Studies on oxidation of benzo [a] pyrene by sunlight and ozone

The destruction of the carcinogen benzo[a]pyrene (BaP) by light is well known; laboratory workers are routinely advised to cover fluorescent lamps with yellow filters while treating samples containing BaP. However until recently the mechanism of oxidation by sunlight and ozone had not been studied in detail. Concentrations of benzo[a]pyrene in urban air are in the range of 5–10 μg/1000 m³. Oxidant concentrations (predominantly in the form of ozone) are reported to be in the range of 0.01 ppm (22 μg per m³). Thus a sampling system with a filter paper would filter about 22,000 μg of ozone passing through and collect about 5 μg of BaP for analysis. The effect of interactions of such large ozone concentrations with BaP deposited on the filter paper is reported; data for the oxidation rates for benzo[a]pyrene coated on quartz surface and exposed to ozone or sunlight are presented. The oxidation products were analysed by thin-layer chromatography and highpressure liquid chromatography. From about eight products detected in these experiments, three have been identified as quinones based on UV-absorption spectrometry and mass spectrometry. Oxidation rates as high as 100% per hour of exposure are observed when less than 0.1 μg of BaP is coated inside the quartz tubes and exposed to ozone or sunlight. Oxidation rates for benzo[a]pyrene (using tritiated BaP) were determined for two types of experimental conditions. In the first set, tritiated BaP was spotted onto a glass fibre paper and sampling continued for 24 h; the loss of BaP was found to be 88%. In the second set tritiated BaP was spotted at intervals of one hour, for eight hours, while sampling is being carried out and the loss of BaP during the period was estimated to be 50%.     

Enhancement of bond strength for epoxy-coated rebar using river sand

In this paper, improvement of bond strength for epoxy-coated rebars is studied. Although the epoxy-coated rebar is well accepted as an alternative corrosion prevention method in engineering practice, it still suffers from its poor bond performance, which requires modification of design parameters such as development length and splice length. Following our previous study [Proceedings of the Third Structure Engineering Conference (1996) 651–659], it is proposed to mix the river sand in the epoxy to improve the bond strength of epoxy-coated rebar. Specimens of several sizes of river sand and sand/epoxy weight ratios were studied. The single-rebar pullout test was performed to examine the bond strength. The open circuit potential method and the linear DC polarization method were conducted for corrosion rate measurements to ensure for keeping the merit of epoxy-coated rebar, i.e. the ability of corrosion. Experimental results show that the proposed method is very promising.     

Heavy metals in maternal and cord blood

Heavy metal concentrations have been determined in maternal and cord blood samples collected from mothers in the age group 20-25 years with full-term neonates (37-40 weeks). The concentrations of Pb, Cd, Cu and Zn were found to be low in cord blood as compared to mother's blood and the ratio between cord blood and maternal blood for the respective elements was found to be approximately 0.80, 0.86, 0.47 and 0.40. On the other hand, the concentrations of Fe and Mg in the mother's blood were found to be lower than those in the cord blood. Prenatal exposure to lead in Mumbai, though low (5.1 microg/dl), is approximately 2-3 times higher than that observed in Canada or Italy. A strong correlation (r = 0.79) between the maternal and cord blood lead levels has been observed during the present study.     

Organochlorines in egg samples from Norwegian birds of prey: congener-, isomer- and enantiomer specific considerations

The content of chlorinated persistent organic pollutants was determined in a total of 44 egg samples from 8 different raptor species collected throughout Norway in the period 1991-1997. The content of 8 chlorinated bornanes, 9 chlorinated pesticides, and 15 polychlorinated biphenyl congeners (PCB) were determined. The highest average concentrations for PCB were found for eggs from White-tailed Sea Eagle and Peregrine Falcon (average sum PCB concentration: 8.9 and 9.1 microg/g wet weight (w.w.), respectively). Merlin and Sparrowhawk eggs were the highest contaminated with chlorinated pesticides (average sum pesticide concentration: 3.0 and 4.3 microg/g w.w.). For the first time, the content of chlorobornanes was determined in Norwegian birds of prey eggs. However, only minor contamination compared to PCBs and conventional chlorinated pesticides was found. The highest sum concentration was determined for White-tailed Sea Eagle eggs (0.09 microg/g w.w.). No chlorobornane contamination was found in Osprey and Merlin eggs. No spatial and regional specific trends or pattern distribution were found for organochlorine contamination in the egg samples analysed. In order to gain information about enantiomer specific bioaccumulation and biotransformation capacity of the organism, enantioselective analyses was performed for the chiral contaminants trans-chlordane, oxy-chlordane and the chlorobornane B9-1679 (Parlar #50). Indications for species-dependent deviation from the racemic distribution (enantiomeric ratio = 1) were found. Peregrine Falcon and Merlin eggs were characterised with an extremely high enantiomeric excess of the (-)-trans-chlordane (enantiomeric ratio (ER) <0.01). For Golden Eagle, Goshawk and Sparrowhawk eggs, the ERs were between 0.1 and 0.22 demonstrating also here that the (-)-trans-chlordane was the most abundant enantiomer. For the distribution of oxy-chlordane and B9-1679 enantiomers no species-dependent differences were found. For all species the ER values between 0.3 and 0.8 were determined. Thus, also for oxy-chlordane and B9-1679, the (-)-enantiomers are the most dominating stereoisomers in the birds of prey eggs analysed.     

