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991.
992.
F. He L. L. Tian X. Y. Tian H. Xu Y. H. Wang W. J. Xie M. Hanif J. L. Xia F. Z. Shen B. Yang F. Li Y. G. Ma Y. Q. Yang J. C. Shen 《Advanced functional materials》2007,17(9):1551-1557
1,4‐di(4′‐N,N‐diphenylaminostyryl)benzene (DPA‐DSB) is a well known compound with a large two‐photon absorption (TPA) section and strong fluorescence in solution. However, the ease with which it crystallizes results in the formation of discontinuous crystalline phases during vacuum deposition processes, thereby greatly limiting its applicability in solid‐state devices. A cruciform dimer of DPA‐DSB, 2,5,2′,5′‐tetra(4′‐N,N‐diphenylaminostyryl)biphenyl (DPA‐TSB) is reported, wherein two DPA‐DSB molecules are linked through a central biphenyl bond. The DPA‐TSB molecules take on a cruciform configuration because of the steric crowding around the central biphenyl core, which has the effect of efficiently suppressing crystalline and intermolecular interactions. The neat DPA‐TSB solid shows strong green–blue fluorescence because of both steady‐state absorption as well as TPA. The DPA‐TSB solid exhibits a photoluminescence (PL) efficiency (ηsolid) of 29 % and a solid‐state two‐photon action cross section (δηsolid) of 954 GM (1 GM = 1 × 10–50 cm4 s photon–1 molecule–1), which is much greater than for the model compound DPA‐DSB (ηsolid = 16 % and δηsolid = 150 GM, where δ is the TPA cross section and η is the fluorescence quantum yield). Based on its high PL efficiency, good film‐forming ability, and strong TPA, DPA‐TSB seems to be a good candidate for applications in solid‐state optical devices. 相似文献
993.
He Wen Huan Jiang Xiaoping Zheng Hanyi Zhang Yili Guo 《Photonics Technology Letters, IEEE》2007,19(18):1377-1379
In this letter, we propose two methods to enhance the performance of multichannel wavelength conversion of return-to-zero differential phase-shift-keying signal in a semiconductor optical amplifier (SOA) based on four-wave-mixing effect. The first one is optimizing the relative time delay of the multichannel signal to reduce the crosstalk-induced penalty in SOA. The second one is using the synchronous clock pumping to raise the power of converted signal. The experiment on wavelength conversion of two channels at 10-Gb/s signal showed the power penalty was improved more than 1 dB in the first method and about 1.5 dB in the second method. 相似文献
994.
Jiankang He Yanan Du José L. Villa‐Uribe Changmo Hwang Dichen Li Ali Khademhosseini 《Advanced functional materials》2010,20(1):131-137
Many biological processes are regulated by gradients of bioactive chemicals. Thus, the generation of materials with embedded chemical gradients may be beneficial for understanding biological phenomena and generating tissue‐mimetic constructs. Here a simple and versatile method to rapidly generate materials containing centimeter‐long gradients of chemical properties in a microfluidic channel is described. The formation of a chemical gradient is initiated by a passive‐pump‐induced forward flow and further developed during an evaporation‐induced backward flow. The gradient is spatially controlled by the backward flow time and the hydrogel material containing the gradient is synthesized via photopolymerization. Gradients of a cell‐adhesion ligand, Arg‐Gly‐Asp‐Ser (RGDS), are incorporated in poly(ethylene glycol)‐diacrylate (PEG‐DA) hydrogels to test the response of endothelial cells. The cells attach and spread along the hydrogel material in a manner consistent with the RGDS‐gradient profile. A hydrogel containing a PEG‐DA concentration gradient and constant RGDS concentration is also shown. The morphology of cells cultured on such hydrogel changes from round in the lower PEG‐DA concentration regions to well‐spread in the higher PEG‐DA concentration regions. This approach is expected to be a valuable tool to investigate the cell–material interactions in a simple and high‐throughput manner and to design graded biomimetic materials for tissue engineering applications. 相似文献
995.
