Kinetics of the reaction of hypobromous acid and organic matters in water treatment processes.

The fate of bromine species from human activity is affected by the bromination reaction in water treatment processes. In this study, kinetic information of the reaction between hypobromous acid (HOBr) and seven different natural organic matters (NOM) was collected by sequential stopped-flow techniques. Multiple reaction phases were found in the reaction between HOBr and NOM. The number of reaction sites for the faster reaction phase ranged from 0.26 to 0.92 micromole (mg DOC)(-1), and was correlated to both SUVA and specific phenolic content at pH 7.0. The apparent second-order rate constants for the faster reaction phase at pH 7.0 ranged from 5.4 x 10(5) to 1.4 x 10(6) M(-1) x s(-1), indicating that vanillin-like structures are involved in this reaction phase.     

Self-stabilizing somersaults

We investigate the open-loop stability of a planar biped robot performing a periodic motion of forward somersaults with alternating single-leg contacts. The robot has a trunk and two actuated telescopic legs with point feet which are coupled to the trunk by actuated hinges. There is compliance and damping in the hip and in the legs. The concept of open-loop control implies that all actuators of the system receive predetermined inputs that are never altered by any feedback interference. Only with the right choice of model parameters and actuator inputs is it possible to create such self-stabilizing motions exploiting the natural stability properties of the system. These unknowns have been determined using special-purpose stability-optimization methods. The resulting motion is not only stable, but also a more efficient form of forward motion than running for the investigated robot.     

Stress-Corrosion Fracture of 12Kh18AG18Sh Steel in Chloride-Containing Media with Copper Cations

We studied the corrosion and corrosion-mechanical resistance of new austenitic high-nitrogen 12Kh18AG18Sh steel for the retaining rings of turbogenerators in aqueous solutions containing chlorides and copper (II) cations. A significant decrease in the corrosion resistance of this steel (P constitutes 0.52–14.50 mm/year) and in its resistance to corrosion cracking and corrosion-fatigue fracture in CuCl₂ solutions was established. We also calculated the coefficients of linear parts of the kinetic diagrams of fatigue fracture of the steel under study in air with a humidity of 40% and in 22% NaCl and CuCl₂ solutions.     

Stability of Periodically Unsteady Axisymmetric Jet

To date, the majority of studies on stability of axisymmetric jets have been completed under the assumption of steady mean flow. Yet, many of the natural and man-made flows that are modeled by these jets can have an inherent unsteadiness; the effects of which on the stability and transition have not been determined. Moreover, controlled unsteadiness can be used to control stability and possibly the transition to turbulence. In this note, the effects of periodic variations of the mean flow on the stability of axisymmetric jets are examined. The problem is treated analytically. The results show that the governing equations and dispersion relation for the unsteady jet can be reduced to those governing the steady jet with a time transformation. It is shown that the periodic variations in the mean flow cause amplitude and phase modulations of the unstable modes. The implications of the modulations on the subsequent transition stages are discussed.     

Single stage and double absorption heat transformers used to recover energy in a distillation column of butane and pentane

This paper presents the theoretical analysis of the use of single stage and double absorption heat transformers operating with the water–lithium bromide mixture coupled to a butane and pentane distillation column in a Mexican refinery. A mathematical model of the heat transformers was developed in FORTRAN and integrated as a user model to the Aspen Plus simulation code. Both components coupled to the column were modelled on steady-state conditions. The results show that it is theoretically possible to reduce the energy consumed in the reboiler between 26 and 43% by the use of single stage heat transformer at specific conditions, and between 28 and 33% with double absorption heat transformers for a wide range of operating conditions. Copyright © 2003 John Wiley & Sons, Ltd.     

Hazard Classification of Holding Ponds for Liquid Radioactive Wastes

This paper is devoted to the development of a method for hazard classification of holding ponds at the Industrial Association Mayak, the Siberian Intergrated Chemical Plant, and the Integrated Iron-Mining and Mining-Chemical Plant. The method is based on a combined approach employing the qualitative characteristics and quantitative parameters of the ponds. The classification of holding ponds is intended to be used for developing the requirements for the composition and content of the documentation presented by enterprises for licensing the operation and decommissioning of holding ponds.     

Determination of the total concentration and speciation of Al(III) in tea infusions

The aluminium species in different tea infusions were investigated, by determining their stability constants and concentration. This was done for some particular samples using a simple experimental method based on the sorption of aluminium on the strongly sorbing resin Chelex 100, by a batch procedure. From the thermodynamic information obtained it is possible to calculate the concentration of the different species, and in particular that of the free metal ion, which is very important for evaluating the adsorption of aluminium on biological membranes. It was found that aluminium in the tea infusions here considered is present at high total concentration, approximately 0.1 mM, but mainly linked to strong complexes, for instance with side reaction coefficient higher than 10(5.11) at pH 3.95 in one case (tea 1). This could be the reason for the low toxicity of aluminium in tea. These strong complexes were not dissociated even in the presence of Chelex 100. In this case only a limiting value of the reaction coefficient could be evaluated. The presence of the very strong complexes was found in all the tea sample here considered. In two of the considered samples (one black and one green tea) a part of Al(III) was linked to less strong complexes, for example with a reaction coefficient 10(4.14) (tea 2, pH 4.20). The presence in the considered tea infusions of other substances able to complex aluminium was also detected, by the well known ligand titration procedure, at concentration ranging from 0.65 to 3.37 mM in three tea infusions, and at somewhat higher concentration in the case of the ready drink, which was also considered for comparison.