Combined nitrification/denitrification in a membrane reactor

An ever stricter legislation regulating wastewater leads to an increasing demand for biological treatment plants which are able to selectively eliminate nitrogen from wastewaters with a high influent concentration, even when operating in partial influent mode. A membrane-tube-module (MSM) reactor (Membran-Schlauch-Modul-Reaktor) was constructed and realized in the IUV at the University of Bremen. The present approach makes use of all the various layers of the whole biofilm, enabling nitrification and denitrification processes to run simultaneously in one and the same biofilm under optimized conditions. The biological degradation capacity of the system was first successfully tested with synthetic wastewater, and subsequently in a real application with effluents from a recycling of animal carcasses plant and from a coke-oven plant. A mathematical model was devised which describes this biofilm system. The resulting equations were solved by means of the simulation software AQUASIM.     

Earthquake analysis of isotropic asymmetric multistory buildings

Isotropic multistory buildings are the ones characterized by the property: all load‐resisting planar frames have proportional lateral stiffness matrices. In the present paper it is proved that the modal analysis of an N‐story isotropic asymmetric, torsionally coupled, building (a problem of order 3N) can be separated into two independent sub‐problems: (a) a sub‐problem that corresponds to a single‐story asymmetric, torsionally coupled, building (a problem of order 3); and (b) a sub‐problem that corresponds to an N‐story, torsionally uncoupled, planar frame (a problem of order N). It is also demonstrated that the orientation of peak modal seismic forces of the building is independent of the orientation of seismic excitation, which affects only their size. The separation provides a better insight into the structural behavior of asymmetric multistory buildings under earthquake ground motion. Copyright © 2006 John Wiley & Sons, Ltd.     

Prediction of the effectiveness of rolling dynamic compaction using artificial neural networks and cone penetration test data

Rolling Dynamic Compaction(RDC),which is a ground improvement technique involving non-circular modules drawn behind a tractor,has provided the construction industry with an improved ground compaction capability,especially with respect to a greater influence depth and a higher speed of compaction,resulting in increased productivity. However,to date,there is no reliable method to predict the effectiveness of RDC in a range of ground conditions. This paper presents a new and unique predictive tool developed by means of artificial neural networks(ANNs) that permits a priori prediction of density improvement resulting from a range of ground improvement projects that employed 4-sided RDC modules;commercially known as"impact rollers". The strong coefficient of correlation(i.e. R0.86) and the parametric behavior achieved in this study indicate that the model is successful in providing reliable predictions of the effectiveness of RDC in various ground conditions.     

On the potential of combining neutron activation analysis and particle induced X-ray emission (PIXE) for micro- and microdistribution analysis of hard metals in human tissues

Tungsten carbide and cobalt are the main components of hard metal alloy while other metals such as chromium, niobium, tantalum, titanium and vanadium are sometimes added in smaller amounts. Exposure to hard metal dusts can induce a lung fibrosis with cobalt playing a major role. In order to provide information on the role that each metal may have in causing this disease, determination of the total content and the distribution of inhaled metals in lung tissue of hard metal workers is of paramount importance. However, samples such as transbronchial biopsy and bronchoalveolar lavage (BAL), often used in the medical diagnosis of pneumoconiosis, only allow for a small amount of material. This calls for sensitive and accurate analytical procedures for microdetermination and distribution of metals in pulmonary tissue and cellular material, such as macrophages. This work proposes a combination of sophisticated analytical techniques such as neutron activation analysis (NAA), currently applied to the determination of the total concentration of more than 30 elements in biological specimens, and PIXE analysis, particularly microPIXE, which has a great potential for microdistribution analysis in small biological samples. Principles and perspectives for the combined use of these techniques for the analysis of human tissue are outlined and discussed. NAA: determination of hard metals in lung tissue are carried out by neutron irradiation (2 × 10¹⁴ neutrons cm⁻² s⁻¹) in the HFR reactor of Petten. After neutron activation, radiochemical separations of ⁶⁰Co, ¹⁸⁷W, ¹⁸²Ta, ⁵¹Cr followed by computer-based high resolution gamma ray spectrometry allow the measurement of these elements in pulmonary tissues with sensitivities ranging from 10⁻⁴ μg (Cr) to 10⁻⁶ μg (W). PIXE: this technique is multielemental and of relatively high sensitivity (μg/g) even in small total sample masses of from 10 to 100 μg, thus allowing the analysis of parts of needle biopsies. Whereas PIXE has been successfully applied to many medical problems, its usefulness is limited in the total samples analysis for cobalt-related hard metal disease, due to the low levels of cobalt in tissue combined with severe element interferences from the generally more abundant metal, iron. Nevertheless, microPIXE, a special variety of the method scanning over the sample with a focussed ion beam of about 2 × 2 μm², could complement the NAA findings in total samples in the sense of achieving a microdistribution analysis of hard metals (including cobalt) in suitable thin tissue sections.The availability of specialized facilities at the JRC such as the powerful HFR reactor (Petten), the NAA laboratories (Ispra) and the microPIXE facility (Geel) could represent a European ‘reference pole’ for the study of metals in tissues of hard metal diseased subjects.     

