCVD)技术,在康宁7101型普通玻璃衬底上沉积了高度C轴择优取向的多晶GaN薄膜.利用反射高能电子衍射(RHEED),X射线衍射(XRD)对样晶进行检测,研究了在低温(430℃)沉积中氮气流量对GaN薄膜结品性的影响.并且利用原子力显微镜(AFM)和室温光敏发光(PL)谱研究了薄膜的表面形貌和发光特性,发现薄膜表面形貌较为平整,其发光峰由较强的紫外近带边发光峰和极其微弱的绿光发光峰组成. 相似文献
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论文对传统的扩频地址码捕获算法进行了分析,指出了其在有多普勒频移情况下的缺陷,进而提出差分相干捕获算法,给出原理框图,并仿真分析了改进算法的性能。结果表明,改进算法对由于多普勒频移造成的匹配滤波器输出信号能量下降具有很好的抑制作用。 相似文献