Hong Yang Yeming Zhuang He Hu Xiaoxia Du Cuixia Zhang Xiangyang Shi Huixia Wu Shiping Yang 《Advanced functional materials》2010,20(11):1733-1741
Monodisperse silica‐coated manganese oxide nanoparticles (NPs) with a diameter of ~35 nm are synthesized and are aminated through silanization. The amine‐functionalized core–shell NPs enable the covalent conjugation of a fluorescent dye, Rhodamine B isothiocyanate (RBITC), and folate (FA) onto their surface. The formed Mn3O4@SiO2(RBITC)–FA core–shell nanocomposites are water‐dispersible, stable, and biocompatible when the Mn concentration is below 50 µg mL?1 as confirmed by a cytotoxicity assay. Relaxivity measurements show that the core–shell NPs have a T1 relaxivity (r1) of 0.50 mM ?1 s?1 on the 0.5 T scanner and 0.47 mM ?1 s?1 on the 3.0 T scanner, suggesting the possibility of using the particles as a T1 contrast agent. Combined flow cytometry, confocal microscopy, and magnetic resonance imaging studies show that the Mn3O4@SiO2(RBITC)–FA nanocomposites can specifically target cancer cells overexpressing FA receptors (FARs). Findings from this study suggest that the silica‐coated Mn3O4 core–shell NPs could be used as a platform for bimodal imaging (both magnetic resonance and fluorescence) in various biological systems. 相似文献
996.
认知无线电是一种新的智能无线通信技术,通过感知周围环境特征,并采用构建理解的方法进行学习。频谱感知技术是认知无线电系统设计的重要组成部分,本文提出了基于人工神经网络(ANN)算法的认知无线电感知技术。由于单用户检测存在检测精度不高的问题,本文通过采用ANN的自主学习能力设计频谱检测分类器,对以往分类器所收集的环境信息进行学习和储存,从而对以后感知新的环境时起到先验信息的作用,能快速准确地判决出主用户的存在与否。通过与能量检测和循环平稳检测对不同调制方式信号进行信号识别仿真实验可以看出,相比原有的单用户频谱检测技术,ANN具有更高的有效性和可靠性。 相似文献
997.
我国生产的集装箱占世界生产量的95%以上,传统的手工集装箱堆场管理已经不适合现状的要求。本文介绍的自主开发的基于RFID电子标签和无线数据传输网络的可视化集装箱堆场实时信息管理系统可以有效地解决自动ID收集、跟踪与监控的实际问题,有助于供应链中的集装箱管理。 相似文献
998.
999.
Xun-jun He Yue Wang Qun Wu Tai-long Gui 《Analog Integrated Circuits and Signal Processing》2012,72(1):19-26
The microelectromechanical system (MEMS) capacitive switch based on clamped?Cclamped microbeam has garnered significant attention due to their geometric simplicity and broad applicability, and the accurate model which describes the multiphysical effects of MEMS capacitive switch should be developed to predict the nonlinear dynamic response of clamped?Cclamped microbeam. A improved macromodel of the clamped?Cclamped microbeam-based MEMS capacitive switch is presented to investigate the nonlinear dynamic response of clamped?Cclamped microbeam of MEMS capacitive switch under different mechanical shock in this article, the macromodel provides an effective and accurate design tool for this class of MEMS devices because of taking account into some effects simultaneously including midplane stretching effect, residual stress and different mechanical shock loads. A numerical analytical method based on multimode Galerkin discretization is presented to investigate the nonlinear response of clamped?Cclamped microbeam of MEMS capacitive switch under the different mechanical shock loads. The results show that using five or more modes can be sufficient to capture the nonlinear dynamic response of clamped?Cclamped microbeam, and the microbeam experiences a mechanical shock load as a quasi-static load or a dynamic load depending on the ration between the natural periods of the structure and the period or frequency of mechanical shock load. The proposed method gives the identical results to other numerical methods in the literature. Moreover, this method is straightforward to implement and could save computation efforts while not losing accuracy. 相似文献
1000.