The coagulation of a kaolinite suspension with aluminium sulphate

A study has been made of the coagulation of a 50 mg l⁻¹ aqueous suspension of kaolinite for a range of aluminium sulphate and hydrogen ion concentrations. The rate of flocculation was determined from jar tests after stirring for 1 h. The data permitted a stability limit diagram to be drawn from which some indication of the coagulation mechanisms of the system could be ascertained.     

Object–Oriented Enterprise Modeling and Simulation of AEC Projects

In this paper we describe an object–oriented framework for developing enterprise models of Architecture, Engineering, Construction projects, and a methodology for formalizing these models such that they can be used for discrete event simulation of information processing and coordination in project execution. The simulation results can be used to predict the probable effects of carrying out proposed changes in planning and managing projects.
In our enterprise modeling framework we represent engineering design projects in terms of deliverables (requirements and solutions), plans (activities and process relations), and organization (participants and organizational relations). The resulting project model is the starting point for identifying coordination requirements between project team participants. Our methodology uses matrix techniques derived from qualtiy function deployment (QFD) to identify interactions between project requirements and solutions and calculate measures of product complexity . We then describe information flow between project activities in a similar matrix and calculate measures of process uncertainty . Finally, we identify the responsibilities of project team members and use a matrix to point out organizational interdependencies .
We apply our framework and methodology to model and simulate engineering design for a major extension of an electrical power substation. Our simulation results demonstrate how project performance is contingent on the fit between the project policies and the objectives and preferences of the project team.     

An experimental behaviour of concrete-filled steel tubular columns

In this paper results of tests conducted on 27 concrete-filled steel tubular columns are reported. The test parameters were the column slenderness, the load eccentricity covering axially and eccentrically loaded columns with single or double curvature bending and the compressive strength of the concrete core. The test results demonstrate the influence of these parameters on the strength and behaviour of concrete-filled steel tubular columns. A comparison of experimental failure loads with the predicted failure loads in accordance with the method described in Eurocode 4 Part 1.1 showed good agreement for axially and eccentrically loaded columns with single curvature bending whereas for columns with double curvature bending the Eurocode loads were higher and on the unsafe side. More tests are needed for the case of double curvature bending.     

Interaction of bacteriophage R17 and reovirus type III with the clay mineral allophane

A study has been made of the adsorption of bacteriophage R17 and reovirus type 3 by the amorphous aluminosilicate clay mineral allophane. In agreement with previous studies of virus adsorption to other minerals such as montmorillonite and aluminium hydroxide, the principal factors influencing adsorption were found to be mixing time, pH and the concentrations and isoelectric points of both the virus and the absorbent. However, allophane was found to be a much better adsorbent for reovirus and R17 over the pH range 5–7, the natural pH range of many fresh waters.By using highly purified radioactive reovirus it was possible to follow both the distribution of radioactive virus in a clay suspension and the specific infectivity of the virus. This study revealed that when adsorbed virus was eluted by neutral phosphate solutions it retained its physical integrity but was of a lower specific infectivity.     

Stability analysis of simply-supported rectangular plates under non-uniform uniaxial compression using rigorous and approximate plane stress solutions

The non-classical problem of buckling of a simply-supported rectangular plate due to various types of non-uniform compressive edge loads is analysed here. For each case, the elasticity solution for the internal in-plane stress field is obtained rigorously using a superposition of Airy's stress functions and also approximately using extended Kantorovich method. Subsequently, the convergent buckling loads are obtained using Galerkin's method. Results are presented to highlight the dependence of the total buckling load and the corresponding buckled shape on the edge load distribution, as well as to illustrate the applicability of the approximate plane stress solutions.