On the Direct Addition of Amine N–H to Ch≡C Triple Bonds with Late Transition Metal Catalysts

The kinetics of the transition metal-catalysed direct addition of amine NH bonds to carbon--carbon multiple bonds (hydroamination) has been explored by in situ spectroscopic techniques. From an open mass balance it was concluded that an intermediate species was formed during the cyclisation of 6-aminohex-1-yne. This species was identified as the enamine 2-methylene-piperidine, which is the primary hydroamination product.     

AN EXTENDED MODELING OF TIDE-WAVE MOTION

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Instability due to Viscosity Stratification Downstream of a Centerline Injector

A common injector geometry upstream of a static mixer is the centerline injector. A flow instability can arise due to viscosity differences between the injected core‐flow and the outer co‐flow. This instability can adversely affect the effectiveness of the mixing operation. An experimental investigation of miscible viscosity‐stratified flow in a circular geometry was performed using Laser Induced Fluorescence (LIF) and Particle Image Velocimetry (PIV). The experimental results for the stable region agree with the analytical results. The unstable region exhibits different modes depending on the viscosity ratio, volume flux ratio, and Reynolds number. The modes include wavy core‐flow with fissures and wavy core‐flow with core breakup. The time‐averaged experiment velocity profiles for the unstable core indicate a broadening of the jet at the centerline, which is consistent with the LIF visualization.     

铜基催化剂孔隙率对气体有效扩散系数的影响

研究了18种具有不同孔结构参数的粒状铜基甲醇合成催化剂孔隙率对有效扩散系数的影响。结果发现，催化剂微孔孔隙率增大，曲节因子亦增大，扩散阻力增加。将孔隙率与催化剂曲节因子关联，得到了半经验方程，用它可估算催化剂的曲节因子。     

热声热机系统振荡频率的理论计算与实验验证

以热声发动机为例采用网络模型计算了热声热机系统的振荡频率，得出振荡频率为复频率，其实部代表实际频率，虚部表示压力幅值的衰减程度。对热机系统在各种不同的情况下(包括不同大小的谐振腔、板叠间距、气体静压、系统长度)进行了数值计算，理论计算值与实验结果能很好的吻合。     

A hexane solution deposition of SnS2 films from tetrabutyltin via a solvothermal route at moderate temperature

SnS₂ films have been deposited on glass and alumina plate substrates by the reactions between an organotin precursor [tetrabuyltin, (CH₂CH₂CH₂CH₃)₄Sn] and carbon disulfide in n-hexane at the temperature range 180-200 °C for 10-40 h. The reaction system was oxygen free and applied at a moderate temperature. The films so prepared were characterized by techniques of X-ray diffraction, Scanning electron microscopy, Raman and Mössbauer spectroscopies. The films deposited on glass as well as on alumina plate have an average thickness of 30 μm, but have different rose-like morphologies, which are influenced by both the anisotropic growths of crystals and the different substrate structures. Photoluminescence measurements show that the films have an emission peak at approximately 590 nm.     

单螺杆挤出机—熔体泵串联挤出系统的性能与应用

从原理与应用方面，分析、探讨了单螺杆挤出机-熔体泵串联挤出系统的优异性能以及在塑料挤出成型领域的高效应用。     

液动旋冲接头冲击功测试方法研究

液动旋冲接头性能参数是旋冲接头设计的主要依据之一，如何对液动旋冲接头的参数进行检测是非常重要的工作。在分析和比较了测试液动旋冲接头性能参数各种方法的基础上，选择了冲击力法来进行破岩液动旋冲接头的性能参数测试，以YD系列测力传感器为检测元件，建立了一套比较完善的自动检测系统。分析了影响单次冲击功测试的因素，得出了测试旋冲接头的性能参数的影响规律。     

TEM method for rapid and precise evaluation of continuous recrystallization

With the aid of a double-tilt holder in a transmission electron microscope, a new method for a rapid and precise determination of the misorientations of a large number of subgrain or grain boundaries is given in this article. By use of the method, the continuous recrystallization can be rapidly and precisely evaluated when compared to the other conventional methods.     

Network model approach for calculating oscillating frequency of thermoacoustic prime mover

The network model is given and used to calculate the oscillating frequency of thermoacoustic prime mover. Theoretically calculated frequency by the model is plural, whose real part denotes actual frequency of the system, and imaginary part means attenuation coefficient of acoustic pressure. Numerical calculation is made under different conditions including different acoustic cavities, spacing between each parallel plate, gas pressures and system lengths. Theoretically calculated frequency and experimentally measured frequency are in quite good agreement.