Microanalysis of anionic surfactants in waste water by infrared spectroscopy

Infrared spectroscopy was applied to identify and determine microamounts of anionic surfactants contained in sewage or river waters. The surfactants tested were linear alkylbenzene sulfonate (LAS), branched alkylbenzene sulfonate (ABS), alpha olefine sulfonate (AOS), fatty alcohol sulfate (AS) and fatty alcohol ethoxy sulfate (AES).Anionic surfactants in waters were extracted by chloroform as methylene blue complexes and sulfate type surfactants, i.e. AS and AES were then removed by subsequent hydrolysis. Residual sulfonate type surfactants were first released from methylene blue complexes by ion exchange technique and then changed to sulfonyl chloride derivatives for infrared spectroscopy. Key bands for the identification of sulfonate type surfactants are 640, 618 and 524 cm⁻¹ for LAS, ABS and AOS, respectively. Sulfate type surfactants was calculated from the difference of methylene blue active substance contents before and after hydrolysis.     

Seismic methods for study of soil building properties

Bulletin of Engineering Geology and the Environment - Information about distribution of elastic wave propagation velocities Vp, Vs in the subsurface zone of a soil mass can be obtained rapidly and...     

Stable lead isotopes and lake sediments--a useful combination for the study of atmospheric lead pollution history

Analysis of stable lead isotopes and lead concentrations in lake-sediment deposits, not least in varved (annually-laminated) sediments, is a useful method to study lead pollution history. This paper presents details from a study of 31 lakes in Sweden. Using a strong acid digestion of sediment samples and ICP-MS analyses, we have found that Swedish lake sediments have a high natural (pre-pollution) 206[Pb]207[Pb] ratio (mean 1.52+/-0.18, range 1.28-2.01, n=31 lakes). In contrast, atmospheric lead pollution derived from metal smelting processes, coal burning and from alkyl-lead added to petrol has a lower ratio (< 1.2). Consequently, when pollution lead deposition began approximately 3500 years ago, the lead isotope ratio of the sediments started to decline, and in modern sediments it is typically < 1.2. Using the isotope and concentration values and a mixing model, the relative contribution of pollution and natural lead in sediment samples can be calculated. The pollution lead records of the Swedish lake sediments show a consistent picture of the atmospheric lead pollution history. Some noticeable features are the Roman peak (approx. 0 AD), the large and permanent Medieval increase (approx. 1000 AD), peaks at approximately 1200 and 1530 AD, the rapid increase after World War II, the peak in the 1970s, and the large modern decline.     

Combined nitrification/denitrification in a membrane reactor

An ever stricter legislation regulating wastewater leads to an increasing demand for biological treatment plants which are able to selectively eliminate nitrogen from wastewaters with a high influent concentration, even when operating in partial influent mode. A membrane-tube-module (MSM) reactor (Membran-Schlauch-Modul-Reaktor) was constructed and realized in the IUV at the University of Bremen. The present approach makes use of all the various layers of the whole biofilm, enabling nitrification and denitrification processes to run simultaneously in one and the same biofilm under optimized conditions. The biological degradation capacity of the system was first successfully tested with synthetic wastewater, and subsequently in a real application with effluents from a recycling of animal carcasses plant and from a coke-oven plant. A mathematical model was devised which describes this biofilm system. The resulting equations were solved by means of the simulation software AQUASIM.     

THE INCREASING EFFECTS OF ZEBRA MUSSELS ON WATER INSTALLATIONS IN ENGLAND

The zebra mussel, Dreissena polymorpha, is a major biofouling pest of water treatment works, irrigation systems and power stations in Europe and North America. This paper documents current problems associated with zebra mussels in English waterworks. Questionnaires and manual surveys conducted between 2001 and 2003 have revealed that over 30 water treatment works in England suffer problems associated with zebra mussels. Hundreds of tonnes of mussels are being removed each year from raw water intakes, pipelines and reservoirs. Problems have increased in. the last five years, due to a spread in the range of zebra mussels around England and the cessation of chemical treatment at the intakes of many treatment facilities during the 1990s. The importance of taking control of zebra mussels into account in planning new water supply schemes is highlighted.